• Title/Summary/Keyword: cyclic structure

Search Result 919, Processing Time 0.023 seconds

Synthesis and Spectral properties of meso-porphyrin (meso-Porphyrin의 합성과 분광특성)

  • Lee, Bum-Hoon;Jaung, Jae-Yun
    • Proceedings of the Korean Fiber Society Conference
    • /
    • 2003.10b
    • /
    • pp.100-103
    • /
    • 2003
  • The basic structure of porphyrin consists of four pyrrole units linked by four methine bridges. It reveals that the cyclic 16-atom is the preferred cyclic system for n-electron delocalization since this pathway exhibits the highest degree of bond equalization. Scheme 1 (a) shows the 16-center system is the chromogen of the porphyrins, which allows 18-electron delocalization that could produce aromatic characteristics (1,2). (omitted)

  • PDF

Theoretical Study on Structures and Energetics of Small Water Clusters

  • Park Yeong Jae;Kang Young Kee;Yoon Byoung Jip;Jhon Mu Shik
    • Bulletin of the Korean Chemical Society
    • /
    • v.3 no.2
    • /
    • pp.50-55
    • /
    • 1982
  • A study of small water clusters composed of two to seven molecules has been performed by using the revised empirical potential function for conformational analysis (REPFCA). Various structures of clusters have been investigated and the relative probability of cluster per molecule is discussed. In general, cyclic structures of water clusters are more favorable than open structures. It is found that cyclic pentamer is the most favorable unit structure in the water cluster.

Experimental studies on steel frame structures of traditional-style buildings

  • Xue, Jianyang;Qi, Liangjie
    • Steel and Composite Structures
    • /
    • v.22 no.2
    • /
    • pp.235-255
    • /
    • 2016
  • This paper experimentally investigated the behavior of steel frame structures of traditional-style buildings subjected to combined constant axial load and reversed lateral cyclic loading conditions. The low cyclic reversed loading test was carried out on a 1/2 model of a traditional-style steel frame. The failure process and failure mode of the structure were observed. The mechanical behaviors of the steel frame, including hysteretic behaviors, order of plastic hinges, load-displacement curve, characteristic loads and corresponding displacements, ductility, energy dissipation capacity, and stiffness degradation were analyzed. Test results showed that the Dou-Gong component (a special construct in traditional-style buildings) in steel frame structures acted as the first seismic line under the action of horizontal loads, the plastic hinges at the beam end developed sufficiently and satisfied the Chinese Seismic Design Principle of "strong columns-weak beams, strong joints-weak members". The pinching phenomenon of hysteretic loops occurred and it changed into Z-shape, indicating shear-slip property. The stiffness degradation of the structure was significant at the early stage of the loading. When failure, the ultimate elastic-plastic interlayer displacement angle was 1/20, which indicated high collapse resistance capacity of the steel frame. Furthermore, the finite element analysis was conducted to simulate the behavior of traditional-style frame structure. Test results agreed well with the results of the finite element analysis.

Seismic Performance Test of a Steel Frame with Multi-action Hybrid Dampers (다중거동 복합형 감쇠장치를 적용한 철골골조의 내진성능실험)

  • Roh, Ji Eun;Heo, Seok Jae;Lee, Sang Hyun
    • Journal of the Earthquake Engineering Society of Korea
    • /
    • v.23 no.1
    • /
    • pp.1-8
    • /
    • 2019
  • In this study, the effectiveness of a multi-action hybrid damper (MHD) composed of lead rubber bearing (LRB) and friction pad was verified in terms of seismic performance improvement of a frame structure. The LRB and the friction elements are connected in series, so the LRB governs the intial small deformation and the friction determines large deformation behavior. Cyclic loading tests were conducted by using a half scale steel frame structure with the MHD, and the results indicated that the structure became to have the stable trilinear hysteresis with large initial stiffness and first yielding due to the LRB, and the second yielding due to the friction. The MHD could significantly increase the energy dissipation capacity of the structure and the hysteresis curves obtained by tests were almost identical to the analytically estimated ones.

A coupled simulation of parametric porous microstructure and stress-strain behavior in mechanical components under variable cyclic loads

  • Domen Seruga;Jernej Klemenc;Simon Oman;Marko Nagode
    • Coupled systems mechanics
    • /
    • v.12 no.5
    • /
    • pp.409-418
    • /
    • 2023
  • A coupled algorithm is proposed which first considers the creation of porous structure of the material and then the simulations of response of mechanical components with porous structure to a variable load history. The simulations are carried out by the Prandtl operator approach in the finite element method (FEM) which enables structural simulations of mechanical components subjected to variable thermomechanical loads. Temperature-dependent material properties and multilinear kinematic hardening of the material can be taken into account by this approach. Several simulations are then performed for a tensile-compressive specimen made of a generic porous structure and mechanical properties of Aluminium alloy AlSi9Cu3. Variable mechanical load history has been applied to the specimens under constant temperature conditions. Comparison of the simulation results shows a considerable elastoplastic stress-strain response in the vicinity of pores whilst the surface of the gauge-length of the specimen remains in the elastic region of the material. Moreover, the distribution of the pore sizes seems more influential to the stress-strain field during the loading than their radial position in the gauge-length.

KSTAR Superconducting Magnet Supporting Post Prototype Manufacturing and Structural Load Test (KSTAR 초전도자석 지지각 시작품재작 및 구조시험)

  • 허남일;이영신
    • Progress in Superconductivity and Cryogenics
    • /
    • v.3 no.1
    • /
    • pp.45-49
    • /
    • 2001
  • A magnet supporting post installed between the lower TF coil tooled by 4.5 K supercritical helium and the cryostat base is one of the most important components of the superconducting magnet supporting structure for KSTAR Tokamak. This structure should be flexible to absorb thermal shrink of the magnet and also should be rigid to support the magnet weight and the Plasma disruptions load. The Post was designed with stainless steel 316LN and CFRP that have low thermal conductivity and high structural strength at low temperature. In order to verify the possibility of fabrication and the structural safety. a whole scale prototype of the KSTAR magnet supporting post was manufactured and tested. Static and compressive cyclic load tests under the maximum Plasma vertical disruption load and the magnet dead weight were performed. The teat results showed that the magnet supporting post of KSTAR Tokamak was possible to manufacture and structurally rigid.

  • PDF

Joint Compensation of Transmitter and Receiver IQ Imbalance in OFDM Systems Based on Selective Coefficient Updating

  • Rasi, Jafar;Tazehkand, Behzad Mozaffari;Niya, Javad Musevi
    • ETRI Journal
    • /
    • v.37 no.1
    • /
    • pp.43-53
    • /
    • 2015
  • In this paper, a selective coefficient updating (SCU) approach at each branch of the per-tone equalization (PTEQ) structure has been applied for insufficient cyclic prefix (CP) length. Because of the high number of adaptive filters and their complex adaption process in the PTEQ structure, SCU has been proposed. Using this method leads to a reduction in the computational complexity, while the performance remains almost unchanged. Moreover, the use of set-membership filtering with variable step size is proposed for a sufficient CP case to increase convergence speed and decrease the average number of calculations. Simulation results show that despite the aforementioned algorithms having similar performance in comparison with conventional algorithms, they are able to reduce the number of calculations necessary. In addition, compensation of both the channel effect and the transmitter/receiver in-phase/quadrature-phase imbalances are achievable by these algorithms.

Contact Pressure of Non-Pneumatic Tires with Auxetic Honeycomb Spoke (음의 각을 가지는 허니컴 스포크를 사용한 비 공압타이어의 접지압 분포)

  • Kim, Kwangwon;Kim, Dooman
    • Journal of Aerospace System Engineering
    • /
    • v.4 no.2
    • /
    • pp.1-9
    • /
    • 2010
  • An airless tire has advantages over the conventional pneumatic tire in terms of flat proof and maintenance free. According to the recently disclosed inventions on the airless tire, non-pneumatic tire (NPT) consists of the flexible polygon spokes. Considering the NPT structure, the spokes undergo the tension-compression cyclic loading while the tire rolls. Therefore the spokes of NPT are required to have both stiffness and resilience under the cyclic tensile-compressible loading. In general, if a material has a high stiffness, it shows a low elastic strain limit. In this paper, using the auxetic honeycomb structure with negative poissons's ratio, the spokes of NPT tire are designed to have both stiffness and resilience. Finite element based numerical simulation of the contact pressure of a NPT is carried out with ABAQUS.

  • PDF

Cyclic behavior of DCFP isolators with elliptical surfaces and different frictions

  • Abdollahzadeh, Gholamreza;Darvishi, Reza
    • Structural Engineering and Mechanics
    • /
    • v.64 no.6
    • /
    • pp.731-736
    • /
    • 2017
  • Friction Pendulum isolators are tools developed in the past few decades. The simplest form of these isolators, are FPS whose main disadvantages are having a constant frequency independent of the frequency of the structure. For this reason, researchers have invented VFPI isolator whose frequency is variable and depends on displacement. Another friction pendulum isolator is DCFP isolator which is a combination of two FPS isolators. In this article, first by changing the geometry of DCFP isolator plates from spherical to elliptical, the motion and frequency equations of DVFPI isolators are defined, and then the seismic behavior of DVFPI isolators are analyzed in various geometric and plate friction settings using motion equations, and confirmed using ABAQUS software. The most important results of this study are that the hysteresis behavior of DVFPI isolators are severely nonlinear, its curve follows two distinct curvatures, and that the restoring force is faced with softening mechanism that limits the seismic force transmitted to the structure, whereas the restoring force in DCFP isolators increases linearly with increasing displacement.