Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis and Properties of Novel Y-type Nonlinear Optical Polyester Containing Dioxynitroazobenzene Group with Enhanced Thermal Stability of Dipole Alignment

  • Kim, Mi-Sung (Institute of Basic Science, Department of Chemistry, Inje University) ;
  • Cho, You-Jin (Institute of Basic Science, Department of Chemistry, Inje University) ;
  • Song, Mi-Young (Institute of Basic Science, Department of Chemistry, Inje University) ;
  • Lee, Ju-Yeon (Institute of Basic Science, Department of Chemistry, Inje University)
  • Received : 2011.05.10
  • Accepted : 2011.07.27
  • Published : 2011.09.20
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Abstract

New Y-type polyester (3) containing nitrophenylazoresorcinoxy groups as NLO chromophores, which are components of the polymer backbone, was prepared and characterized. Polyester 3 is soluble in common organic solvents such as N,N-dimethylformamide and acetone. It shows a thermal stability up to $240^{\circ}C$ in thermogravimetric analysis with glass-transition temperature ($T_g$) obtained from differential scanning calorimetry near $116^{\circ}C$. The second harmonic generation (SHG) coefficient ($d_{33}$) of poled polymer film at the 1064 nm fundamental wavelength is around $4.63{\times}10^{-9}$ esu. The dipole alignment exhibits a thermal stability even at $4^{\circ}C$ higher than $T_g$, and there is no SHG decay below $120^{\circ}C$ due to the partial main-chain character of polymer structure, which is acceptable for NLO device applications.

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References

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