• Journal of the korean academy of Pediatric Dentistry
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• v.33 no.2
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• pp.221-232
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• 2006

The purpose of this study was to investigate the effect of step-curing mode on polymerization shrinkage and contraction of composite resin restoration. Class I cavities were prepared on the extracted human premolars. The cavities were ailed with Filtek $Z-250^{TM}$ (hybrid resin, 3M ESPE, USA) and Filtek $flow^{TM}$ (flowable resin, 3M ESPE, USA) and cured with one of the following irradiation modes; Halogen 40sec with continuous curing, LED 10sec with continuous curing, and LED 13sec with step-curing. Contraction stress was measured with strain gauge which was connected to TML $Datalogger^{TM}$ (TDS-102, SOKKI, Japan) and resin-dentin interfaces were observed by scanning electron microscope. The results of present study can be summarized as follows : 1. Composite resin restoration showed transient expansion just after irradiation of curing light. Contraction stress was increased rapidly at the early phase of polymerization and reduced slowly as time elapsed (P<0.05) 2. $Filtek\;flow^{TM}$ showed lower contraction stress than Filtek $Z-250^{TM}$ regardless of curing modes. 3. LED step-curing mode showed lowest contraction stress in Filtek $Z-250^{TM}$ compared with other curing modes(P<0.05). 4. LED step-curing mode showed lowest contraction stress in $Filtek\;flow^{TM}$ compared with other curing modes(P<0.05), but difference in contraction stress was not so greate as in $Filtek\;Z-250^{TM}$. 5. Polymerization of composite resin by LED light with step-curing mode and halogen light with continuous ode resulted in better marginal sealing than LED light with continuous mode.

• Journal of Adhesion and Interface
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• v.11 no.2
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• pp.41-49
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• 2010

Furan-containing epoxide monomers (8, 9) were designed and synthesized as carbon-neutral, environment-friendly adhesion material. Bicyclic skeleton were constructed using the Diels-Alder reaction of furan and methyl acrylate, both readily accessible starting material from a biomass via bio-refinery process. After reduction of ester functionality, resulting hydroxyl moieties were coupled to epichlorohydrin to provide the epoxy-functionalized furanic monomers (8, 9). The structure of new furanic monomers was confirmed by $^1H$ and $^{13}C$ NMR spectroscopy. As UV-curable monomers, basic properties such as UV curing time and the extent of UV curing were evaluated by photo DSC. Photo-curing shrinkages were measured by linear variable differential transformer transducer (LVDT) and the effect of molecular structure on shrinkage was considered. In addition, new synthetic compounds showed the shear strength over 3 MPa when they were photo-cured between polycarbonate plates, which indicates these compounds are feasible to use as photo-curable adhesive materials.

• Restorative Dentistry and Endodontics
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• v.25 no.1
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• pp.85-90
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• 2000

For more esthetic treatments the use of composite in molar areas are increasing. But polymerzation shrinkage that cause marginal leakage and cuspal deflection has been the problems of composites. The purpose of this study is to compare the effect of low intensity curing and polishing period on marginal leakage. Cavities were prepared on the buccal or lingual surface of forty five sound extracted human teeth and etching, application of bonding agent and filling of composite was done. Group 1 was light cured at intensity of 600$mW/cm^2$ for 41 seconds and polished. Group 2 was light cured at intensity of 300$mW/cm^2$ for 2 seconds and polished and after polishing it was light cured for 40 seconds at 600$mW/cm^2$. Group 3 was light cured at intensity of 300$mW/cm^2$ for 2 seconds and waited for 5 minutes and after curing at 600$mW/cm^2$ for 40 seconds polishing was done. The specimens were thermocycled at $5^{\circ}C$ and $55^{\circ}C$ for 1000 cycles and immersed in 2% methylene blue solution for 24 hours. Composite-tooth interface was examined under stereobinocular microscope for dye penetration. The results were as follows : 1. Group which were cured at low intensity and polished after curing at high intensity showed less marginal leakage than group which were cured at high intensity for 41 seconds(p<0.05). 2. Marginal leakage between group which were cured at low intensity and polished immediately and group which were cured at high intensity for 41 second were not significantly different. Light curing at low intensity can reduce marginal leakage but polishing immediately after curing at low intensity for short time can affect marginal leakage.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.21 no.1
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• pp.154-163
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• 1997

Thermally-induced deformation in SMC(Sheet Molding Compound) products is analyzed using three dimensional finite element method. Planar fiber orientation, which causes the anisotropic material properties, is calculated through the flow analysis during the compression stage of the mold. Also curing process is analyzed to predict temperature profile which has significant effects on warpage of SMC products. Through the developed procedure, effects of various process conditions such as charge location, mold temperature, fiber contents, and fiber orientations on deformation of final products are studied. and processing strategies are proposed to reduce the warpage and the shrinkage.

• KCI Concrete Journal
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• v.14 no.3
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• pp.93-101
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• 2002

The details of an approach to account for the factors that have been found to affect the ability and the probability to control cracking due to sawcutting in newly constructed concrete pavements are presented. Several factors such as material strength parameters, method and quality of curing, slab and subbase stiffness, and concrete shrinkage affect the probability of crack initiation. Others are relevant to concrete mixture characteristics that affect development of early aged stresses caused by shrinkage and thermally induced contraction. This paper presents the results of a probabilistic analysis of the factors that affect crack control using sawcut notches. Cost analyses on both conventional and early-entry sawcutting methods are shown to support the results of the probabilistic analysis. From both an operational and cost standpoint, it is evident for the environmental conditions considered that early-entry sawcut methodology holds a significant advantage over conventional methods.

• Journal of Powder Materials
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• v.13 no.3 s.56
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• pp.211-216
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• 2006

In an attempt to reduce processing cost and to improve resolution of PDPs, micro mold transfer processing route for barrier ribs of plasma display panel was attempted. In this study, the parameters that may cause defects during the process were identified, which include the shrinkage during UV curing process, stress due to evaporation of organic components, and sintering shrinkage. Considering such parameters, UV curable paste was developed and barrier ribs of PDPs were successfully processed via the process. This work demonstrated the possibility of build-up route in manufacturing barrier ribs of PDP.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.11a
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• pp.433-436
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• 2003

This paper proposes rheological creep and shrinkage model of FCM bridges made for HPC about 40Mpa. The proposed model separates time dependent part with characteristic material part and regards main variable as elastic modulus, which represents material characteristic and history. To find parameters of the model, we had creep, shrinkage and basic material tests about four FCM bridges. All specimens were tested with same condition, after 3days, 28days and 90days of curing. Also, exposed condition and closed condition were separately given to compare the data of each bridge. Finally, all creep data of four FCM bridges were compared to proposed rheological model and other proposed world code models, AASHTO, ACI, CEB-FIP, JSCE and etc.

• 한국정보디스플레이학회:학술대회논문집
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• 2006.08a
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• pp.917-920
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• 2006

In an attempt to reduce processing cost and to improve resolution of PDPs, micro mold transfer processing route for barrier ribs of plasma display panel was developed. In this study, the parameters that may cause defects during the process were identified, which include the shrinkage during UV curing process, stress due to evaporation of organic components, and sintering shrinkage. Considering such parameters, UV curable paste was developed and barrier ribs of PDPs were successfully processed via the process. In addition, the process was successfully applied for the processing of barrier ribs with embedded counter electrodes.

• Proceedings of the Korea Concrete Institute Conference
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• 1995.10a
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• pp.108-112
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• 1995

In this study, the fundamental properties of nonshrinkage high strength concrete using calcium sulphoaluminate cement (CSA cement) which was develiped at the Ssangyong Cement Ind, CO., Ltd. Were considered by some experiments. The concrete using CSA cement show a good workability and higher strength development in early age. And, the resultant compressive strength was also higher than OPC. The drying shrinkage of CSA concrete was much less than that of concrete made with OPC and expansive agent.In addition, the value of drying shrinkage was not dependent on the agitating time and the curing condition. Compared to that of OPC.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.793-798
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• 2003

The purpose of this study is to investigate the setting properties of polystyrene mortars using waste expanded polystyrene(EPS) solution-based binders. The binders for polystyrene mortars are made by mixing crosslinking agent with waste EPS solutions which prepared by dissolving EPS in styrene. Polystyrene mortars are prepared with various EPS concentrations of EPS solutions and crosslinking agent contents, subjected to a dry curing, and tested for working life, peak exotherm temperature and 10h-length change. From the test results, the working lives of polystyrene mortars are shortened with raising EPS concentration of EPS solution and crosslinking agent content. Low-shrinkage or non-shrinkage of polystyrene mortars should be accomplished by adjusting EPS concentration of EPS solution and crosslinking agent content.