• Membrane and Water Treatment
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• 제13권4호
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• pp.167-172
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• 2022

The analytical results are presented for the mass transfer in a cylindrical pore covering from the macroscale, multiscale to nanoscale owing to the variation of the inner diameter of the pore. When the thickness h_bf of the physically adsorbed layer potentially fully formed on the pore wall is comparable to but less than the inner radius R₀ of the pore, the multiscale flow occurs consisting of both the nanoscale non-continuum adsorbed layer flow and the macroscopic continuum liquid flow; When R₀ ≤ h_bf, the flow in the whole pore is essentially non-continuum; When R₀ is far greater than h_bf, the flow in the whole pore can be considered as macroscopic and continuum and the adsorbed layer effect is negligible.

• Bulletin of the Korean Chemical Society
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• 제33권3호
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• pp.901-905
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• 2012

In this study, we investigated the pure geometrical effect of porous materials in gas adsorption using the grand canonical Monte Carlo simulations of primitive gas-pore models with various pore geometries such as planar, cylindrical, and random pore geometries. Although the model does not possess atomistic level details of porous materials, our simulation results provided many insightful information in the effect of pore geometry on the adsorption behavior of gas molecules. First, the surface curvature of porous materials plays a significant role in the amount of adsorbed gas molecules: the concave surface such as in cylindrical pores induces more attraction between gas molecules and pore, which results in the enhanced gas adsorption. On the contrary, the convex surface of random pores gives the opposite effect. Second, this geometrical effect shows a nonmonotonic dependence on the gas-pore interaction strength and length. Third, as the external gas pressure is increased, the change in the gas adsorption due to pore geometry is reduced. Finally, the pore geometry also affects the collision dynamics of gas molecules. Since our model is based on primitive description of fluid molecules, our conclusion can be applied to any fluidic systems including reactant-electrode systems.

• 환경생물
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• 제36권3호
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• pp.319-328
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• 2018

The morphology, anatomy and reproduction (tetra/bisporic and male) of Lithothamnion japonicum Foslie was studied, using holotype material and materials collected from Korea. Lithothamnion japonicum is characterized based on the presence of encrusting, warty to fruticose thallus, branched or unbranched short and cylindrical protuberances, conical shaped spermatangial conceptacles, branched (dendroid) spermatangial systems formed on floor, walls, and roof of conceptacle chamber, cylindrical shaped spermatangial conceptacle canal, 9-10 cell layered spermatangial conceptacle roof, raised tetra/bisporangial conceptacles without rims, flattened tetra/bisporangial conceptacle pore plate, 16-50 pores on each pore plate, 6-8 rosette cells surrounded by each pore, pore canal lining filaments composed of tetra/bisporangial conceptacle roof, and buried senescent tetra/bisporangial conceptacles completely infilled with relatively large and irregularly arranged calcified sterile cells. In this study, we report a new record of Lithothamnion japonicum from Korean coasts.

• 한국재료학회지
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• 제20권5호
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• pp.252-256
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• 2010

The study was done to change the morphology and pore size of SBA-15 silica, and the characteristics of SBA-15 silica were investigated with TG-DSC, XRD, SEM, TEM and N2 adsorption-desorption under changing aging conditions. SBA-15 silica having a 2D-hexagonal structure was synthesized and confirmed by SEM and TEM. The structure of mesoporus silica SBA-15 showed a pore having regularly formed hexagonal structure and a passage having a cylindrical shape. This result is in good agreement with the pore forming in XRD and cylindrical shape of the structure in $N_2$ adsorption-desorption isotherm. SBA-15 silica showed a large BET surface area of $603-698\;m^2/g$, a pore volume of $0.673-0.926\;cm^3/g$, a large pore diameter of 5.62-7.42 nm, and a thick pore wall of 3.31-4.37 nm. This result shows that as the aging temperature increases, the BET surface area, pore volume, and pore diameter increase but the pore wall thickness decreases. The BET surface areas in SM-2 and SM-3 are as large as $698\;m^2/g$. However, SM-2 has a large surface area and forms a thick pore wall, when the aging temperature is $100^{\circ}C$ and is synthesized into stable mesoporous SBA-15 silica.

• 청정기술
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• 제12권4호
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• pp.224-231
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• 2006

현탁액중의 부유입자를 제거하는 입상여과공정을 Network 모델을 이용하여 여과효율과 압력손실에 대해 예측하였다. 구형 여재로 구성되어 있는 여재 층을 node와 원통형 bond로 구성된 network로 가정하였으며 여과 공정을 통해 부유입자는 bond 표면에 포집된다. 원통형 bond에서의 여과효율은 bond의 세공부피를 단위 cell의 유체 막 부피로 가정하여 입자의 경로 분석을 이용하여 구하였으며, 포집된 부유입자가 추가적인 여재로서의 역할은 bond 세공이 좁아짐에 따른 효율 증가로 나타내었다. 또한 세공이 좁아짐에 따른 압력손실도 예측하였다. 본 network 모델의 세공 분포를 부여하는 과정의 stochastic한 성질로 인하여 많은 전산모사가 필요하지만, 본 모델을 이용하여 여과효율과 압력손실을 동시에 예측할 수 있었다.

• Geomechanics and Engineering
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• 제4권1호
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• pp.19-37
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• 2012

This paper presents the results of analytical and numerical analyses of the effects of performing a pressuremeter test or driving a pile in clay. The geometry of the problem has been simplified by the assumptions of plane strain and axial symmetry. Pressuremeter testing or installation of driven piles has been modelled as an undrained expansion of a cylindrical cavity. Stresses, pore water pressures, and deformations are found by assuming that the clay behaves like normally consolidated modified Cam clay. Closed-form solutions are obtained which allow the determination of the principal effective stresses and the strains around the cavity. The analysis which indicates that the intermediate principal stress at critical state is not equal to the mean of the other two principal stresses, except when the clay is initially isotropically consolidated, also permits finding the limit expansion and excess pore water pressures by means of the Almansi finite strain approach. Results are compared with published data which were determined using finite element and finite difference methods.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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• pp.847-848
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• 2004

We studied a low density 8CB liquid crystal-hydrophobic aerosil dispersions imbedded in submicron-size cylindrical pores. The nanosize spherical aerosil particles are adsorbed at the pore wall and hinder the planar anchoring. The adsorption is temperature dependent, and an axial to radial molecular configuration transition occurs within the cylindrical pores.

• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2553-2559
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• 2012

The adsorption properties of benzene, toluene, p-xylene in MCM-41 with heterogeneous and cylindrical pore were studied using grand canonical ensemble Monte Carlo simulation. The simulated isotherms were compared with experimental ones, and the different adsorption behaviors in MCM-41 with pore diameters of 2.2 and 3.2 nm were investigated. The simulated adsorption amounts above the capillary-condensation pressure agreed with the experimental ones. The simulation results showed that most molecular planes were nearly parallel to the pore axis. This orientation was not affected by the molecular position in the pore. The molecular planes were nearly parallel to the pore surface for the adsorbate molecules close to the pore wall, and the molecules in the MCM-41 with the pore diameter of 3.2 nm were ordered along the pore axis.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2008년도 춘계학술대회 논문집
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• pp.79-83
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• 2008

We carry out three-dimensional simulation of pore closing processes during upsetting in open die forging. Several pores on a plane section of a cylindrical material are traced at the same time and the results of hydrostatic pressure and effective strain are discussed to reveal the parameters affecting pore closing phenomena. Five different sizes of pores are also investigated by simulation to reveal the pore size effect in pore closing during upsetting. AFDEX 3D is employed for this study.

• 한국음향학회지
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• 제21권2호
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• pp.110-119
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• 2002

수중퇴적물의 투과음향특성을 실험실 조건에서 고찰하였다. 물로 포화된 입자지름 0.5 mm이하의 모래퇴적물을 (재질의 두께가 1 mm이고 부피가100mm×100m×42m인 아크릴상자 안에) 형성시켜 수중모래퇴적물 시료를 제작하였다. 수중 모래퇴적물 시료의 다공율을 조절할 수 있도록 퇴적물 내부에 내경 3 mm, 길이 42 mm인 원통형 관들을 이용하여 물로 채워진 관을 위치시켜서, 원통다공율이 각각 0 %, 5%, 11%, 18%, 26%인 다섯 개의 수중 모래퇴적물 시료를 만들었다. 수중 모래퇴적물 시료의 음향특성을 다공율과 0.3 MHz에서 4 MHz의 구간에서 주파수의 함수로 분석하였다. 수중 모래퇴적물 시료를 투과한 음향신호는 시료 전체로부터 나온 첫번째파 (first-kind wave)와 관을 통하여 나온 두번째파 (second-kind wave)를 구분하여 관측하였다. 중심주파수 1 MHz에서는 첫번째파가 지배적이었으나 중심주파수 2.25 MHz에서는 두번째파가 지배적이었다. 첫번째파의 경우, 다공율이 증가되면 음압투과계수는 작아지고 음속은 물의 음속에 가깝게 낮아지며, 주파수가 증가되면 투과계수는 점차 작아지나 음속의 변화는 없었다. 두번째파의 경우, 다공율이 커지면 투과계수가 커지고 음속은 변화가 없었으며, 주파수가 증가되어도 투과계수와 음속의 변화는 없었다.