• Title/Summary/Keyword: deactivated

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Surface Renewable Hydrogen Ion-Selective Polymeric Composite Electrode Containing Iridium Oxide

  • Quan, Hongmei;Kim, Won;Chung, Koo-Chun;Park, Jong-Man
    • Bulletin of the Korean Chemical Society
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    • v.26 no.10
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    • pp.1565-1568
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    • 2005
  • A surface renewable pH electrode was prepared by utilizing composite electrode technique. Iridium oxide micro-fine particles was prepared by hydrolysis of $(NH_4)_2IrCl_6$ at elevated temperature. The iridium oxide particles were mixed with well-dispersed carbon black and then filtered. The mixture was suspended in DMF containing PVC as a binder. The mixture was precipitated rapidly by adding large amount of water. The precipitate was ground and pressure-molded to iridium oxide composite electrode material. The electrode showed linear response between pH 1-13 with 50 to 60 mV/pH slope. The electrode maintained the pH response without appreciable slope drift for 170 days if stored in deionized water. The electrode surface can be renewed reproducibly by simple grinding process whenever contaminated or deactivated.

Dual Capillary Column System for the Qualitative Gas Chromatography: 1. Comparison Between Split and Splitless Injection Modes

  • Kim, Kyoung-Rae;Kim, Jung-Han;Park, Hyoung-Kook;Oh, Chang-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.12 no.1
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    • pp.87-92
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    • 1991
  • A dual capillary column system is described for the simultaneous measurement of retention index (RI) and area ratio (AR) values of each peak on two capillary columns of different polarity, DB-5 & DB-1701. Both capillary columns were connected to a common splitless injector via a deactivated fused-silica capillary tubing of 1 m length and a 'Y' splitter, the dead volume effect of which was found to be negligible. RI and AR were measured with high reproducibility(${\leq}$0.05% RSD) and with high accuracy (<10% RE), respectively. When applied to the test samples of the organic acid mixture, each acid was positively identified by the combined computer RI library search-AR comparison.

Dual Capillary Column System for the Qualitative Gas Chromatography: 2. Comparison between Splitless and On-Column Injection Modes

  • Kim, Kyoung-Rae;Kim, Jung-Han;Park, Hyoung-Kook;Oh, Chang-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.14 no.2
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    • pp.250-255
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    • 1993
  • A dual capillary column system is described for the simultaneous analysis of a given sample and measurement of retention index (RI) and area ratio (AR) values of each peak on two capillary columns of different polarity, DB-5 & DB-1701 from a single injection. Both capillary columns were connected to either a splitless injector or an on-column injector via a deactivated fused-silica capillary tubing of 1 m length and a 'Y' splitter. Both injection modes allowed to measure RI and AR values with high reproducibility (<0.01% RSD) and high accuracy (<10% RE), respectively with the exception that the trace and high boiling solutes required the on-column mode for the accurate quantification and AR comparison. When the dual capillary column system in on-column injection mode was applied to the blind samples containing organic acids, each acid was positively indentified by the combined computer RI library search-AR comparison.

Development of Control Algorithms Considering the Effect of a Control Sampling Period on the Total Amount of Switching for a Switched System (컨트롤 샘플링 주기가 스위칭 시스템의 결합-분리 횟수에 미치는 영향을 고려한 제어 알고리듬 개발)

  • Joung, Jin-Wook;Chung, Lan
    • Journal of the Earthquake Engineering Society of Korea
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    • v.13 no.4
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    • pp.67-76
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    • 2009
  • Recently, the active interaction control (AIC) system was proposed as a semi-active control system. The AIC system consists of a primary structure and an auxiliary structure. The objective of the AIC system is to control the response of the primary structure through engagement and disengagement between the primary and auxiliary structures. Previous switching control algorithms have been shown to be effective in reducing the response of the primary structure. However, they have the main drawback of requiring an excessive engagement-disengagement frequency and high interaction force. In this paper, the regions in which the switching is activated and the regions in which the switching is deactivated are described separately, to effectively determine the engagement or the disengagement. The general relationship between the switching regions and the deactivated switching regions selected according to the engagement-disengagement conditions is described within the newly-developed comprehensive switching framework. The proposed engagement-disengagement conditions are designed within a comprehensive switching framework, to reduce engagement-disengagement frequency and interaction force. Furthermore, the effect of a control sampling period on the AIC system is explained in terms of the engagement-disengagement frequency. The effectiveness of the proposed algorithms and the effect of the control sampling period are considered for a single degree of freedom model under free vibration. It is observed that increasing the duration of stay by using a large control sampling period prevents the AIC system from activating the possible chance of switching. The proposed algorithms are shown to be effective, both in restricting ineffective switching and in reducing interaction force.

A Study on the Effectiveness of Remanufacturing Technology for the Catalyzed Diesel Particulate Filter-trap(DPF) Deactivated by Diesel Exhaust Gas (촉매가 담지된 사용후 경유차 매연저감장치 DPF의 재제조 효과에 관한연구)

  • Choi, Kang-Yong;Park, Hea-Kyung
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.10
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    • pp.957-964
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    • 2010
  • The deactivated catalyzed diesel particulate filter-trap (DPF) was remanufactured by ultrasonic wave treatment with various prepared solutions, followed by active component re-impregnation, and the emission control performance and surface properties of remanufactured DPF were studied at various remanufacturing conditions. The proper ultrasonic wave cleaning time at various prepared solutions and optimal re-impregnation amounts of active component for the best emission control performance of DPF were investigated and its performance tests were also carried out with various temperatures for the conversions of CO, THC (total hydrocarbon) and PM (particulate matter) by catalytic reaction test unit using bypass gas from the diesel engine dynamo system. It was found that the emission control performance of DPF remanufactured with the high-temperature air washing, ultrasonic wave cleaning at acid/base solutions and active component re-impregnation method was recovered to 95% level of its activity compared to that of the fresh DPF, which was caused by removing the deactivating materials from the surface of the DPF, through the analyses of performance test and their surface characterization by Optical microscope, EDX, ICP, TGA, and porosimeter.

Effect of Inlet Valve Angle on In-Cylinder Swirl. Generation Characteristics(II) (흡입밸브 각이 실린더 내 와류 발생 특성에 미치는 영향(II))

  • Ohm, In-Yong;Park, Chan-Jun
    • Transactions of the Korean Society of Automotive Engineers
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    • v.17 no.2
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    • pp.42-48
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    • 2009
  • This paper is the second of 2 companion papers which investigate in-cylinder swirl generation characteristics according to inlet valve angle. Two DOHC 4 valve engines, one has wide intake valve angle and the other has narrow valve angle, were used to compare the characteristics of swirl motion generation in the cylinder. One intake port was deactivated to induce swirl flow. A PIV (Particle Image Velocimetry) was applied to measure in-cylinder velocity field according to inlet valve angle during intake stroke. The results show that the flow patterns of narrow valve engine are much more stable and well arranged compared with the normal engine over the entire intake and compression stroke except early intake stage, and very strong swirl motion is generated at the end of compression stage in this engine nevertheless using straight port which is unfavorable for swirl generating. In the wide valve angle one, however, strong swirl motion induced during intake stroke is destroyed as the compression progresses.

IoT based real time agriculture farming

  • Mateen, Ahmed;Zhu, Qingsheng;Afsar, Salman
    • International journal of advanced smart convergence
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    • v.8 no.4
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    • pp.16-25
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    • 2019
  • The Internet of things (IOT) is remodeling the agribusiness empowering the agriculturists through the extensive range of strategies, for example, accuracy as well as practical farming to deal with challenges in the field. The paper aims making use of evolving technology i.e. IoT and smart agriculture using automation. The objective of this research paper to present tools and best practices for understanding the role of information and communication technologies in agriculture sector, motivate and make the illiterate farmers to understand the best insights given by the big data analytics using machine learning. The methodology used in this system can monitor the humidity, moisture level and can even detect motions. According to the data received from all the sensors the water pump, cutter and sprayer get automatically activated or deactivated. we investigate a remote monitoring system using Wi-Fi. These nodes send data wirelessly to a central server, which collects the data, stores it and will allow it to be analyzed then displayed as needed and can also be sent to the client mobile.

A Study on the Design of Low Power Digital PLL (저전력 디지털 PLL의 설계에 대한 연구)

  • Lee, Je-Hyun;Ahn, Tae-Won
    • 전자공학회논문지 IE
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    • v.47 no.2
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    • pp.1-7
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    • 2010
  • This paper presents a low power digital PLL architecture and design for implementation of the PLL-based frequency synthesizers. In the proposed architecture, a wide band digital logic quadricorrelator is used for preliminary frequency detector and a narrow band digital logic quadricorrelator is used for final DCO control. Also, a circuit technique for reducing leakage current is adopted in order to minimize the standby mode power consumption of the deactivated block. The proposed digital PLL is designed and verified by MyCAD with MOSIS 1.8V $0.35{\mu}m$ CMOS technology, and the simulation results show that the power consumption can be lowered by more than 20%.

Enzyme Deactivation During Enzyme Recycling with Ultrafiltration Hollow Fibers (한외여과막을 이용한 효소재순환 시스템에서의 효소역가감소)

  • 김준석;정용섭홍석인
    • KSBB Journal
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    • v.11 no.3
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    • pp.347-352
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    • 1996
  • The enzyme deactivation in a membrane recycling system for the simultaneous saccharification and fermentation(SSF) was studied under various temperature and pressure. The optimum molecular weight cut off(MWCO) of the ultrafiltration membrane for recycling cellulase and ${\beta}$-glucosidase was 50,000. When the cellulase was recycled continuously through the membrane system, it was not deactivated. But the activity of ${\beta}$-glucosidase was decreased with an increase in operating temperature and transmembrane pressure. After 720 minutes at $42^{\circ}C$ and 24.8 psig , the activity of ${\beta}$-glucosidase was reduced by 35% of the initial activity. Such tendencies could be well explained by the results of highly induced shear at the fiber surface of membrane when temperature and transmembrane pressure became higher.

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Development of Two-stage CSTG/TBF System for the Cometabolic Degradation of Gas-phase TCE by Burkholderia cepacia G4 (Burkholdera cepacia G4를 이용한 기상의 트리클로로에틸렌의 공대사적분해를 위한 2단계 CSTR/TBF 시스템 개발)

  • 이은열;박성훈
    • KSBB Journal
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    • v.16 no.5
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    • pp.511-515
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    • 2001
  • In this paper, we development and operated a two-stage continuous stirred tank reactor (CSTR)/trickling biofilter(TBF)system for the long-term continuous treatment of trichloroethylene (TCE) using Burkholderia cepacia G4. In this reactor system. CDTR with cell recycle from TBF was coupled to the TBF for the reactivation of the cells deactivated during TCE degradation. The critical elimination capacity was determined to be 25.3 mg TCE/L day and the reactor has been stably operated for more than 1 months, which clearly represented that CSTR/TBF system can be used for long-term treatment of TCE.

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