• Title/Summary/Keyword: cycle stability

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Hydrolysis of Egg Yolk Protein in a Packed Bed Reactor by Immobilized Enzyme (충진층 반응기에서 고정화 효소에 의한 난황 단백질의 가수분해)

  • Kang, Byung-Chul
    • Journal of Life Science
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    • v.20 no.11
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    • pp.1656-1661
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    • 2010
  • Alkaline protease for the hydrolysis of egg yolk protein was immobilized on five carriers - Duolite A568, Celite R640, Dowex-1, Dowex 50W and Silica gel R60. Duolite A568 showed a maximum immobilization yield of 24.7%. Optimum pH for the free and immobilized enzyme was pH 8 and 9, respectively. However, no change was observed in optimum temperature ($50^{\circ}C$). Thermal stability was observed in immobilized enzymes compared to free enzymes. The immobilized enzyme retained 86% activity after 10 cycle operations in a repeated batch process. The effect of flow rate on the stability of enzyme activity in continuous packed-bed reactor was investigated. Lowering flow rate increased the stability of the immobilized enzyme. After 96 hr of continuous operation in a packed-bed reactor, the immobilized enzyme retained 83 and 61% activity when casein and egg yolk were used as a raw materials, respectively.

Enhancement of Electrochemical Activity of Ni-rich LiNi0.8Mn0.1Co0.1O2 by Precisely Controlled Al2O3 Nanocoatings via Atomic Layer Deposition

  • Ramasamy, Hari Vignesh;Sinha, Soumyadeep;Park, Jooyeon;Gong, Minkyung;Aravindan, Vanchiappan;Heo, Jaeyeong;Lee, Yun-Sung
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.196-205
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    • 2019
  • Ni-rich layered oxides $Li(Ni_xCo_yMn_z)O_2$ (x + y + z = 1) have been extensively studied in recent times owing to their high capacity and low cost and can possibly replace $LiCoO_2$ in the near future. However, these layered oxides suffer from problems related to the capacity fading, thermal stability, and safety at high voltages. In this study, we use surface coating as a strategy to improve the thermal stability at higher voltages. The uniform and conformal $Al_2O_3$ coating on prefabricated electrodes using atomic layer deposition significantly prevented surface degradation over prolonged cycling. Initial capacity of 190, 199, 188 and $166mAh\;g^{-1}$ is obtained for pristine, 2, 5 and 10 cycles of ALD coated samples at 0.2C and maintains 145, 158, 151 and $130mAh\;g^{-1}$ for high current rate of 2C in room temperature. The two-cycle $Al_2O_3$ modified cathode retained 75% of its capacity after 500 cycles at 5C with 0.05% capacity decay per cycle, compared with 46.5% retention for a pristine electrode, at an elevated temperature. Despite the insulating nature of the $Al_2O_3$ coating, a thin layer is sufficient to improve the capacity retention at a high temperature. The $Al_2O_3$ coating can prevent the detrimental surface reactions at a high temperature. Thus, the morphology of the active material is well-maintained even after extensive cycling, whereas the bare electrode undergoes severe degradation.

A Study on the Emulsifying Stability of W/O Type Sunscreen Cream by the Hansen Solubility Parameter (Hansen Solubility Parameter 를 통한 W/O 형 자외선차단 제형의 유화 안정성에 관한 연구)

  • Kim, Dong Hee;Lee, Jin Jae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.47 no.4
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    • pp.273-280
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    • 2021
  • The water resistance is important factor for sunscreen formulations. Generally a sunscreen cream was formulated by a water-in-oil (W/O) emulsion. In the W/O emulsion system, silicone oils are added to improve the texture of formulations. Silicone oils have low compatibility with organic sunscreen agent, causing problems with the stability in emulsion. In this study, the compatibility between various oils in the W/O emulsion was derived numerically using Hansen solubility parameter (HSP) at first. HSP is represented a dispersion degree, a polarity, and a hydrgen bond in a composition. In this study, various emulsions were prepared according to the types of oils with different HSP values and then monitored by a viscosity and morphology according to the time and temperature. The HSP values of components and the experimental results have similar activities for the stability of emulsions. HSP made it easy to select oil with high compatibility. When the compatibility of the oil phase in the W/O emulsion was high, the viscosity change over time was small. The stability was improved under the freeze-thaw cycle (-15 ℃ ~ 45 ℃). In the future, if the composition of the ingredients is optimized through HSP, it is expected that it will be helpful in the development of W/O type sunscreen formulations that are excellent in use and stability.

Stability of fishing vessel according to the LED luring lamp installation (LED집어등 설치에 따른 연안 채낚기 어선의 복원성능)

  • Jeong, Seong-Jae;An, Heui-Chun
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.50 no.4
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    • pp.623-632
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    • 2014
  • In this study, the stability of fishing vessels get some change in accordance with the installation of LED luring lamp in comparison with metal halide luring lamp were investigated. Inclining test for 9.77 ton class of squid jigging and hair-tail angling vessel was performed in order to make a stability evaluation. A performance analysis of the target vessels to the stability on the basis of KST-SHIP program was evaluated. The results were as follows in this study. The stability of the fishing vessel by a metal halide such as LED and the like according to the result obtained by the inclining test is a slightly present difference, and the stability is not affected. The fishing vessel with LED lamp installed satisfies all the stability criteria specified in law and IMO rule. Compared to the metal halide LED lamp the increase of the height of the center of gravity and the initial transverse metacenter was caused. Due to the LED installation, the somewhat wider wind area of the waterline, which appears as a result, does not lead to an actual increase in rolling period. But then it is necessary to be designed on that the LED lamp shape reduces wind pressure area. Because of LED lamp installation, the GM value of vessels is increasing faster rolling cycle so causes a decrease in the sense that the crew is aboard.

EFFECT ON THE COLOR STABILITY OF STAINED PORCELAIN DUE TO TOOTH BRUSHING (잇솔질이 도재의 색 안정성에 미치는 영향)

  • Lee, Im-Gi;Jeong, Jun-Oh;Park, Charn-Woon
    • The Journal of Korean Academy of Prosthodontics
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    • v.40 no.2
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    • pp.172-183
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    • 2002
  • This study is going to compare the degree of color change which occurs in the following two cases of the factors which cause the color change of extra-staining, one is during glazing by the dental technician, the other is tooth brush abrasion which makes the biggest influence on color change. To compare the degree of color change before and after glazing, a sample was made with vintage incisal porcelain No. 59 OPAL(Shofu Inc, Japan), after that it was painted with three colors of porcelain stainers, then the degree of color was measured with a spectrophometer(Model Chromaview 300, Spectoron Tech Co. Korea) after it had been treated with firing only and glazing after firing 40,000-cycle and 80,000-cycle of tooth brush abrasion test were carried out in order to simulate the brushing effect of 4 years and 8 years by using the abrasion tester. The colors were measured before the test, and after the 40,000-cycle and 80.000-cycle operations and the surfaces were examined by SEM. The results of this study were as follows ; 1. The color change before and after glazing was not great enough to have a clinical significance but the orange color was changed more significantly statistically than the blue and light brown(p<0.05). 2. In the case of the color change of stained porcelain by tooth brushing, carrying out staining and glazing with two-times firings resulted in statically less color change than one firing only(p<0.05). 3. In the case of the difference in the stainer's color, the orange color which has higher chroma was statically more sensitive than the blue color(p<0.05) 4. In the case of the color change after the 80,000-cycle abrasion, all showed color change when there was one firing and the orange stainer showed some color change with clinical significance when firings were done two times.

An Experimental Study of Fastening System on CWR(Continuous Welded Rail) Track Stability (장대레일 궤도의 안정성에 미치는 체결장치의 실험적 연구)

  • Kim, Jung-Hun;Han, Sang-Yun;Lim, Nam-Hyoung;Kang, Young-Jong
    • Proceedings of the KSR Conference
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    • 2007.05a
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    • pp.317-324
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    • 2007
  • Until now, the railway has been constructed using track with jointed rails of relatively short lengths to allow thermal expansion in hot summer months. These joints weaken the track structurally and increase track maintenance cost and power consumption of the running train. The CWR(Continuous Welded Rail) Track is the solution of these drawbacks. Although the CWR track not only reduces the track maintenance cost but also increases the life cycle of track components, the stability of the track is highly affected by change of temperatures and vehicle load. A three dimensional nonlinear analysis which considers rail, fastening system and tie has been performed to understand structural behavior of the CWR track. In this case, the translational and rotational stiffness values of fastening system have not been studied. The fastening system makes ties and rails connect. In this study, the stiffness values of various types of fastening systems which consist of clips, rail-pads and insulators are determined by the experiment. The experimental results of the fastening system are compared with the results of parametric study that is performed to investigate the sensitivity of fastening system on stability of CWR track.

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COLOR STABILITY OF CEROMERS AFTER THERMOCYCLING AND BRUSHING (잇솔질과 열처리가 세로머의 색안정성에 미치는 영향)

  • Yi Yang-Jin;Cho Lee-Ra
    • The Journal of Korean Academy of Prosthodontics
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    • v.39 no.1
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    • pp.37-48
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    • 2001
  • Ceromers, new indirect resin system, are now being adopted for esthetic restorations. Despite of its translucency and good color matching, color stability after long-term use was unknown till now. This in vitro study was designed to evaluate color stability of some ceromers when subjected to brushing after thermocycling. Three types of ceromers: Scupture, Targis, Artglass and a direct resin system, Z100 were prepared to disks 12 mm in diameter, 2.5 mm in thickness. All specimens were polished, and Sculpture and Targis specimens were divided two groups, respectively. Then, half of them were glazed according to manufacturer's instructions. All specimen were brushed 20,000 times after 10,000 cycle thermocycling. Color was measured with spectrophotometer after 1,000, 3,000, 10,000 times thermocycling and 20,000 time brushing, respectively. Color difference (${\Delta}E$) was calculated according to CIE LAB system. During thermocycling, Sculpture & Targis system with polished surface showed greater color change than any other groups. After brushing, color difference was reduced significantly. Mean values of ${\Delta}E$ ranged 0.98 to 2.98. All Ceromers were considered clinically acceptable after thermocycling and brushing, and color change mechanism was affected by the brands and finishing methods. It might be concluded that color change of ceromer is due to surface alteration.

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Effect of Pt Layers on the Photoelectrochemical Properties and Stability of a Copper Oxide/n-Si Electrode (Copper oxide/n-Si 전극의 광전기화학 변환 특성과 안정성에 미치는 Pt 층의 영향)

  • 윤기현;홍석건;강동헌
    • Journal of the Korean Ceramic Society
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    • v.37 no.3
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    • pp.263-270
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    • 2000
  • The Pt/copper oxide/n-Si electrodes were fabricated by depositing copper oxide thin film of 500${\AA}$ and very thin Pt layer on the n-type (100) Si substrate. hotoelectrochemical properties and stability profiles of the electrodes were investigated as a function of deposition time of Pt layer. As the deposition time of Pt layer increased up to 10 seconds, the photocurrent and quantum efficiency were increased and then decreased with further depositing time. The better cell stability was observed for the electrode with longer deposition time. The improvements in above photoelectrochemical properties indicate that Pt layer acts as a catalyst layer at electrode/electrolyte interface as well as a protective layer. The decreasing tendency of the photocurrent and efficiency for the electrode with Pt layer deposited above 20 seconds was explained as an increases in probbility of electron-hole pair recombination and also the absorbing photon loss at electrode surface due to the excessive thickness of Pt layer. The results were confirmed by impedance spectroscopy, mutiple cycle voltammograms and microstructural analyses.

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A Study on the Long-Term Integrity of Polymer Concrete for High Integrity Containers

  • Young Hwan Hwang;Mi-Hyun Lee;Seok-Ju Hwang;Jung-Kwon Son;Cheon-Woo Kim;Suknam Lim
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.21 no.3
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    • pp.411-417
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    • 2023
  • During the operation of a nuclear power plant (NPP), the generation of radioactive waste, including dry active waste (DAW), concentrates, spent resin, and filters, mandates the implementation of appropriate disposal methods to adhere to Korea's waste acceptance criteria (WAC). In this context, this study investigates the potential use of polymer concrete (PC) as a high-integrity container (HIC) material for solidifying and packaging these waste materials. PC is a versatile composite material comprising binding polymers, aggregates, and additives, known for its exceptional strength and chemical stability. A comprehensive analysis of PC's long-term integrity was conducted in this study. First, its compressive strength, which is crucial for ensuring the structural stability of HICs over extended periods, was evaluated. Subsequently, the resilience of PC was tested under various stress conditions, including biological, radiological, thermal, and chemical stressors. The findings of this study indicate that PC exhibits remarkable long-term properties, demonstrating exceptional stability even when subjected to diverse stressors. The results therefore underscore the potential viability of PC as a reliable material for constructing high-integrity containers, thus contributing to the safe and sustainable management of radioactive waste in NPPs.

Stability-based On-demand Multi-path Distance Vector Protocol for Edge Internet of Things

  • Dongzhi Cao;Peng Liang;Tongjuan Wu;Shiqiang Zhang;Zhenhu Ning
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.17 no.10
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    • pp.2658-2681
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    • 2023
  • In edge computing scenarios, IoT end devices play a crucial role in relaying and forwarding data to significantly improve IoT network performance. However, traditional routing mechanisms are not applicable to this scenario due to differences in network size and environment. Therefore, it becomes crucial to establish an effective and reliable data transmission path to ensure secure communication between devices. In this paper, we propose a trusted path selection strategy that comprehensively considers multiple attributes, such as link stability and edge cooperation, and selects a stable and secure data transmission path based on the link life cycle, energy level, trust level, and authentication status. In addition, we propose the Stability-based On-demand Multipath Distance Vector (STAOMDV) protocol based on the Ad hoc AOMDV protocol. The STAOMDV protocol implements the collection and updating of link stability attributes during the route discovery and maintenance process. By integrating the STAOMDV protocol with the proposed path selection strategy, a dependable and efficient routing mechanism is established for IoT networks in edge computing scenarios. Simulation results validate that the proposed STAOMDV model achieves a balance in network energy consumption and extends the overall network lifespan.