• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 춘계학술대회 논문집 유기절연재료 방전 플라즈마연구회
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• pp.44-48
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• 2003

할로겐 난연재료 및 고분자의 연소시 Dioxine의 문제점이 대두되고 있어 유럽국가를 중심으로 할로겐 난연제 사용을 규제하고 있다. 환경과 인체에 대한 안정성을 고려해서 저 유해 가스화, 저 발연화, 저 부식성, 리사이클링 등을 겸비한 제품의 개발로 관심이 모아지고 있는 실정이다. 본 연구에서는 환경친화적인 금속화합(수산화 알루미늄)을 사용하여 연소시 발생할 수 있는 난연성, 무독성, 소연성 등을 함량별로 확인하고 난연재가 증가할수록 취약한 기계적 물성 보완을 위해 moisture cure crosslikable 기술로 케이블절연 및 자켓 피복층 특성을 증가 시켰다. 그러나 수산화알루미늄 함량이 증가할수록 기계적 물성과 기타 특성도 감소하는 경향을 보이고 있어 최적의 난연제 조성함량이 약 130~150 phr정도에서 우수한 결과를 확인하였다. 또한 moisture cure agent는 전선압출 시 표면에 scorch 및 장기 압출에 영향을 주므로 약 1.5~2phr 범위에서 처방하는 것이 우수하다. 원료투입 후 mixing 공정 중에서는 온도관리가 매우 중요하므로 되도록 믹싱 온도를 $130^{\circ}C$ 이하를 유지해야한다. 온도는 수산화알루미늄의 분산성과 케이블 피복압출 시 표면에도 영향을 주기 때문이다 본 연구는 이런 작업방법을 통해 친환경 가교 난연콤파운드가 비(比) 가교된 제품에 비해 특성이 증가되는 것을 입증할 수 있었다.

• 생약학회지
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• 제28권3호
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• pp.112-116
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• 1997

Hibiscus syriacus L. (Malvaceae) is widely distributed over Korean, China, India and Siberia. The dried flower of Hibiscus syriacus is used as a folk medicine for curing of hematochezia, dysentery, obstruction due to wind-phlegm, regurgitation, and vomiting of food, and the dried root bark is used antipyretic, anthelmintic and antifungal agents. From a chloroform extract of root bark of this plant, compound I, II, and III were isolated and the structures were elucidated by various spectroscopic analyses. These compounds were identified as syringaresinol. E-N-feruloyltyramine, and Z-N-feruloyltyramine, respectively and were isolated from this plant for the first time. Compound II and III exhibited lipid peroxidation inhibitory activities with $IC_{50}$ of 15.5 and 28.6 ${\mu}g/ml$, respectively.

• 한국재료학회지
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• 제14권5호
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• pp.322-327
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• 2004

Copper-based leadframe sheets were oxidized in two kinds of hot alkaline solutions to form brown-oxide or black-oxide layer on the surface. The oxide coated leadframe sheets were molded with epoxy molding compound (EMC). After post mold curing, the oxide-coated EMC-leadframe joints were machined to form sandwiched Brazil-nut (SBN) specimens. The SBN specimens were used to measure the fracture toughness of the EMC/leadframe interfaces under mixed-mode (mode I + mode II) loading conditions. Fracture surfaces were analyzed by various equipment to investigate failure path. The results revealed that the failure paths were strongly dependent on the oxide type. In case of brown oxide, hackle-type failure was observed and failure path lay near the EMC/CuO interface with a little inclining to CuO at all case. On the other hand, in case of black oxide, quite different failure path was observed with respect to the distance from the tip of pre-crack and phase angle. Different failures occurred with oxide type is presumed to be due to the difference in microstructure of the oxides.

• Elastomers and Composites
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• 제55권4호
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• pp.306-313
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• 2020

To investigate the reinforcing effects of functional fillers in nitrile rubber (NBR) materials, high-structure carbon black (HS45), coated calcium carbonate (C-CaCO3), silica (200MP), and multi-walled carbon nanotubes (MWCNTs) were used as functional filler, and carbon black (SRF) as a common filler were used for oil-resistant rubber. The curing and mechanical properties of HS45-, 200MP-, and MWCNT-filled NBR compounds were improved compared to those of the SRF-filled NBR compound. The reinforcing effect also increased with a decrease in the particle size of the fillers. The C-CaCO3-filled NBR compound exhibited no reinforcing effect with increasing filler concentration because of their large primary particle size (2 ㎛). The reinforcing behavior based on 100% modulus of the functional filler based NBR compounds was compared by using several predictive equation models. The reinforcing behavior of the C-CaCO3-filled NBR compound was in accordance with the Smallwood-Einstein equation whereas the 200MP- and MWCNT-filled NBR compounds fitted well with the modified Guth-Gold (m-Guth-Gold) equation. The SRF- and HS45-filled NBR compounds exhibited reinforcing behavior in accordance with the Guth-Gold and m-Guth-Gold equations, respectively, at a low filler content. However, the values of reinforcement parameter (100Mf/100Mu) of the SRF- and HS45-filled NBR compounds were higher than those determined by the predictive equation model at a high filler content. Because the chains of SRF composed of spherical filler particles are similarly changed to rod-like filler particles embedded in a rubber matrix and the reinforcement parameter rapidly increased with a high content of HS45, the higher-structured filler. The reinforcing effectiveness of the functional fillers was numerically evaluated on the basis of the effectiveness index (��SRF/��f) determined by the ratio of the volume fraction of the functional filler (��f) to that of the SRF filler (��SRF) at three unit of reinforcing parameter (100Mf/100Mu). On the basis of their effectiveness index, MWCNT-, 200MP-, and HS45-filled compounds showed higher reinforcing effectiveness of 420%, 70%, and 20% than that of SRF-filled compound, respectively whereas C-CaCO3-filled compound exhibited lower reinforcing effectiveness of -50% than that of SRF-filled compound.

• 한국건축시공학회지
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• 제15권5호
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• pp.451-456
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• 2015

본 연구는 시멘트계 바탕 바름재에 사용되는 바닷모래를 대체하기 위한 재료로서 현무암 가공과정에서 발생되는 현무암 석분슬러지를 재활용하기 위해 현무암 석분슬러지를 사용한 경화모르타르의 특성(연도변화, 응결경화, 흡수계수, 건조수축, 그리고 부착강도 실험)을 평가하였다. 현무암 석분슬러지를 사용한 경화모르타르는 콘크리트 바탕 바름재에 사용되는 기존의 보통모르타르의 특성과 유사하거나 좀 더 향상된 성능을 보였다. 그러나, 현무암 석분슬러지를 사용한 경화모르타르는 보통 모르타르보다 재령 8~9일 이후 건조수축이 증가되었고 부착강도는 감소되었다. 그러나 현무암 석분슬러지를 사용한 경우, KS F 4716 '시멘트계 바탕 바름재'에서 요구하는 최소 품질 규준은 만족하였다.

• 대한기계학회논문집A
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• 제21권1호
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• pp.154-163
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• 1997

Thermally-induced deformation in SMC(Sheet Molding Compound) products is analyzed using three dimensional finite element method. Planar fiber orientation, which causes the anisotropic material properties, is calculated through the flow analysis during the compression stage of the mold. Also curing process is analyzed to predict temperature profile which has significant effects on warpage of SMC products. Through the developed procedure, effects of various process conditions such as charge location, mold temperature, fiber contents, and fiber orientations on deformation of final products are studied. and processing strategies are proposed to reduce the warpage and the shrinkage.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회A
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• pp.632-635
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• 2007

Automobile tire has very complicated shape and is composed of rubber, steel cord and ply cord, Tread pattern of tire is very essential for the basic characteristics of tire, such as braking, acceleration and comfortableness. Tire components such as tread, sidewall, and spex are prepared by forcing uncured rubber compound through an extruder to shape during curing process. Because of its complexity of shape, adaptive mesh refinement was used for the analysis of tire tread. Effects of forming variables were evaluated.

• Macromolecular Research
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• 제8권5호
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• pp.209-214
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• 2000

Polyenaminonitriles containing cycloaliphatic and aliphatic units were prepared by interfacial or solution polymerization reaction of p-bis(1-chloro-2,2-dicyanovinyl) benzene (1) with 4-aminobenzyl-amine, 1-(2-aminoethyl)piperazine, 2-(aminomethyl)pyrrolidine and 4-(aminomethyl)piperidine. The chemical structure of the polymers was confirmed through a syntheses of the model compound. The resulting polymers possessed inherent viscosities of 0.29∼0.62 dL/g and they were easily soluble in polar aprotic solvents and common organic solvents. Thermal properties of the polymers such as curability and stability were studied by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and infrared spectroscopy. The polymers exhibited a large exotherm in DSC analyses and underwent a curing reaction around 340-370$\^{C}$ to form insoluble materials. The polymers showed 70-80% residual weight at 600 $\^{C}$ under nitrogen.

• Bulletin of the Korean Chemical Society
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• 제35권11호
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• pp.3299-3302
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• 2014

The In2S3 thin films of tetragonal structure and In2O3 films of cubic structure were synthesized by a spin coating method from the organometallic compound precursor triethylammonium indium thioacetate ($[(Et)_3NH]^+[In(SCOCH_3)_4]^-$; TEA-InTAA). In order to determine the electron mobility of the spin-coated TEA-InTAA films, thin film transistors (TFTs) with an inverted structure using a gate dielectric of thermal oxide ($SiO_2$) was fabricated. These devices exhibited n-channel TFT characteristics with a field-effect electron mobility of $10.1cm^2V^{-1}s^{-1}$ at a curing temperature of $500^{\circ}C$, indicating that the semiconducting thin film material is applicable for use in low-cost, solution-processed printable electronics.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2009년도 춘계 학술대회 제21권1호
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• pp.417-418
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• 2009

해안 및 매립지 구조물은 염화물의 침투로 인해 매입된 철근의 피막파괴로 철근부식이 일어나 콘크리트 구조체에 열화가 급속하게 진행되기 때문에 앞으로의 해안 구조물의 수밀성, 내염해성을 필요로 한다. 따라서 본 연구에서는 내염해성 개선에 효과적인 액상형태의 Si/Al 복합 무기염을 모르타르에 적용하여 시간경과(7, 14, 28, 56일)에 따른 내염해특성을 파악하고자 하였다.