• Title/Summary/Keyword: curing agent

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Variation of Elastic Stiffness of Polydimethylsiloxane (PDMS) Stretchable Substrates for Wearable Packaging Applications (웨어러블 패키징용 Polydimethylsiloxane (PDMS) 신축성 기판의 강성도 변화거동)

  • Choi, Jung-Yeol;Park, Dae-Woong;Oh, Tae Sung
    • Journal of the Microelectronics and Packaging Society
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    • v.21 no.4
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    • pp.125-131
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    • 2014
  • In order to develop stretchable substrates for wearable packaging applications, the variation behavior of elastic modulus was evaluated for transparent PDMS Sylgard 184 and black PDMS Sylgard 170 as a function of the base/curing agent mixing ratio. Both for Sylgard 184 and Sylgard 170, the true elastic modulus evaluated on a true stress-true strain curve was higher more than two times compared to the engineering elastic modulus obtained from an engineering stres-sengineering strain curve, and their difference became larger with increasing the stiffness of the PDMS. Sylgard 184 exhibited a maximum engineering elastic modulus of 1.74 MPa and a maximum true elastic modulus of 3.57 MPa at the base/curing agent mixing ratio of 10. A maximum engineering elastic modulus of 1.51 MPa and a maximum true elastic modulus of 3.64 MPa were obtained for Sylgard 170 at the base/curing agent mixing ratio of 2.

An Experimental Study on Shrinkage of High Strength Concrete with Mineral Admixture (혼화재 사용에 따른 고강도 콘크리트의 수축에 관한 실험적 연구)

  • Lee, Young-Jae
    • Journal of the Korean Society of Industry Convergence
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    • v.13 no.2
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    • pp.99-106
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    • 2010
  • The effects of additive and shrinkage reducing agent on the drying and autogenous shrinkage of high strength concrete are investigated in this study. As results, when the ratio of W/B(low water to binder ratio) increase, the compressive strength is decreased. Comparing with PC(portland cement) concrete, the strength is 2.8%, 3.2% and 3.8% lower respectively than that of PC when concrete mixing ratio is 0.2%, 0.3% and 0.4% in 28 days curing. Drying shrinkage strain of PC concrete showed $-650{\times}10^{-6}$ in 91 days curing. When SR(shrinkage reducing agent) of 0.2%, 0.3% and 0.4% is mixed, the drying shrinkage strains are 21%, 34% and 41% lower than those of PC in 91 days curing. Autogenous shrinkage strain of PC concrete appeared $-480{\times}10^{-6}$ in 56 days curing. When SR of 0.2%, 0.3% and 0.4% is mixed, the autogenous drying shrinkage strain are 12.5%, 19.8% and 33.3% lower than those of PC in 56 days curing. In cases of using the mineral and shrinkage agent or only using a shrinkage reducing agent also appeared same reducing effects for drying shrinkage and autogenous shrinkage.

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Curing Behavior by Rotation Rheometer of Acrylic High-Solid Coatings (아크릴계 하이솔리드 도료의 Rotation Rheometer에 의한 경화거동 연구)

  • Yang, In-Mo;Jung, Choong-Ho;Kim, Tae-Ok;Park, Hong-Soo;Park, Eun-Kyung
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.1
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    • pp.40-48
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    • 2001
  • Curing reaction was carried out with the acrylic resin (ACR) [n-butyl acrylate/atyrene/2-hydroxyethyl methacrylate/acetoacetoxyethyl methacrylate (AAEM)] synthesized before and a curing agent, hexamethoxymethylmelamine (HMMM). With rotational rheometer, the effect of catalysts on curing rate of acrylic resin/melamine was examined. Among the four catalysts used, p-toluene sulfonic acid showed the highest reactivity, and the optimum amount of catalyst was 0.5 phr. It was observed that in the ACR/HMMM curing reaction, gelation point was lowered with the increasing the amount of AAEM and HMMM in the ACR.

Influence of Membrane Forming Compounds for Concrete on Water Retention Properties of Concrete Mortar (콘크리트용 피막 양생제가 시멘트 모르타르의 보습특성에 미치는 영향)

  • Lee, Gun-Cheol;Noh, Sang-Kyun;Cho, Byoung-Young;Kim, Young-Geun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.11a
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    • pp.117-120
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    • 2009
  • It has been gradually increased with the use of resin based membrane forming agent for curing method, which plays a role in protecting moisture evaporation by forming resin membrane at the surface of concrete. In this paper, tests were carried out to examine moisture retention capability of cement mortar applying membrane forming agent. Dosages and types of the membrane forming agent were varied. It is found that sheet curing sealed with the surface of concrete closely has favorable moisture retention capability. However, the application of membrane forming curing method had superiority in moisture retention capability at early stage but at later age, its capability is deteriorated. Hence, further study regarding altering application method was necessary to secure enhanced moisture retention capability.

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Curing Behavior by Rheovibron of Acrylic High-Solid Coatings (아크릴계 하이솔리드 도료의 Rheovibron에 의한 경화거동 연구)

  • Kim, Dae-Won;Hwang, Kyu-Hyun;Kim, Seung-Jin;Wu, Jong-Pyo;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.2
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    • pp.142-152
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    • 2001
  • Acrylic resin(ACR) was blended with a curing agent, hexamethoxymethylmela-mine(HMMM), in which blending ratio was 70:30. The curing behavior was examined using Rheovibron. Cross-linking reaction started at $170^{\circ}C$ in 2 min of reaction and curing was completed in 10 min. It was found that the extent of cross-linking increased with the content of acetoacetoxyethyl methacrylate monomer in the ACR.

Properties of Strength Development Under Various Curing Condition at Early Age of Cement Mortar Using Agent for Enduring Cold Weather (내한성 혼화제를 이용한 시멘트 모르타르의 초기양생 온도변화에 따른 강도증진 특성)

  • Han, Cheon-Goo;Hong, Sang-Hee;Kim, Hyun-Woo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.5 no.2
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    • pp.191-197
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    • 2001
  • In this study, the admixtures for agents for enduring cold weather used widely are collected and applied to cement mortar to analyze the strength development due to variation of curing temperature at early age. The test results show that anti-freezing admixture have some problems due to high chloride content, which may cause the corrosion of reinforcement embedded in concrete. However, the mortar applied by accelerator and another kind of agent for enduring cold weather produced by S company lead to delay of strength development in low temperature. Also, it is clarified that there are no significant problems for cement mortar in strength development due to low temperature if a suitable kind of agent enduring cold weather is used and cement mortar is cured for more than $7.5^{\circ}D.D$ at early age.

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Effects of chemical surface treatment on the shear bond Strength of denture reliners and denture base resin (화학적 표면처리에 따른 의치상 레진과 이장재 간의 전단 결합강도)

  • Choi, Esther;Kwon, Eun-Ja
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.11
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    • pp.5745-5751
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    • 2013
  • The purpose of this study was to evaluate the effect of the surface treatment of MMA and TEGDMA concentration, silane coupling agent on the shear bond strength of denture base resin and denture reliners. Denture base resin surface was treated with MMA and TEGDMA concentration, silane coupling agent. After denture reliners were injected bond strength was measured. The results of MMA and TEGDMA concentration on the shear bond strength of Vertex self curing resin showed that the value of MMA 95% and TEGDMA 5%, MMA 90% and TEGDMA 10%, MMA 80% and TEGDMA 20% groups were higher than that of other group(P<0.05). MMA and TEGDMA concentration on the shear bond strength of Kooliner resin showed that the value of MMA 95% and TEGDMA 5%, MMA 90% and TEGDMA 10% were higher than that of other group(P<0.05). Silane coupling agent on the shear bond strength of Vertex self curing resin and Kooliner showed that the value of MMA 95% and silane coupling agent 5% groups was higher than that of other group(P<0.05). Therefore, we could conclude that appropriate chemical surface treatments are supposed to affect the bond of denture base resin and denture reliners.

Cure Behavior of a DGEBF Epoxy using Asymmetric Cycloaliphatic Amine Curing Agent (비대칭 고리형 지방족 아민 경화제를 이용한 DGEBF 계열 에폭시의 경화 거동)

  • Kim, Hongkyeong
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.200-204
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    • 2008
  • The curing kinetics of diglycidyl ether of bisphenol F (DGEBF) with an asymmetric cycloaliphatic amine curing agent were examined by thermal analysis in both isothermal and dynamic curing conditions. From the residual curing of the samples partially cured in isothermal condition and from the dynamic curing with various heating rates, it was found that there exist two kinds of reactions such as at low temperature and at high temperature regions. It was thus also found that the cure parameters obtained from the isothermal curing kinetic model hardly estimate experimental results for a degree of cure larger than 0.6. The activation energies and frequency factors of these two kinds of reactions were obtained from the dynamic curing experiments with various heating rates. From the curing analysis, it was verified that the total cure kinetics for low degrees of cure is dominated by the cure reaction in the low temperature region.

A Study on the Mechanical Properties of Water Soluble Curing Agent and Epoxy Resins (수용성 경화제에 의한 에폭시 수지의 물성에 관한 연구)

  • Kim, Yong-Ho;Lee, Kwang-Won;Kwak, Young-Chae
    • Elastomers and Composites
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    • v.35 no.1
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    • pp.12-18
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    • 2000
  • With growing concerns of environment and due to strengthening the government regulations on volatile organic compounds(VOC) the coatings industries are developing new technologies to reduce the amount of VOC released from coatings. In this study. a water soluble curing agent of amino-epoxy adduct was synthesized and its structure was identified by FT-IR, GPC and TG/DTA. The mechanical properties of the new curing agent in combination of KER-828 and KER-500 were investigated respectively. As an experimental result, the drying time of KER-828 was faster than that of KER-500 but the adhesion and impact strength of KER-500 was better than that of KER-828.

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