• Title/Summary/Keyword: cycling performance

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Improving Electrochemical Properties of LiFePO4 by Doping with Gallium

  • Nguyen, Van Hiep;Park, Ju-Young;Gu, Hal-Bon
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.6
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    • pp.320-323
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    • 2014
  • Ga-doped $LiFePO_4$ cathode materials were synthesized using a hydrothermal method. The microstructural characteristics and electrochemical performances were systematically investigated using field emission scanning electron microscopy, high-resolution X-ray diffraction, energy dispersive X-ray spectroscopy, charge-discharge cycling, cyclic voltammetry, and electrochemical impedance spectroscopy. Among the as-prepared samples, $LiFe_{0.96}Ga_{0.04}PO_4$ demonstrates the best electrochemical properties in terms of discharge capacity, electrochemical reversibility, and cycling performance with an initial discharge capacity of $125mAh\;g^{-1}$ and high lithium ion diffusion coefficient of $1.38{\times}10^{-14}cm^2s^{-1}$ (whereas for $LiFePO_4$, these were $113mAh\;g^{-1}$ and $8.09{\times}10^{-15}cm^2\;s^{-1}$, respectively). The improved electrochemical performance can be attributed to the facilitation of Li+ ion effective diffusion induced by $Ga^{3+}$ substitution.

The study on Fabrication and Characterization of $LiMn_{2-x}Cu_{x}O_{4}$for cathode material of Lithium-ion Battery (리튬이온 이차전지 양극활물질 $LiMn_{2-x}Cu_{x}O_{4}$의 제작과 전극특성에 관한 연구)

  • 박종광;고건문;홍세은;윤기웅;안용호;한병성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.713-716
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    • 2001
  • In many papers, the electrochemical analysis of LiMn$_2$O$_4$shows the transition results of Mn$^{3+}$ ion. Charge ordering is accompanied by simultaneous orbital ordering due to the Jahn-Teller effect in Mnl$^{3+}$ ions. To analyze the cycle performance of LiMn$_{2-x}$Cu$_{x}$ O$_4$as the cathode of 4 V class lithium secondary batteries, XRD, TGA analysis were conducted. Although the cycle performance of the LiMn$_{2-x}$Cu$_{x}$ O$_4$was improved from pure LiMn$_2$O$_4$, the discharge capacity was significantly lower than LiCoO$_2$. In this paper, We study the Electrochemical characterization and enhanced stability of Cu-doped spinels in the LiMn$_{2-x}$Cu$_{x}$ O$_4$upon initial cycling.l cycling.

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A Study of the Current State of Cyclist Wear (사이클 전문복 착용실태에 관한 연구)

  • Kim, Eun-Kyong
    • Journal of the Korean Society of Costume
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    • v.60 no.5
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    • pp.88-105
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    • 2010
  • The purpose of this study is to grasp the actual wearing conditions, inconvenience and problems with cycle wear. To attain this purpose, a questionnaire was completed by direct observation and by interviewing bicyclists. The questionnaire was given to 273 bicyclists. The questionnaire consisted of items that are related to concerns with dressing appropriately and enhancement of physical performance through dress. Following are the results of this study. According to the survey, many of them purchased imported cycle wear rather than national cycle wear, and the satisfaction according with purchase rate was low. Bicyclists were uneasy with finding right size cycle wear especially for women. It turned out that the area of the knee and elbow are mostly the areas that they get hurt while riding. Even though the knee and elbow are the mostly hurt area, bicyclists do not prefer to wear appropriate protector for the knee and elbow to excel in their performance in cycling. In material related questions, lower dissatisfaction was indicated for the lints caused by fraction. Average satisfaction was indicated for the distortion after washing, changes in color, touch of the fabric, matters with static and sweat. With regard to the areas where the bicyclists felt discomfort was highly indicated with lower-body clothing. Discomfort was highly indicated with crotch area when riding long period of time. Also when riding a cycle, discomfort was indicated with the leggings cuffs when it comes upward with riding motion. Most of the bicyclists felt the tight fitting leggings were embarrassing.

Experimental Evaluation for Structural Performance of Diagrid BRB Structural System (Diagrid BRB의 실험적 구조성능 평가)

  • Lee, Jong-Hyock;Ju, Young-Kyu;Kim, Young-Ju;Kim, Sang-Dae
    • Journal of Korean Society of Steel Construction
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    • v.22 no.3
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    • pp.261-269
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    • 2010
  • It is now possible to design buildings in various forms using a diagrid structural system, which is the one of the most useful structural systems. It is difficult to design and construct the connections, however, and the bucklings in braces weaken the seismic performance of structures. In this study, the initial stiffness, ductility, and energy-dissipated capacity of a diagrid and a diagrid BRB were evaluated via frame tests. The results of the cycling load tests showed that the diagrid BRB had better initial stiffness and ductility, and dissipated extra energy after the BRBs were yielded.

Synthesis of $LiCoO_2$ by solution route and its behaviour as a cathode material in lithium ion secondary battery (액상반응에 의해 합성한 $LiCoO_2$ 를 정극활물질로 이용한 Li ion 2차전지의 특성)

  • 김상필;조정수;박정후;심윤보;윤문수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.143-146
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    • 1998
  • The $LiCoO_2$ powder was synthesized at >$700^{\circ}C$, >$850^{\circ}C$ by solution route. In this paper, we investigated X-ray diffraction, and charge-discharge performance for $LiCoO_2$/Li and $LiCoO_2$/MPCF cell. The $LiCoO_2$/Li ceSl exhibited a high avmge discharge potential of 38-3% and a good cycle life performance at 5(hnA/g during chargedischarge cycling between 43-3.0V. And, the $LiCoO_2$MPCF cell showed a high average discharge voltage of 3.6-3.W and a excellent cycle life prfomam during chargedischarge cycling b&wm 4 2-2.W. As a result, the $LiCoO_2$ powdm syd-eizd by solution route is a good cathode material for lithium ion secondary battery.

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Charge/discharge Properties of $Li_2O-P_2O-V_2O_5$ Glasses as a Cathode Material for Lithium Rechargeable Battery (리튬 이차전지의 정극 물질로서 $Li_2O-P_2O-V_2O_5$ 유리의 충방전 특성)

  • 송희웅;구할본;손명모;이헌수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.383-386
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    • 1999
  • The importance of rechargeable lithium cells has been emphasized. So a large variety of materials has been discovered and evaluated for use as reversible cathodes and electroyltes. This paper examines the charge/discharge properties and the charge/discharge cycling life of Li$_2$O-P$_2$O-V$_2$O$_{5}$Li cells. In audition, DTA tests were carried out on Li$_2$O-P$_2$O-V$_2$O$_{5}$ glass. As a result the best performance was achieved when 0.3Li$_2$O-0.1P$_2$O$_{5}$-0.6V$_2$O$_{5}$Li cells was mixed with SP270. that is discharge capacity of 240mAh/g have been achieved. In addition this battery exhibited good cycling performance. Considering these results we expected utilization of the Li$_2$O-P$_2$O-V$_2$O$_{5}$ glass as a cathode material in a secondary battery.y battery.

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A novel free-standing anode of CuO nanorods in carbon nanotube webs for flexible lithium ion batteries

  • Lee, Sehyun;Song, Hyeonjun;Hwang, Jun Yeon;Kim, Seung Min;Jeong, Youngjin
    • Carbon letters
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    • v.27
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    • pp.98-107
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    • 2018
  • Free-standing electrodes of CuO nanorods in carbon nanotubes (CNTs) are developed by synthesizing porous CuO nanorods throughout CNT webs. The electrochemical performance of the free-standing electrodes is evaluated for their use in flexible lithium ion batteries (LIBs). The electrodes comprising CuO@CNT nanocomposites (NCs) were characterized by charge-discharge testing, cyclic voltammetry, and impedance measurement. These structures are capable of accommodating a high number of lithium ions as well as increasing stability; thus, an increase of capacity in long-term cycling and a good rate capability is achieved. We demonstrate a simple process of fabricating free-standing electrodes of CuO@CNT NCs that can be utilized in flexible LIBs with high performance in terms of capacity and cycling stability.

Electrochemical properties of $LiCr_xMn_{1-x}O_2$ cathode materials for lithium ion battery (리튬 이온 이차전지용 $LiCr_xMn_{1-x}O_2$ 정극활물질의 전기 화학적 특성)

  • Jin, En-Mei;Jeon, Yeon-Su;Beak, Hyoung-Ryoul;Gu, Hal-Bon;Son, Myung-Mo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.418-419
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    • 2005
  • $\o-LiMnO_2$ is known to have poor cycle performance causing the irreversible phase transformation on cycling. In this paper, the effect of chemical substitution on improving cycle performance of $o-LiMnO_2$ was studied at the compositions of $LiCr_xMn_{1-x}O_2$(x=0, 0.1, 0.2, 0.4). XRD is showed that structure of $LiCr_xMn_{1-x}O_2$ transformed from orthorhombic to spinel according to the increase of substitute degree. For lithium ion battery applications, $LiCr_xMn_{1-x}O_2$/Li cell were characterized electrochemically by charge/discharge cycling.

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Morphology-Controlled WO3 and WS2 Nanocrystals for Improved Cycling Performance of Lithium Ion Batteries

  • Lim, Young Rok;Ko, Yunseok;Park, Jeunghee;Cho, Won Il;Lim, Soo A;Cha, EunHee
    • Journal of Electrochemical Science and Technology
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    • v.10 no.1
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    • pp.89-97
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    • 2019
  • As a promising candidate for anode materials in lithium ion battery (LIB), tungsten trioxide ($WO_3$) and tungsten disulfide ($WS_2$) nanocrystals were synthesized, and their electrochemical properties were comprehensibly studied using a half cell. One-dimensional $WO_3$ nanowires with uniform diameter of 10 nm were synthesized by hydrothermal method, and two-dimensional (2D) $WS_2$ nanosheets by unique gas phase sulfurization of $WO_3$ using $H_2S$. $WS_2$ nanosheets exhibits uniformly 10 nm thickness. The $WO_3$ nanowires and $WS_2$ nanosheets showed maximum capacities of 552 and $633mA\;h\;g^{-1}$, respectively, after 100 cycles. Especially, the capacity of $WS_2$ is significantly larger than the theoretical capacity ($433mA\;h\;g^{-1}$). We also examined the cycling performance using a larger size $WO_3$ and $WS_2$ nanocrystals, showing that the smaller size plays an important role in enhancing the capacity of LIBs. The larger capacity of $WS_2$ nanosheets than the theoretical value is ascribed to the lower charge transfer resistance of 2D nanostructures.

Adhesive Flip Chip Technology

  • Paik, Kyung-W
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2000.10a
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    • pp.7-38
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    • 2000
  • Performance, reliability, form factor drive flip chip use. BGAs and CSPs will provide stepping stone to FC DCA .Growing vendor infrastructure - Low cost, high density organic substrates -New generations of fluxes and underfills .Adhesives flip chip technology as a low cost flip chip alternatives -Low cost Au stud or Electroless Ni bumps -Reliable thermal cycling and electrical performance.

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