• Title/Summary/Keyword: cylindrical pore

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Effect of CH3COOH Concentration on Characteristics of Fe2O3Supported δ-alumina Catalyst by Hydrothermal Method (CH3COOH 농도가 수열법으로 제조된 Fe2O3 담지 감마알루미나 촉매의 특성에 미치는 영향)

  • 박병기;이정민;서동수
    • Journal of the Korean Ceramic Society
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    • v.40 no.8
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    • pp.758-764
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    • 2003
  • The cylindrical ${\gamma}$-alumina pellets were prepared by forming, hydration, drying and calcination after mixing amorphous alumina and pore generating agent with water. Concentration of Fe(NO$_3$)$_3$ㆍ9$H_2O$ that was catalyst precursor was fixed and made mixing solution that changed concentration of $CH_3$COOH in range of 2.5~20%, and here ${\gamma}$-alumina pellets were immerged and were hydrothermaly treated for 3 h at $200^{\circ}C$. And then we investigated creation and change of crystal, pore characteristics, $N_2$ adsorption and desorption isotherms, changes of acid site and mechanical strengths etc. According to the concentration of $CH_3$COOH, the crystals grew to acicular shape of 0.5~2${\mu}m$ length, and crystal structure showed the pseudo-boehmite structure. When hydrothermaly treated in 10% $CH_3$COOH solution, pore volume between 100~1000 $\AA$ was highest by 0.86 cc/g, and width of hysteresis curved line due to $N_2$ adsorption/desorption appeared as was smallest. When concentration of $CH_3$COOH was in range of 5~15%, new C-H functional groups were formed. Mechanical strength of pellets was highest by 1.35 MPa when $CH_3$COOH concentration was 2.5%.

A Study on the Drainage Effects of Gravel Drain by Laboratory Model Test (실내모형시험을 통한 Gravel Drain의 배수효과에 관한 연구)

  • 천병식;김백영;고용일;여유현;박경원
    • Proceedings of the Korean Geotechical Society Conference
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    • 1999.10a
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    • pp.87-94
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    • 1999
  • Sand drain as a vertical drainage is widely used in soft ground improvement. Recently, sand, the principal source of sand drain, is running out. A laboratory model test was carried out to utilize gravel as a substitute for sand. Though which the characteristics of gravel are compared to those of sand for engineering purpose. Two cylindrical containers for the model test were filled with marine clayey soil from the west coast of Korea with a column in the center, one with sand, the other with gravel. Vibrating wire type piezometers were installed at the distance of 1.0D, 1.5D and 2.0D from the center of the column. D is the diameter of the column. The transient process of pore water pressure with loading and the characteristics of consolidation were studied with the data gained from the measuring instrument place on the surface of the container. The parameter study was performed for the marine clayey soil before and after the test in order to check the effectiveness of the improvement. The clogging effect was checked at various depth in gravel column after the test. According to the test, the settlement was found to be smaller in gravel drain than in sand drain. The increase in bearing capacity by gravel pile explains the result. The clogging effect was not found in gravel column. As a result, it is assumed that gravel is relatively acceptable as a drainage material.

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An Experimental Study on the Heat Transport Characteristics of a Sodium Heat Pipe for a Solar Furnace (태양열 반응로용 나트륨 히트파이프의 열이송 특성에 관한 실험적 연구)

  • Boo, Joon-Hong;Park, Cheol-Min;Kim, Jin-Soo;Kang, Yong-Heack
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.178-181
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    • 2008
  • Cylindrical stainless-steel/sodium heat pipe for a high-temperature application was manufactured and tested for transient and steady-state operations. The container material was made of stainless-steel 316, and the working fluid was sodium. Stainless-steel 316 mesh screen was inserted as a capillary structure. The working fluid fill charge ratio was approximately 64 $\sim$ 181% based on the pore space of the wick. The outer diameter of the heat pipe was 12.7 mm and the total length was 250 mm. The evaporator part was 150 mm and the condenser 80 mm. The performance test of the heat pipe has been conducted in the furnace with up to 800 W. The variation of the average heat transfer coefficient was investigated as a function of heat flux and vapor temperature. As input thermal load increased, it was showed that difference of temperatures in evaporator and condenser decreased and that operating section and heat transfer characteristics at the heat pipe increased.

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Thermally Stabilized Porous Nickel Support of Palladium Based Alloy Membrane for High Temperature Hydrogen Separation

  • Ryi, Shin-Kun;Park, Jong-Soo;Cho, Sung-Ho;Hwang, Kyong-Ran;Kim, Sung-Hyun
    • Corrosion Science and Technology
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    • v.6 no.3
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    • pp.133-139
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    • 2007
  • Nickel powder was coated with aluminum nitrate solution to increase the thermal stability of a porous nickel support and control the nickel content in the Pd-Cu-Ni ternary alloyed membrane. Raw nickel powder and alumina coated nickel powder were uniaxialy pressed by home made press with metal cylindrical mold. Though the used nickel powder prepared by pulsed wire evaporation (PWE) method has a good thermal stability, the porous nickel support was too much sintered and the pores of porous nickel support was plugged at high temperature (over $800^{\circ}C$) making it not suitable for the porous support of a palladium based composite membrane. In order to overcome this problem, the nickel powder was coated by alumina and alumina modified porous nickel support resists up to $1000^{\circ}C$ without pore destruction. Furthermore, the compositions of Pd-Cu-Ni ternary alloy membrane prepared by magnetron sputtering and Cu-reflow could be controlled by not only Cu-reflow temperature but also alumina coating amount. SEM analysis and mercury porosimeter analysis evidenced that the alumina coated on the surface of nickel powder interrupted nickel sintering.

Experimental Study on Consolidation Characteristics of Soft Marine Deposit by Piezocone Dissipation Test (피에조콘 소산시험을 통한 해성연악지반의 압밀특성에 대한 실험적 연구)

  • 박찬국;송정락;김수일
    • Journal of the Korean Geotechnical Society
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    • v.18 no.2
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    • pp.137-146
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    • 2002
  • Field piezocone dissipation tests are performed, and the results are compared to the Rowe cell consolidation tests results to investigate the consolidation characteristics of soft marine deposit at the same location in Korea. From these results, statistical formula fur the relation between the coefficients of horizontal consolidation$(c_r)$ from Rowe cell consolidation tests and $t_{50}$ from pore pressure dissipation tests by Piezocone is suggested through the regression analysis. The results are also compared to the existing theoretical formula. It is also shown that suggested formula is similar to Torstensson's(1977) formula based on cylindrical cavity expansion theory and Houlsby and Teh's(1988) formula based on strain path method.

The diffusion model on the electrodes with nano-porous surfaces (나노 다공성 표면 전극 위의 확산 모델)

  • Park, Jin-Hyoung;Park, Sae-Jin;Chung, Taek-Dong;Kim, Hee-Chan
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1100-1103
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    • 2003
  • One of the good ways to raise the rate of the electrochemical reaction is to broaden the effective surface area of the electrode by developing cylindrical nano-pores on the surfaces. The numerous pores of several nanometer in diameter can be used to enhance a specific faradaic reaction so that the nano-porous structure attract keen attention in terms of implication of new bio/chemical sensors, in which no chemical modification is involved. Amperometric glucose sensor is a representative example that needs the selective enhancement of glucose oxidation over the current due to physiological interferents such as ascorbic acid. The present paper reports how the ascorbic acid and glucose diffuse around the nano-porous surface by simulation study, for which 2D-FDM (Finite Difference Method) was adopted. The results of the simulation not only consist with those from electrochemical experiments but also reveal valuable potential for more advanced application of the nano-porous electrode.

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Analysis of the Negative Skin Friction Acting on a Model Pile (모형말뚝에 작용하는 부마찰력 거동 해석)

  • Lee, Song;Lee, Kyu-Hwan;Yi, Chang-Tok
    • Journal of the Korean Geotechnical Society
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    • v.15 no.2
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    • pp.81-93
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    • 1999
  • This paper investigated the negative skin friction acting on the model piles driven in the cylindrical chamber filled with remolded marine clay. In model tests, three load cells were installed on the model piles consisting of three parts to measure the negative skin friction forces independently. Pore pressures and ground movements were monitored throughout the period of investigation. Finite element analysis was used to simulate the behavior of a model pile. This paper describes the comparison of the behavior of negative skin friction on the single model pile with a numerical analysis by CRISP.

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A Study on the Behavior of Combustion Wave Propagation and the Structure of Porous TiNi Body during Self-propagating High-temperature Synthesis Process

  • Kim, Ji-Soon;Gjuntera, Victor E.;Kim, Jin-Chun;Kwon, Young-Soon
    • Journal of Powder Materials
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    • v.17 no.1
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    • pp.29-35
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    • 2010
  • We produced cylindrical porous TiNi bodies by Self-propagating High-temperature Synthesis (SHS) process, varying the heating schedule prior to ignition of a loose preform compact made from (Ti+Ni) powder mixture. To investigate the effect of the heating schedule on the behaviour of combustion wave propagation and the structure of porous TiNi shape-memory alloy (SMA) body, change of temperature in the compact during SHS process was measured as a function of time and used for determining combustion temperature and combustion wave velocity. Microstructure of produced porous TiNi SMA body was observed and the results were discussed with the combustion characteristics. From the results it was concluded that the final average pore size could be controlled either by the combustion wave velocity or by the average temperature of the preform compact prior to ignition.

A novel triaxial testing device for unsaturated soils with measurement of suction and volumetric strains

  • Qian-Feng Gao;Mohamad Jrad;Mahdia Hattab;Said Taibi;Jean M. Fleureau
    • Geomechanics and Engineering
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    • v.37 no.2
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    • pp.109-122
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    • 2024
  • Standard triaxial cells are commonly used to measure the mechanical behavior of saturated soils. However, this type of standard system is difficult to use for unsaturated soil specimens since it cannot measure the changes in the pore-air volume and pressure. This paper proposes to extend the measurement possibilities of the standard triaxial testing device in a simple way and to adapt it to partially saturated soils. The system is supplied by two hygrometers installed at each end of the cylindrical unsaturated specimen to measure local relative humidity, which allows the derivation of suction. The volumetric strain of the specimen is calculated by analyzing digital photos captured from the outside of the transparent cell wall. Specimens made of kaolin clay, having different hydraulic properties, were tested to verify the reliability of the measurements, and thus, the relevance of the proposed techniques to study the mechanical behavior of unsaturated soils.

Preparation of the Hollow Fiber Type Perovskite Catalyst for Methane Complete Oxidation (메탄의 완전산화 반응을 위한 중공사형 페롭스카이트 촉매 제조)

  • Lee, Seong Woon;Kim, Eun Ju;Lee, Hong Joo;Park, Jung Hoon
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.297-302
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    • 2018
  • Bead type and hollow fiber type catalyst (HFC, Hollow Fiber type Catalyst) was prepared by $La_{0.1}Sr_{0.9}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ (LSCF1928) perovskite powder catalyst which showed excellent methane complete oxidation characteristics through previous studies. The HFC have a cylindrical shape with an empty interior, and pores can be formed through Phase inversion method so the specific surface area can be remarkably improved. In the case of the bead type catalyst prepared by adding Methyl Cellulose (MC), $SrCO_3$ was produced in addition to the original catalyst composition of LSCF1928 due to the reaction of $CO_2$ emitted from MC and Sr of the catalyst. In the case of the HFC, a single phase perovskite structure was obtained without impurities. The HFC calcined at $700{\sim}900^{\circ}C$ showed pore structure of finger-sponge-finger structure, and 99.9% oxygen conversion rate was achieved through complete oxidation of methane at $475^{\circ}C$. Air gap and spinning pressure condition were changed to control the HFC pore. 2 cm air gap and 7 bar spinning pressure showed the best catalytic performance and achieved oxygen conversion rates of more than 70.65%, 93.01%, and 99.99% at $425^{\circ}C$, $450^{\circ}C$ and $475^{\circ}C$, respectively.