• Journal of the Korean Society for Precision Engineering
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• v.28 no.2
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• pp.219-225
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• 2011

Silicone resin is recently used as encapsulant for high-power LED module due to its excellent thermal and optical properties. In the present investigation, finite element analysis of cure process was attempted to examine residual stress evolution behavior during silicone resin cure process which is composed of chemical curing and post-cooling. To model chemical curing of silicone, a cure kinetics equation was evaluated based on the measurement by differential scanning calorimeter. The evolutions of elastic modulus and chemical shrinkage during cure process were assumed as a function of the degree of cure to examine their effect on residual stress evolution. Finite element predictions showed how residual stress in cured silicone resin can be affected by elastic modulus and chemical shrinkage behavior. Finite element analysis is supposed to be utilized to select appropriate silicone resin or to design optimum cure process which brings about a minimum residual stress in encapsulant silicone resin.

• Restorative Dentistry and Endodontics
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• v.35 no.2
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• pp.125-133
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• 2010

Objectives: Rapid polymerization of overlying composite resin causes high polymerization shrinkage stress at the adhesive layer. In order to alleviate the shrinkage stress, increasing the light intensity over the first 5 seconds was suggested as an exponential curing mode by an LED light curing unit (Elipar FreeLight2, 3M ESPE). In this study, the effectiveness of the exponential curing mode on reducing stress was evaluated with measuring microtensile bond strength of three adhesives after the overlying composite resin was polymerized with either continuous or exponential curing mode. Methods: Scotchbond Multipurpose Plus (MP, 3M ESPE), Single Bond 2 (SB, 3M ESPE), and Adper Prompt (AP, 3M ESPE) were applied onto the flat occlusal dentin of extracted human molar. The overlying hybrid composite (Denfil, Vericom, Korea) was cured under one of two exposing modes of the curing unit. At 48h from bonding, microtensile bond strength was measured at a crosshead speed of 1.0 mm/min. The fractured surfaces were observed under FE-SEM. Results: There was no statistically significant difference in the microtensile bond strengths of each adhesive between curing methods (Two-way ANOVA, p > 0.05). The microtensile bond strengths of MP and SB were significantly higher than that of AP (p < 0.05). Mixed failures were observed in most of the fractured surfaces, and differences in the failure mode were not observed among groups. Conclusion: The exponential curing method had no beneficial effect on the microtensile dentin bond strengths of three adhesives compared to continuous curing method.

• Polymer(Korea)
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• v.28 no.5
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• pp.426-432
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• 2004

To reduce volumetric shrinkage of the commercially available polymeric dental composite during curing reaction, (2,2-bis [4-(2-hydroxy-3-methacryloyloxy propoxy) phenyl] propane) (bis -GMA) derivatives, i.e., (2,2-bis[3-methyl, 4-(2-hydroxy-3-methacryloyloxy propoxy) phenyl] propan) (DMBis-GMA) and (2,2-his [3,5-dimethyl ,4- (2-hydroxy-3-methacryloyloxy propoxy) phenyl] propane) (TMBis-GMA) were synthesized and then new dental composite resin composed of Bis-GMA derivatives, diluent, spiro orthocarbonate (SOC), and inorganic filler was produced. Among the Bis-GMA derivative/Bis-GMA derivative/diluent mixtures, Bis-GMA/ TMBis-GMA/TEGDMA mixture exhibited the lowest volumetric shrinkage. Volumetric shrinkage of this mixture was further reduced by adding SOC. Volumtric shrinkage of dental composite prepared from commercially available resin monomer mixture was $2.5\%$, while that prepared from resin monomer mixture having minimum volumetric shrinkage was reduced to $0.7\%$. Mechanical strength of this dental composite was nearly the same with that of commercial products but the time required for the curing reaction was retarded.

• Journal of the Korea Concrete Institute
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• v.16 no.5 s.83
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• pp.621-626
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• 2004

The use of blast-furnace slag (BFS) in making not only normal concrete but also high-performance concrete has several advantages with respect to workability, long-term strength and durability. However, slag concrete tends to show more shrinkage than normal concrete, especially autogenous shrinkage. High autogenous shrinkage would result in severe cracking if they are not controlled properly. Therefore, in order to minimize the shrinkage stress and to ensure the service life of concrete structures, the autogenous shrinkage behavior of concrete containing BFS should be understood. In this study, small prisms made of concrete with water-binder (cement+BFS) ratio (W/B) ranging from 0.27 to 0.42 and BFS replacement level of $0\%$, $30\%$, and $50\%$, were prepared to measure the autogenous shrinkage. Based on the test results, thereafter, material constants in autogenous shrinkage prediction model were determined. In particular, an effective autogenous shrinkage defined as the shrinkage that contributes to the stress development was introduced. Moreover, an estimation formula of the 28-day effective autogenous shrinkage was proposed by considering various W/B's. Test results showed that autogenous shrinkage increased with replacement level of BFS at the same W/B. Interestingly, the increase of autogenous shrinkage is dependent on the W/B at the same content of BFS; the lower W/B, the smaller increasing rate. In concluding, it is necessary to use the combination of other mineral admixtures such as shrinkage reducing admixture or to perform sufficient moisture curing on the construction site in order to reduce the autogenous shrinkage of BFS concrete.

• The Journal of Engineering Research
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• v.8 no.1
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• pp.31-50
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• 2006

Shrinkage may cause cracking in concrete. In practice such cracking must be considered in most concrete applications because, under normal conditions, drying of the concrete is unavoidable, and when drying takes place shrinkage occurs. Cracked concrete is an inferior concrete because it is weaker, more permeable, and more susceptible to chemical attack. The development of the strength of LAC with aging depends on a few factors such as type of the cement, W/C ratio, curing conditions and periods. The higher the strength of LAC, the lower the possibility of shrinkage cracking. Hence, the strength of LAC in the hypocaust system depends to a large extent on the effect of cracking decrease of the antifoaming rate to drying shrinkage in cement.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.857-860
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• 2008

This study shows systematic procedures for investigating creep and shrinkage properties of 50, 60, 70 MPa concrete mixes, which were developed by Lotte E&C R&D Ins. for Lotte Super Tower Jamsil. The concrete test was performed both local and foreign laboratory, S-Lab. and CTL Group respectively. The former have done for total five days. The procedures included the followings, specimen fabrication, mold removal, specimen marking, water bath curing, packaging, and shipment. The latter has been doing by CTL within PCA(Portland Cement Association). They are testing on static and dynamic modulus of elasticity, compressive strength, creep & shrinkage, splitting tensile strength. In the case of creep and shrinkage, the test will be doing for 18 months according to each loading age.

• Composites Research
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• v.31 no.6
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• pp.404-411
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• 2018

As the autoclave process progresses in a given cure cycle, residual stress in the composite product is induced by cure shrinkage of the resin. As a result, It generates the thermal deformation such as spring-in and warpage, and the inaccuracy of the final product increases. It is important to predict thermal deformation in aerospace parts which require precise fabrication. The research has been done on predicting and grasping curing process of composite material. In this study, the cure mechanism of composite materials according to the process is predicted through finite element analysis, and the effect of cure shrinkage on thermal deformation generated by the process is analyzed.

• Journal of Technologic Dentistry
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• v.42 no.2
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• pp.113-120
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• 2020

Purpose: This study is to compare and analyze the shrinkage of the specimen after UV irradiation of UV cured resin at 5, 15, and 30 minutes. Methods: A cylindrical UV cured specimen was produced using a stainless steel mold. UV cured resin specimens were prepared in three groups: 5 minutes cured (5M), 15 minutes cured (15M), and 30 minutes cured (30M). The measurement was made in total 3rd. The measurement was made in total 3rd. The primary measurement was made after 24 hours using a digital measuring instrument. The 2nd and 3rd measurements were deposited in a constant temperature water bath and the shrinkage was measured. The measured data was calculated by referring to the ASTM C326 linear measurement calculation method. T-test and One-way ANOVA were performed to test the significance between groups. The post-test was conducted with Tukey (α=0.05). Results: When the inner diameter and the outer diameter of the three groups not placed in the water bath were compared and analyzed, the contraction was the smallest at 6.8% in the 5M group, and the contraction was the largest at 7.3% in the 30M group. In the outer diameter, the contraction of the 5M group was the smallest at 3.5%, and the contraction of the 30M group was the largest at 4.5%. Shrinkage decreased in all three groups immersed in a water bath for 3-7 days. Conclusion: In the UV cured resin specimen, the shrinkage increased as the amount of UV irradiation increased.

• Composites Research
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• v.30 no.6
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• pp.393-398
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• 2017

The shrinkage distribution of a dental composite (Clearfil AP-X, Kuraray, Japan) used for dental restoration was observed using a digital image correlation method. In order to analyze the shrinkage distribution formed during and after light irradiation, digital images were taken with different photographing conditions for each period. Optimal photographing conditions during LED irradiation were obtained through a preliminary experiment in which the exposure time was applied from 0.15 ms to 0.55 ms in 0.05 ms intervals. The DIC analysis results showed that the strain was non-uniform. For the initial 20 s of light irradiation the composite resin shrank to the level of 50~60% of the final curing shrinkage. Such large shrinkage amount of the composite resin lump affected the tensile stress concentration near the adhesive region between the composite resin and the substrate.

• Journal of Technologic Dentistry
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• v.43 no.2
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• pp.48-55
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• 2021

Purpose: This study aimed to analyze deformation according to post-curing of complete arch artificial teeth for temporary dentures printed with a digital light processing (DLP) printer. Methods: An edentulous model was prepared and an occlusal rim was produced. The edentulous model and occlusal rim were scanned using a model scanner. A complete denture was designed using a dental computer-aided design, and the denture base and artificial tooth were separated. Ten complete arch artificial teeth were printed using a 3D printer (DLP). Complete arch artificial teeth was classified into the following three groups: a group no post-curing (NC), a group with 10 minutes post-curing (10M), and a group with 20 minutes post-curing (20M). Specimens were scanned using a model scanner. The scanned data were overlapped with the reference data. Statistical analysis was performed using one-way ANOVA analysis of variance, Kruskal-Wallis test, and Mann-Whitney U test (α=0.05). Results: Regarding the overall deviation of complete arch artificial teeth, the NC group showed the lowest mean deviation of 111.13 ㎛ and the 20M group showed the highest mean deviation of 131.03 ㎛. There were statistically significant differences among the three groups (p<0.05). Conclusion: The complete arch artificial tooth showed deformation due to post-curing. In addition, the largest shrinkage deformation was observed at 10 minutes of post-curing, whereas the least deformation was observed at 20 minutes.