• Title/Summary/Keyword: cylindrical pores

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Fabrication of nano-rod on AAO template (AAO에 의한 나노로드 제작)

  • Hamrokulov, B.;Park, B.H.;Kim, In-Soo
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.482-484
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    • 2008
  • Anodic aluminum oxide (AAO) which prepared with two-step anodizing method (with dissimilar solutions) was used as a template to fabricate highly ordered, free standing metal nano-rods. AAO nano-template technique can realize self-organized hexagonal pore structure with nanometer dimension size, it's easy to control pore diameter, length and density by varying anodizing conditions. Ni and Ni/Fe/Cu multi-metal layer nanorods were electrochemically deposited into AAO nano-template by AC voltage in simple sulfate solutions.. The properties of samples are tested by X-ray diffraction (XRD), field emission microscopy (FE-SEM).

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Design LixV2O5 Cathode Structure for Effective Lithium Ion Intercalation (리튬 이차전지 양극재 LixV2O5의 효율적인 방전을 위한 구조 설계)

  • Park, Jun Kyu;Kim, Soo Il;Kim, Dongchoul
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.7
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    • pp.589-594
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    • 2014
  • Recently, higher capacity and energy density of lithium ion batteries are increasingly demanded for enhancing their performance in view of the rise in the commercial distribution of electric and hybrid vehicles. Computational analysis of a porous structure of vanadium pentoxide cathode was performed, employing a phase field model. The incipient model was designed as a spherical structure with cylindrical-shaped pores. Modifying the diameters and lengths of the pore cylinder and the number of pores, we considered different conditions for the porous vanadium pentoxide cathodes for analyzing their effect on the amount of lithium ion intercalated to them. Subsequently, we optimized the porous structure to contain the largest amount of intercalated lithium ion during discharge.

Computed tomography investigation of the three-dimensional structure and production method of White Porcelain Water Dropper with Openwork Lotus Scroll Design and Eight Trigram Design in Cobalt-blue Underglaze (CT 조사를 통한 청화백자투각연당 초팔괘문연적의 3차원적 구조와 제작방법에 대한 고찰)

  • Na, Ahyoung;Hwang, Hyunsung
    • Conservation Science in Museum
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    • v.25
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    • pp.1-8
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    • 2021
  • This study investigated White Porcelain Water Dropper with Openwork Lotus Scroll Design and Eight Trigram Design in Cobalt-blue Underglaze (hereinafter, the "water dropper") in the collection of the National Museum of Korea using computed tomography (CT). A replica was produced to examine both the structure and its original production method. The CT scanning identified no joint lines or pores in the clay, which suggests that the body (the lower part of the water dropper) was shaped in a single piece using a mold and was then matched with a mold-formed lid (the upper part of the water dropper). The inner container of the body portion was roughly trimmed with a bamboo knife so that its upper surface could be securely attached to the bottom of the lid and prevent any leakage in the joined surface. It appears that the inner container for storing water was made first in a cylindrical shape that met the unit of quantity used at the time and could be easily formed by molding. It was transformed into a trapezoid shape during the process of combining it with the lid. A cylindrical inner container was reproduced using silicon 3D printing to compare its capacity with that of the original inner container. The comparison revealed that the reproduced container had a capacity of 152.5㎖, whereas the original container holds approximately 168.6㎖, a figure similar to three hop (around 174㎖) in Joseon-period units of quantity. Since the capacity of the cylindrical inner container corresponds to a known measure from the late Joseon dynasty, it is likely that the water dropper was originally produced to contain a cylindrical inner container.

Modified Shrinking Core Model for Atomic Layer Deposition of TiO2 on Porous Alumina with Ultrahigh Aspect Ratio

  • Park, Inhye;Leem, Jina;Lee, Hoo-Yong;Min, Yo-Sep
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.519-523
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    • 2013
  • When atomic layer deposition (ALD) is performed on a porous material by using an organometallic precursor, minimum exposure time of the precursor for complete coverage becomes much longer since the ALD is limited by Knudsen diffusion in the pores. In the previous report by Min et al. (Ref. 23), shrinking core model (SCM) was proposed to predict the minimum exposure time of diethylzinc for ZnO ALD on a porous cylindrical alumina monolith. According to the SCM, the minimum exposure time of the precursor is influenced by volumetric density of adsorption sites, effective diffusion coefficient, precursor concentration in gas phase and size of the porous monolith. Here we modify the SCM in order to consider undesirable adsorption of byproduct molecules. $TiO_2$ ALD was performed on the cylindrical alumina monolith by using titanium tetrachloride ($TiCl_4$) and water. We observed that the byproduct (i.e., HCl) of $TiO_2$ ALD can chemically adsorb on adsorption sites, unlike the behavior of the byproduct (i.e., ethane) of ZnO ALD. Consequently, the minimum exposure time of $TiCl_4$ (~16 min) was significantly much shorter than that (~71 min) of DEZ. The predicted minimum exposure time by the modified SCM well agrees with the observed time. In addition, the modified SCM gives an effective diffusion coefficient of $TiCl_4$ of ${\sim}1.78{\times}10^{-2}\;cm^2/s$ in the porous alumina monolith.

Ultrastructural Variations on the Micropyle of Blacktip Grouper, Epinephelus Fasciatus before and after Artificial Fertilization (홍바리, Epinephelus fasciatus의 인공수정 전.후 난문의 미세구조적 변화)

  • Kim, Seong-Hoon;Lee, Chi-Hoon;Ju, Hea-Sung;Kim, Hyung-Bae;Lee, Young-Don
    • Applied Microscopy
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    • v.41 no.2
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    • pp.123-128
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    • 2011
  • The micropyles on the prefertilized and artificial fertilized eggs of Epinephelus fasciatus were investigated using scanning electron microscope (SEM). The micropyles ($6.6{\pm}0.41\;{\mu}m$) of E. fasciatus eggs were found in the animal pole and theirs shape were observed as a flat crateriform of cylindrical shape. The micropylar vestibule arranged by 6~7 thickened spiral annuli on the ridge and contributed to differentiate and form fertilization cone for blocking to polyspermy by presenting swollen vestibule structure. As E. fasciatus eggs was pelagic, so chorionic surface was an uneven structures such as circular and fillar form nodules. Especially, various pores (0.15~0.55 ${\mu}m$, 230~270 pores) distributed at the only around micropyles, those pores radiately exhibited regular projection structures showing gill filament-shape. These ultrastructural characters of E. fasciatus eggs can be utilized in a taxonomical cue of grouper species.

Nanoporous Membrane with Ultrahigh Selectivity and Flux Suitable for Filtration of Viruses

  • Yang, Seung-Yun;Ryu In-Cheol;Jang, Sung-Key;Kim, Jin-Kon;Russell Thomas P.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.313-313
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    • 2006
  • In this study, we describe a new double layered nanoporous membrane suitable for virus filtration. One layer is an 80 nm thick film having cylindrical pores with diameters of 15 nm and a narrow pore size distribution. This layer is prepared by using a thin film of the mixture of a block copolymer and a homopolymer, and mainly acts to separate viruses. The support layer (${\sim}150\;microns\;thick$) is a conventional micro-filtration membrane with a broad pore size distribution. This asymmetric membrane showed very high selectivity and flux for the separation of human rhinovirus type 14 (HRV 14) which has a diameter of ${\sim}30\;nm$ and is a major pathogen of the common cold in humans.

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First Record of Potentially Pathogenic Amoeba Vermamoeba vermiformis (Lobosea: Gymnamoebia) Isolated from a Freshwater of Dokdo Island in the East Sea, Korea

  • Park, Jong Soo
    • Animal Systematics, Evolution and Diversity
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    • v.32 no.1
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    • pp.1-8
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    • 2016
  • Vermamoeba vermiformis is a very important free-living amoeba for human health in association with Legionnaires' disease and keratitis. This interesting amoeba was firstly isolated from a freshwater of Dokdo (island), which was historically used for drinking water. Trophozoites and cyst forms of V. vermiformis strain MG1 are very similar to previous reported species. Trophozoites of V. vermiformis strain MG1 showed cylindrical shape with prominent anterior hyaline region. The average ratio of length and width was about 6.5. Typically, cysts of the strain MG1 showed a spherical or slightly ovoidal shape with smooth wall, and lacked cyst pores. Some cysts had crenulate-walled ectocyst, which was separated from endocyst wall. Further, 18S rRNA gene sequence of V. vermiformis strain MG1 showed very high similarity to other V. vermiformis species (99.4%-99.9% identity). Molecular phylogenetic analysis based on 18S rRNA gene sequences clearly confirmed that the isolate was one strain of V. vermiformis with maximum bootstrap value (maximum likelihood: 100%) and Bayesian posterior probability of 1. Thus, the freshwater of Dokdo in Korea could harbor potentially pathogenic amoeba that may cause diseases in humans.

Thermally Stabilized Porous Nickel Support of Palladium Based Alloy Membrane for High Temperature Hydrogen Separation

  • Ryi, Shin-Kun;Park, Jong-Soo;Cho, Sung-Ho;Hwang, Kyong-Ran;Kim, Sung-Hyun
    • Corrosion Science and Technology
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    • v.6 no.3
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    • pp.133-139
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    • 2007
  • Nickel powder was coated with aluminum nitrate solution to increase the thermal stability of a porous nickel support and control the nickel content in the Pd-Cu-Ni ternary alloyed membrane. Raw nickel powder and alumina coated nickel powder were uniaxialy pressed by home made press with metal cylindrical mold. Though the used nickel powder prepared by pulsed wire evaporation (PWE) method has a good thermal stability, the porous nickel support was too much sintered and the pores of porous nickel support was plugged at high temperature (over $800^{\circ}C$) making it not suitable for the porous support of a palladium based composite membrane. In order to overcome this problem, the nickel powder was coated by alumina and alumina modified porous nickel support resists up to $1000^{\circ}C$ without pore destruction. Furthermore, the compositions of Pd-Cu-Ni ternary alloy membrane prepared by magnetron sputtering and Cu-reflow could be controlled by not only Cu-reflow temperature but also alumina coating amount. SEM analysis and mercury porosimeter analysis evidenced that the alumina coated on the surface of nickel powder interrupted nickel sintering.

Measurement of Effective Refractive Index of Anodic Aluminum Oxide Using a Prism Coupler

  • Gong, Su-Hyun;Cho, Y.H.;Stolz, Arnaud;Gokarna, Anisha;Dogheche, Elhadj;Ryu, Sang-Wan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.195-195
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    • 2010
  • In recent years, Anodic aluminum oxide(AAO) has become popular and attractive materials. It can be easily fabricated and self-organized pore structures. It has been widely used as a biosensor membrane, photonic crystal for optical circuit and template for nanotube growth etc. In previous papers, the theory was developed that AAO shows anisotropic optical properties, since it has anisotropic structure with numerous cylindrical pores. It gives rise to the anisotropy of the refractive index called as birefringence. It can be used as conventional polarizing elements with high efficiency and low cost. Therefore, we would like to compare the theory and experimental results in this study. One method which can measure effective refractive index of thin film is the prism coupling technique. It can give accurate results fast and simply. Furthermore, we can also measure separately the refractive index with different polarization using polarization of the laser (TE mode and TM mode). We calculated the effective refractive index with effective medium approximations (EMAs) by pore size in the SEM image. EMAs are physical models that describe the macroscopic system as the homogeneous and typical method of all mean field theories.

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Acoustic Characteristics of Lucite Slab with Circular Cylindrical Pores (원통형 다공을 갖는 판형 루사이트의 음향 특성)

  • Baik Jae Yoon;Roh Heui-Seol;Yoon Suk Wang
    • Proceedings of the Acoustical Society of Korea Conference
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    • autumn
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    • pp.299-302
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    • 2000
  • 임의의 매질에서 음파의 전파는 매질의 고유물성 및 구조적 특성에 영향을 받게 된다. 본 연구는 의공학에서 관심을 가지는 골다공증 진단의 기초 물리적 음향 특성을 이해함에 목적을 두고 있다. 따라서 구조적 특성의 중요한 요소인 매질의 다공성에 초점을 두고 있으며, 비강체의 다공성 물질로써 루사이트 판에 원통 형태의 관을 균일하게 배열시켰고 이 관들의 배열을 다공성 구조로 간주하였다. 다공도는 본 연구에서 의미 있는 범위, 약 $0\%-30\%$에 제한하였으며, 다공도에 따른 음향 특성 변화를 관찰하기 위하여 다공도의 차이를 두었고, 관의 직경에 따른 음향 특성 변화를 관찰하기 위하여 같은 다공도와 두 종류의 관의 크기를 갖는 다공성 루사이트를 제작하였다. 실험은 수중에서 음파의 입사각에 대한 의존도를 배제하기 위하여 수직 입사에 대하여 수행하였고 사용된 주파수는 880kHz이다. 다공도 및 관의 크기의 변화에 따른 음파의 투과 계수의 변화를 관측하여 다공도 및 관의 크기의 변화에 따른 음향특성 변화의 상관 관계를 고찰함으로써 골다공증 진단에의 응용 가능성을 연구하였다.

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