• Journal of the Korean Chemical Society
• /
• v.40 no.1
• /
• pp.65-71
• /
• 1996

The chemical behaviour of the Eu(Ⅲ) complexes with organic ligands(tris[3-(trifluoromethylhydroxymethylene-camphorato)]) and tris[3-heptafluoropropylhydroxymethylene-camphorato)] has been investigated by the UV/vis-spectrophotometric, magnetic, and electrochemcial methods. The two or three energy absorption bands are observed by the spectra of these complexes. The magnitude of crystal field splitting energy, the spin pair energy and strength were obtained from the spectra of the complexes. These complexes are found to be delocalization, low-spin state, and strong bonding strenth of electron configuration. The magnetic dipolemoment are found to be diamagnetic. The redox reaction processes of complexes were investigated by cyclic voltammetry in aprotic solvent. The redox reaction processes of complexes are turned out to be single or double reaction with respect to one electron diffusion current.

• Journal of Korean Society of Steel Construction
• /
• v.28 no.6
• /
• pp.415-425
• /
• 2016

Load-bearing steel stud wall system is widely used for the middle-to-high rise modular buildings worldwide. Seismic performance is a key issue to apply load-bearing steel stud wall system to modular buildings in Korea. This study proposes a new strap braced steel stud wall system with enhanced seismic performance and design equations considering the flexural behaviour of the vertical outer studs. For the verification, two specimens with different strap braces and vertical outer stud were designed and tested. The test results showed that the total strengths were evaluated to be 1.11 to 1.18 times higher than the predicted values. Usually strap braced walls are considered to have low energy dissipation capacities. The proposed system showed enhanced seismic performance with equivalent damping of 9.42% due to the reduced pinching effects.

• Journal of Electrochemical Science and Technology
• /
• v.11 no.3
• /
• pp.291-309
• /
• 2020

Chromium was electrodeposited from deep eutectic solvents-based Cr³⁺ electrolytes on HB-pencil graphite electrode. Factors influencing the electrochemical behavior and the processes of Cr nucleation and growth were explored using cyclic voltammetry and chronoamperometry techniques, respectively. Cr³⁺ reduction was found to occur through an irreversible diffusion-controlled step followed by another irreversible one of impure diffusional behaviour. The reduction behavior was found to be greatly affected by Cr³⁺ concentration, temperature, and type of hydrogen bond donor used in deep eutectic solvents (DESs) preparation. A more comprehensive model was suggested and successfully applied to extract a consistent data relevant to Cr nucleation kinetics from the experimental current density transients. The potential, the temperature, and the hydrogen bond donor type were estimated to be critical factors controlling Cr nucleation. The nucleation and growth processes of Cr from either choline chloride/ethylene glycol (EG-DES) or choline chloride/urea (U-DES) deep eutectic solvents were evaluated at 70℃ to be three-dimensional (3D) instantaneous and diffusion-controlled, respectively. However, the kinetics of Cr nucleation from EG-DES was found to be faster than that from U-DES. Cr nucleation was tending to be instantaneous at higher temperature, potential, and Cr³⁺ concentration. Cr nuclei electrodeposited from EG-DES were characterized at different conditions using scanning electron microscope (SEM). SEM images show that high number density of fine spherical nuclei of almost same sizes was nearly obtained at higher temperature and more negative potential. Energy dispersive spectroscopy (EDS) analysis confirms that Cr deposits were obtained.

• Journal of the Korean Chemical Society
• /
• v.40 no.10
• /
• pp.649-655
• /
• 1996

The chemical behaviour of Pt(Ⅱ) and Pd(Ⅱ) complexes with the organic ligand tetramethylenesulfoxide(TMSO) has been investigated by UV/vis-spectrophotometric, magnetic, and electrochemical methods. Two energy absorption bands are observed in the spectra of these complexes. The crystal field splitting energy, spin pairing energy, and bond strength were obtained from the spectra of the complexes. The electronic properties of the complexes are found to be delocalized, and low-spin state. The correlation between ligand and metals were strong bonding strength. These complexes are diamagnetics. The redox reaction processes of the complexes were investigated by cyclic voltammetry in an aprotic solvent. The redox processes of complexes turned out to be respect to one-electrton one step. These complexes were considerably diffusion and reaction controlled.

• Journal of Korean Society of Steel Construction
• /
• v.14 no.1
• /
• pp.51-58
• /
• 2002

To reduce the story height for high-rise buildings, the TEC Beam is developed as a new composite beam composed of structural tee, precast concrete, stirrup, and site-in-cast reinforced concrete slab. The preliminary test of the proposed system was performed for simple beams and it showed a good behavior. However, for the field application of the system, it is required to develope a steel moment resisting connection using steel brackets on which upper rebars of the TEC BEAM are anchored. In this paper, three types of the proposed system are experimentally investigated. The parameters of the test are as follows: (1) the spacing of transverse bars, (2) the ratio of width of rebar's layer to bracket length. Specimens were classified as semi-rigid full strength by the Eurocode 4. It could be concluded that the proposed moment resisting system shows a good structural behavior and may be applicable in the filed.

• Steel and Composite Structures
• /
• v.26 no.6
• /
• pp.793-808
• /
• 2018

In this study, the seismic performance of the connections between L-shaped columns composed of concrete-filled steel tubes (L-CFST columns) and H-beams used in high-rise steel frame structures was investigated. Seven full-scale specimens were tested under quasi-static cyclic loading. The variables studied in the tests included the joint type, the axial compression ratio, the presence of concrete, the width-to-thickness ratio and the internal extension length of the side plates. The hysteretic response, strength degradation, stiffness degradation, ductility, plastic rotation capacity, energy dissipation capacity and the strain distribution were evaluated at different load cycles. The test results indicated that both the corner and exterior joint specimens failed due to local buckling and crack within the beam flange adjacent to the end of the side plates. However, the failure modes of the interior joint specimens primarily included local buckling and crack at the end plates and curved corners of the beam flange. A design method was proposed for the flexural capacity of the end plate connection in the interior joint. Good agreement was observed between the theoretical and test results of both the yield and ultimate flexural capacity of the end plate connection.

• Journal of the Korean GEO-environmental Society
• /
• v.7 no.6
• /
• pp.133-143
• /
• 2006

A fully coupled effective stress dynamic analysis procedure for modeling seismic liquefaction on slope is presented. An elasto-plastic formulation is used for the constitutive model UBCSAND in which the yield loci are radial lines of constant stress ratio and the flow rule is non-associated. This is incorporated into the 2D version of Fast Lagrangian Analysis of Continua (FLAC) by modifying the existing Mohr-Coulomb model. This numerical procedure is used to simulate centrifuge test data from the Rensselaer Polytechnic Institute (RPI). UBCSAND is first calibrated to cyclic direct simple shear tests performed on Nevada sand. Both pre- and post-liquefaction behaviour is captured. The centrifuge test is then modeled and the predicted accelerations, excess porewater pressures, and displacements are compared with the measurements. The results are shown to be in general agreement. The procedure is currently being used in the design of liquefaction remediation measures for a number of dam, bridge, tunnel, and pipeline projects in Western Canada.

• Corrosion Science and Technology
• /
• v.7 no.1
• /
• pp.45-49
• /
• 2008

The cyclic polarisation technique was applied to determine the corrosion, primary-passivation, transpassive, and protection potential of AISI 316L stainless steels immersed in 3550-ppm NaCl solution containing sulfate in the content up to 3000 ppm. The solutions were kept constant at $27^{\circ}C$ and saturated by laboratory air. The solution pH was varied from 3 to 11. Each type of potentials was plotted in function of pH and linked as lines to determine the different zones in the constructed potential-pH diagram. The predominant regimes of the immunity, general corrosion, perfect passivation, imperfect passivation, and pitting corrosion were determined based on those lines of potentials. Comparing to the potential-pH diagram of specimens immersed in the aerated and deaerated 3550-ppm NaCl solutions, the addition of 3000-ppm $Na_2SO_4$ to these solutions increased the overall, perfect and imperfect, passivation regime by shifting the transpassive-potential line to the noble direction. However, it also widened the imperfect passivation area. The addition of $Na_2SO_4$ did not significantly affect the corrosion potential. It was found that the dissolved oxygen tends to negatively shift the transpassive-potential and protection-potential lines at all studied pH. The considerable effect of dissolved oxygen on corrosion and primary-passivation potentials could not be observed.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.17 no.2
• /
• pp.71-82
• /
• 2013

Eight small scale circular reinforced concrete columns (4.5 aspect ratio) were tested under cyclic lateral load with constant axial load. The selected test variables are longitudinal steel ratio (2.017%, 3.161%), transverse steel ratio, and axial load ratio (0, 0.07, 0.15). Volumetric ratio of spirals of all the columns is 0.335~0.894% in the plastic hinge region. It corresponds to 39.7~122.3% of the minimum requirement of confining steel by Korean Bridge Design Specifications, which represent existing columns not designed by the current seismic design specifications or designed by seismic concept. The final objectives of this study are to provide quantitative reference data and tendency for performance or damage assessment based on the performance levels such as cracking, yielding, steel fracture, etc. In this paper, describes mainly failure behavior, strength degradation behaviour, displacement ductility of circular reinforced concrete bridge columns with respect to test variables.

• Journal of the Korean Chemical Society
• /
• v.55 no.1
• /
• pp.50-56
• /
• 2011

The electrochemical reduction of (2,4-difluoro-phenyl)-(2-phenyl-1H-quinolin-4-ylidene)-amine was investigated in 0.1 M tetrabutylammoniumbromide in N,N-dimethylformamide at glassy carbon electrode (GCE) using the technique of cyclic voltammetry at the room temperature (290 K). The reduction of imines occurs in two successive steps, involving one electron in each. In this medium the first peak was observed at about -0.793 V (vs Ag/$Ag^+$) at the glassy carbon electrode surface, which is more stable and well defined as compared to the second peak. The diffusion coefficient ($D_0$) of imine in the investigated solvent media has been calculated using the modified Randles-Sevcik equation. The electron transfer coefficient ($\alpha$) of the reactant species has also been calculated.