• Proceedings of the KIEE Conference
• /
• 1988.07a
• /
• pp.761-762
• /
• 1988

This paper is to investigate dielectric properties, dielectric breakdown strength, varing of interior organization and gelling point temperature as parameter of post-cure conditions of thermo-setting epoxy resin.

• Journal of Adhesion and Interface
• /
• v.10 no.3
• /
• pp.117-126
• /
• 2009

Epoxy/anhydride systems with silica filler were studied to improve the cure behavior and characteristics. To study the curing process of epoxy/anhydride using DSC and a stress rheometer, it was observed that gelation temperature increased by increasing the thermal rate or in high isothermal conditions, while it was observed that the degree of cure at gelation decreased. Thermal stability of the epoxy/anhydride system showed any increment by increasing silica contents, except slight decrease of weight by containing humidity. The epoxy resin cured with 30% of silica filler decreased coefficient thermal expansion (CTE) about 33% to show $40ppm/^{\circ}C$. Specimens filled with 30 wt% of silica showed 60% increase in storage modulus at $30^{\circ}C$ to show 3909 MPa compared with neat resin to 2,377 MPa. Epoxy/anhydride systems with surface treated silica by silane coupling agent decreased storage modulus.

• Polymer(Korea)
• /
• v.27 no.2
• /
• pp.120-128
• /
• 2003

The effects of catalyst, accelerator and blend composition on the cure behavior of unsaturated polyester resin (UPE), vinyl ester resin (VE) and their blends were studied using differential scanning calorimetry(DSC). The DSC thermograms strongly depend on each variable. The result shows that the small exothermic peak at 115$^{\circ}C$ is due mainly to the UPE component in the UPE/VE blends and the large one at 134~138 $^{\circ}C$ is due mainly to the VE component. The results also indicate that the change of the DSC thermogram measured after each blend was exposed to high temperature 18$0^{\circ}C$ and the fast curing conditions of a few tens seconds provide useful information on understanding the thermal processing of a blend at high speed. The measurements of resin flow time represent that there are three distinct stages of cure in the UPE/VE blends: induction, transition and macro-gelation stages, as similarly reported for UPE by others earlier. The thermal stability and flexural properties of the cured UPE are significantly improved by blending it with the VE, depending on the composition.

• Proceedings of the International Microelectronics And Packaging Society Conference
• /
• 2001.11a
• /
• pp.134-137
• /
• 2001

The cure kinetics of a cycloalipatic epoxy / anhydride / Co(II) system for a no-flow underfill encapsulant, has been studied by using a differential scanning calorimetry(DSC) under isothermal and dynamic conditions over the temperature range of $160^{\circ}C ~220^{\circ}C$. The kinetic analysis was carried out by fitting dynamic/isothermal heating experimental data to the kinetic expressions to determine the reaction parameters, such as order of reaction and reaction constants. Diffusion-controlled reaction has been observed as the cure conversion increases and successfully analyzed by incorporating the diffusion control term into the rate equation. The prediction of reaction rates by the model equation corresponded well to experimental data at all temperature.

• Journal of the Korean Society of Clothing and Textiles
• /
• v.28 no.7
• /
• pp.1029-1036
• /
• 2004

The fragrant fabrics were prepared by treatment with eucalyptus microcapsules. 100% cotton fabric, 100% polyester fabric and 100% wool fabric were used as test specimens. Using pad-dry-cure method, microcapsules were attached on each specimen by acrylic binder under conditions of varying concentration. Surface property, stiffness, and air permeability of fragrant fabrics were evaluated. As increasing concentration of binder, add-on yield was increased. Add-on yield was decreased with increasing laundering cycle, especially in polyester fabric. As the concentration of binder was increased, the properties of stiffness and air permeability were decreased. Also it fumed out that pad-dry-cure method was not suitable to polyester fabric.

• Fibers and Polymers
• /
• v.3 no.2
• /
• pp.60-67
• /
• 2002

In the present study, the fluorescence behavior ova phenylethynyl-terminated imide (LaRC PETI-5) resin, a bismaleimide (BMI) resin, and various LaRC PETI-5/BMI blends with different blend compositions has been characterized as a function of heat-treatment temperature, using a steady-state fluorescence technique with a front-face illumination method far solid-state films. It is observed that there are distinguishable changes in the spectral shape, size, and position of fluorescence with varying heat-treatment temperature in the pure and blend samples. The result is qualitatively explained in terms of charge transfer complex formation as well as microenvironmental change with local mobility and viscosity occurring in the LaRC PETI-5, BMI, and their blends during the cure process. The result also implies that a steady-state fluorescence technique may be a useful tool to understand the processing conditions of polyimides and their blends in the film form on the basis of their thermo-photophysical responses.

• Korean Journal of Optics and Photonics
• /
• v.12 no.6
• /
• pp.460-462
• /
• 2001

We have analyzed the characteristics of IR lens mounting with elastomer and applied the results to the mounting of a silicon lens with diameter 117 mm which is the objective of a thermal imaging system. The elastomer, the 577 primerless silicone adhesive (Dow Corning Co.) which is heat cure type, and the mount material, A16061 are used for our analysis. Theoretical analysis gives the result that the space between lens and mount is required to be more than 250 ${\mu}{\textrm}{m}$ under the operational temperature conditions of -40~+6$0^{\circ}C$.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2006.11a
• /
• pp.465-468
• /
• 2006

This paper investigates the effect of curing conditions on the strength improvement of polymer-modified mortars using epoxy resin with various curing methods. The polymer-modified mortars using epoxy resin are prepared with various polymer-cement ratios, and subjected to standard, hot water, heat cure and autoclave cures. The epoxy-modified mortars are tested for flexural and compressive strengths at desired curing methods. From the test results, the flexural and compressive strengths of the epoxy-modified mortars are hardly improved by the autoclave and hot water cures compared to the ideal cure of $20^{\circ}C$. Among the four types of curing methods, the strengths of the heat cured epoxy-modified mortars is largely improved. Especially, it is obtained in the mortars sealed with PVDC film.

• Textile Coloration and Finishing
• /
• v.2 no.1
• /
• pp.14-20
• /
• 1990

The cotton fabrics were treated with formaldehyde in the presence of zinc nitrate catalyst and urea. The effects of HCHO concentration, urea concentration, catalyst ratio, cure time and cure temperature on the physical properties of fabrics were studied. Cotton fabric finished with HCHO and urea had the lower tensile strength and tear strength than untreated one. These strength losses resulted from tighter oxymethylene crosslinks. The enhanced wrinkle recovery for fabric treated with formaldehyde in the presence of urea was indicative of the formation of urea-formaldehyde polymer. These experimental conditions were set up according to table of orthogonal arrays.

• Tribology and Lubricants
• /
• v.36 no.5
• /
• pp.267-273
• /
• 2020

This study experimentally investigates hydrophobic surfaces fabricated via additive manufacturing. Additive manufacturing, commonly known as 3D printing, is the process of joining materials to fabricate parts from 3D model data, usually in a layer-upon-layer manner. Digital light processing is used to fabricate hydrophobic surfaces in this study. This method uses photo-curable resins and ultraviolet (UV) sources. Moreover, this technique generally has faster shaping speeds and is advantageous for the fabrication of small components because it enables the fabrication of one layer at a time. Two photo-curable resins with different compositions are used to fabricate micro-patterns of hydrophobic surfaces. The resins are composed of a photo-initiator, monomer, and oligomer. Experiments are conducted to determine suitable process conditions for the fabrication of hydrophobic surfaces depending on the type of resin. The most important factors affecting the process conditions are the UV exposure time and slice thickness. The fabrication capability according to the process conditions is evaluated using the side and top views of the micro-patterns observed using a microscope. The micro-patterns are collapsed and intertwined when the exposure time is short because sufficient light (heat) is not applied to cure the photo-curable resin with a given slice thickness. On the other hand, the micro-patterns are attached to each other when the exposure time is prolonged because the over-curing time can cure the periphery of a given shape. When the slice is thicker, the additional curing area is enlarged in each slice owing to the straightness of UV light, and the slice surface becomes rough.