• 콘크리트학회논문집
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• 제16권1호
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• pp.54-60
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• 2004

발포폴리스티렌(EPS)의 효율적인 재활용 기술개발의 일환으로서 폐 발포폴리스티렌을 중합성 모노머인 스티렌에 용해한 고분자 용액에 가교제, 개시제, 촉진제 등을 첨가하여 상온 중합성 결합재를 개발하였으며 이를 이용한 폴리스티렌 모르타르를 제조하여 그 중요한 경화특성인 사용가능시간, 건조양생재령에 따른 발열온도 및 길이변화 거동에 미치는 폐 발포폴리스티렌 용액농도 및 TMPTMA 첨가량의 영향에 대해서 검토하였다. EPS용액을 이용한 결합재 및 폴리스티렌 모르타르의 사용가능시간은 EPS용액 농도 및 TMPTMA 첨가율의 증가에 따라서 짧아지며, 또한 폴리스티렌 모르타르의 경화에 따른 길이변화는 EPS용액 농도 및 TMPTMA 첨가율에 크게 영향을 받는데 이를 적절히 조절하여 경화특성을 제어함으로써 저수축 혹은 무수축 폴리스티렌 모르타르의 제조가 가능하다는 것을 검증하고 있다.

• Composites Research
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• 제18권4호
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• pp.14-20
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• 2005

방향족아민 경화제의 벤젠링 사이의 관능기 변화가 반응특성, 기계적특성 및 열적특성에 미치는 영향을 고찰하기 위하여 범용 에폭시수지인 DGEBF와 방향족아민 경화제 DDM, DDS 각각을 1:1의 당량비로 혼합하여 동일한 조건으로 경화하였다. 그 결과 에폭시수지 경화물의 특성은 경화제의 벤젠링 사이의 관능기 구조에 따라 매우 큰 영향을 받았다. 즉, 벤젠링 사이에 길이가 길고 bulky한 술폰기를 포함한 DDS는 반응성, 열안정성, 밀도, shrinkage($\%$), 선팽창계수, 인장탄성율. 인장강도, 굴곡탄성율, 굴곡강도의 값이 벤젠링 사이에 메틸기를 가지는 DDM 경화물계 보다 높게 나타났지만, epoxide기의 전환율, 유리전이온도의 값은 낮게 나타냈다. 이것은 술폰기의 강한 전기음성도와 메틸기의 전기 양성적인 repulsive한 성질의 차이에 의한 영향인 것으로 판단된다. 굴곡 파단면의 관찰 결과는 DDS 경화물계의 각개 grain이 불규칙적으로 분포되어 있음을 확연하게 보여준다.

• Composites Research
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• 제14권6호
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• pp.47-58
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• 2001

This paper describes applications of cure monitoring techniques by using embedded fiber optic strain sensors, which are extrinsic Fabry-Perot interoferometric (EFPI) and/or fiber Bra99 grating (FBG) sensors, to three kinds of molding methods of autoclave, FW and RTM molding methods. In these applications, internal strain of high-temperature curing resin was monitored by EFPI sensors. From theme experimental results, it was shown that strain caused by thermal shrink at cooling stage could be measured well. In addition, several specific matters to these molding methods were considered. As thor an autoclave molding of unidirectional FRP laminates, it was confirmed that off-axis strain of unidirectional FRP could be monitored by EFPI sensors. As for FW molding using room-temperature (RT) cured resin, it was found that the strain outputs from EFPI sensors represented curing shrinkage as well as thermal strain and the convergence meant finish of cure reaction. It was also shown that this curing shrinkage should be evaluated with consideration on logarithmic change in stiffness of matrix resin. As for a RTM melding, both EFPI and FBC sensors were employed to measure strain. The results showed that FBG sensors hale also good potential for strain monitoring at cooling stage, while the non-uniform thermal residual strain of textile affected the FBG spectrum after molding. This study has proven that embedded fiber optic strain sensors hale practical ability of cure monitoring of FRP. However, development of automatic installation methods of sensors remains as a problem to be solved for applications to practical products.

• 대한치과기공학회지
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• 제42권3호
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• pp.208-212
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• 2020

Purpose: This study aimed to analyze the shrinkage and expansion strain of ultraviolet (UV)-cured resin according to the wavelength of the light source and compare the shrinkage and expansion. Methods: We prepared the mold with according to the ISO 4049 specimen. The size of the circle in the mold was prepared with a height of 6.02 mm and a diameter of 4 mm. UV-curable resin for three-dimensional (3D) printing was injected into the circular mold. The control group was irradiated with a wavelength of 400~405 nm using UV-curing equipment (400 group), and the experimental group was irradiated with a wavelength of 460~465 nm (460 group). Both groups were produced ten specimens. The produced specimen was first measured with a digital micrometer. After the first measurement, the specimen was immersed in a constant temperature water bath for 15 days, after which the second measurement was performed, and the third measurement was taken after 30 days. The measured values were analyzed using the independent sample t-test (α=0.05). Results: In the non-immersion water tank, the contraction was 0.9% in the 400 group and 1.3% in the 460 group. In the constant temperature bath, the expansion was high at -0.4% in the 400 group for 15 days, and the smallest expansion was -0.03% for the 400 group for 30 days. There were significant differences between the two groups (p<0.05). Conclusion: The 400 group had a lower UV resin specimen strain than the 460 group. Therefore, it is recommended to use the wavelength required by the UV-curing resin.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2006년도 추계 학술논문 발표대회 논문집
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• pp.5-8
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• 2006

This study investigates the field application, Songdo the # 1st WORLD, on zero-crack construction of the fundamental mass concrete using double bubble sheets and applying low heat mixture. Experimental results of hydration heat analysis showed that crack modulus of concrete incorporating 20% of blast furnace slag cement was 1.0 in 120 hours, representing 50% probability of crack occurrence, thus requiring additional measures. As for a curing method, a specimen insulating two layers of vinyl chloride+double bubble sheets exhibited only $16.5^{\circ}C$ difference between upper and lower sections, and it also showed favorable workability as well as competitive economic side. Therefore it was determined to use it for curing method in this field. For the curing results of practical field, using 2 layers of vinyl chloride+double bubble sheets and applying low heat mixture on the fundamental mass concrete in 3A residential building exhibited less than only $15^{\circ}C$ difference between surface and center section of that in 5 days elapse and less than $20^{\circ}C$ in 9 days. This means that the crack by hydration heat was prevented, and other fields structures also resisted the plastic shrinkage by insulating the vinyl, sinking crack by second temping, even drying shrinkage by the mixture of low unit water. Therefore the crack on the placement has not been found so far, since the construction was started before 6 month.

• 한국건축시공학회지
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• 제18권3호
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• pp.251-257
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• 2018

여름철 콘크리트는 수분증발에 의한 소성 및 건조수축균열, 슬럼프 저하, 콜드조인트 발생 등 다양한 문제가 발생한다. 이에 국내에서는 수분증발을 방지하고, 단열성능을 확보하기 위해 표면피복 양생을 위한 다양한 형태의 버블시트를 제작하여 사용하고 있으나, 여름철에는 적용사례가 없었다. 따라서 본 연구에서는 여름철 시공중인 아파트 현장에 1중의 투명, 백색 및 알루미늄 증착 버블시트와 PE필름 및 표면노출의 5가지 표면피복 양생재를 적용하여 콘크리트의 온도 및 균열특성 등 품질에 미치는 영향을 분석하였다. 실험결과 알루미늄 증착 버블시트가 온도저감, 균열저감 면에서 가장 뛰어난 것으로 나타났지만, 알루미늄 재질의 특성상 빛이 반사되어 시공자의 눈부심에 따른 시각공해가 발생하기 때문에 백색 버블시트의 사용이 가장 효과적인 것으로 밝혀졌다.

• 콘크리트학회논문집
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• 제12권1호
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• pp.79-88
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• 2000

Usually, the expansive additives is used to prevent the occurrence of drying shrinkage in concrete. However it may sometimes be over-added in field due to the insufficient cognition of constructor's, which may cause the serious problems in concrete structures. In this study the experiments are performed to present the expansion properties of concrete by varying the water to binder ratios, unit contents of expansive additives and curing conditions. By the results, the strength showed an increase with the addition of expansion additives from 30kg/㎥ up to 50kg/㎥, and a great decrease by contraries if the larger amount are added. Also the more the expansion additives were used, the more length change occurred in concrete. In view of the curing conditions, the concrete by air cured appeared a little expansion even the unit expansion additives increased, which showed an opposite inclination of that with standard curing. This could be explained by the less occurrence of hydration in air condition which also lead to the little expansion of concrete. Hence the expansion concrete to be cured in water or moisture condition became an especial important thing. concrete using expansive additives showed that high expansion was taken place with the rise of temperature.

• 한국건축시공학회지
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• 제14권1호
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• pp.110-117
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• 2014

본 연구에서는 양생온도변화에 따른 자기수축의 예측을 위하여 FA 및 SF를 치환한 시멘트모르타르를 대상으로 자기수축변화를 측정하고 이를 등가재령방법으로 해석하고자 하였다. 이를 위해 수화반응의 온도민감도를 고려하는 Ea의 변화에 따라 지수함수모델을 이용하여 자기수축 해석을 실시하였는데, 경화단계의 $E_a$를 이용할 경우 응결단계의 $E_a$를 사용한 경우보다 정확한 해석이 가능한 것으로 나타났는데, 이는 경화의 전단계에 걸친 수화의 온도민감도 영향을 반영한 $E_a$값에 기인된 결과로 사료된다.

• 한국농공학회지
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• 제16권4호
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• pp.3545-3554
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• 1974

The objective of this study was to investigate the characteristics of the evaporation rate, the plastic shrinkage and the compressive strength of concrete exposed to a rapid evaporation environment immediately after casting. Drying of concrete were conducted under a controlled chamber in which the temperature was mainfoimed at 30 ${\pm}$1$^{\circ}C$, the relative humidity 22 ${\pm}$1 percent, and the wind velocity 7 ${\pm}$1 m/sec. The compressive strength of concrete was tested after 28 days of standard curing. The results obtained are as follows: 1. The evaporation rate was the highest at the very beginning, was decreased as the drying progresses, and was kept almost constant after 6 hours. 2. The shrinkage of concrete was changed in three different rates for the concrete mixture having its slump vallue between 3.0cm and 7.5cm. 3. The plastic shrinkage was ended within 5 or 6 hours after casting, regardless of the water cement ratio. 4. The shrinkage was increased within the limit of slump values between 3.0cm and 7.5cm as the water-cement ratio was increased. 5. The evaporation was kept on even after the plastic shrinkage was ended. 6. Within the limit of good workability (slump value between 4.5cm and 7.5cm), the compressive strength of concrete was increased when the shrinkage rate was slow but it was decreased when the rate was rapid 7. From the result of this study it is recommended that (1) the water-cement ratio should be less as long as the workability of concrete is allowable; (2) the evaporation should be prevented at least for 4 hours after casting concrete.

• 대한토목학회논문집
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• 제26권4A호
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• pp.795-808
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• 2006

이 논문에서는 참고문헌(곽효경 등, 2004; 곽효경 등, 2005)에서 제안된 소성수축균열 해석모델을 바탕으로 분할타설되는 콘크리트 슬래브의 소성수축균열 해석방법을 제안하였다. 이 해석방법을 이용해 슬래브의 분할타설이 소성수축균열에 미치는 영향에 대해 알아보았고 분할타설방법에 따른 소성수축균열 발생 특성을 정량적으로 분석하였다. 나아가 콘크리트 배합과 외기조건 및 분할타설방법을 변수로 하여 수행한 소성수축균열 해석으로부터 얻어진 해석결과를 바탕으로 슬래브의 표면 건조시기와 먼저 타설된 콘크리트의 표면 건조를 방지하기 위한 임계 타설시간간격에 대한 모델식을 제안함으로써 슬래브에 소성수축균열이 발생하지 않도록 분할타설방법을 계획하거나 소성수축균열의 제어를 위해 적절한 시기에 양생을 시작할 수 있도록 하였다.