• Title/Summary/Keyword: curable

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Curing and Surface Properties of UV-curable Coating Containing Wax (왁스를 함유한 자외선 경화형 코팅제의 경화 및 표면 물성)

  • Han, A-Ram;Kim, Jong-Gu;Hong, Jin-Who;Kim, Hyun-Kyoung
    • Journal of Adhesion and Interface
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    • v.13 no.1
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    • pp.38-44
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    • 2012
  • Surface properties and curing behavior of UV-initiated photopolymerization with and without wax have been investigated by pendulum hardness, pencil hardness, gloss, photo-differential scanning calorimetry (photo-DSC) and SEM. In addition, the influence of wax type (paraffin wax, PE wax) on the various properties of UV cured films was studied. The results showed that the wax type was the significant factor affecting gloss and surface hardness of UV cured films. Specially, the photo-DSC results showed that ${\Delta}H$ for the UV cured films containing paraffin wax was higher than the corresponding values for the formulation without wax and with PE wax. The observed results clearly demonstrate that the photopolymerization of UV curing with paraffin wax in an air atmosphere is less inhibited by the oxygen compared to UV curing without wax and with PE wax.

Fabrication of Nanopatterns for Biochip by Nanoimprint Lithography (나노임프린트를 이용한 바이오칩용 나노 패턴 제작)

  • Choi, Ho-Gil;Kim, Soon-Joong;Oh, Byung-Ken;Choi, Jeong-Woo
    • KSBB Journal
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    • v.22 no.6
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    • pp.433-437
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    • 2007
  • A constant desire has been to fabricate nanopatterns for biochip and the Ultraviolet-nano imprint lithography (UV-NIL) is promising technology especially compared with thermal type in view of cost effectiveness. By using this method, nano-scale to micro-scale structures also called nanopore structures can be fabricated on large scale gold plate at normal conditions such as room temperature or low pressure which is not possible in thermal type lithography. One of the most important methods in fabricating biochips, immobilizing, was processed successfully by using this technology. That means immobilizing proteins only on the nanopore structures based on gold, not on hardened resin by UV is now possible by utilizing this method. So this selective nano-patterning process of protein can be useful method fabricating nanoscale protein chip.

A New Evaluation Method of UV Curing Process by Using Electrical Properties (전기적 특성을 이용한 UV 경화 프로세스에 대한 새로운 평가방법)

  • Lee, Mun-Hag;Kim, Sung-Bin;Son, Se-Mo;Cheon, Jae-Kee
    • Korean Chemical Engineering Research
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    • v.43 no.3
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    • pp.393-400
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    • 2005
  • A novel evaluation method was investigated for measuring the ability of acid amplification of acid amplifier. The method was based on the measurement of conductivity change by the acid generation according to UV radiation. It was found that the decrease of conductivity was caused by photopolymerization of epoxy monomer during UV curing process of ink film and by the rate of UV curing. In this paper, the novel acid amplifiers were synthesized and measured thermal stability by means of DSC. It was found that mono-type acid amplifiers were more stable than di-type. It was possible to make the dynamical evaluation of the curing rate of UV curable ink in curing process by this method.

Spectroscopic Properties of Er-doped Sulfide Fiber (Er 첨가 황화물계 광섬유의 제조 및 분광학적 특성)

  • Choi, Yong-Gyu;Lim, Dong-Sung;Kim, Kyong-Hon;Park, Se-Ho;Heo, Jong
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.781-786
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    • 2000
  • An Er-doped sulfide fiber was drawn, and its spectroscopic properties were analyzed. Compositions of a 1000 ppmwt Er3+-doped core and an undoped clad were Ge30-Ga1-Asg-S61 and Ge30-As8-S62, in at.%, respectively. Refractive index of the core composition was approximately 0.01 high than that of the clad. In order to enhance the mechanical stability as well as to prevent infiltration of impurity ions such as OH-, an UV-curable polymer was used for the coating. The optical loss of a fiber formed directly from a polymer coated core rod without cladding was ∼15 dB/m at 1.06$\mu\textrm{m}$. In the case of a fiber with core/clad structure, the optical loss was so high that the stimulated emission of erbium fluorescence was not evident. It is believed that presence of inhomogeneous core/clad interface and crystalline aggregates precipitated in the clad region were responsible for the high optical loss. On the other hand, fluorescence characteristics of Er3+ embedded in the core region were more or loss deteriorate compared to fiber preform, which is attributed to the redistribution of the Er ions along with the partial crystallization of the core glass during the fiberization process.

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A Study on the Formation of Air Bubble by the Droplet Volume and Dispensing Method in UV NIL (UV NIL공정에서 액적의 양과 도포방법에 따른 기포형성 연구)

  • Lee, Ki Yeon;Kim, Kug Weon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.9
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    • pp.4178-4184
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    • 2013
  • Nanoimprint lithography (NIL) is an emerging technology enabling cost-effective and high-throughput nanofabrication. Recently, the major trends of NIL are high throughput and large area patterning. UV curable type NIL (UV NIL) can be performed at room temperature and low pressure. And one advantage of UV NIL is that it does not need vacuum, which greatly simplifies tool construction, so that vacuum oprated high-precision stages and a large vacuum chamber are no longer needed. However, one key issue in non-vacuum environment is air bubble formation problem. Namely, can the air bubbles be completely removed from the resist. In this paper, the air bubbles formation by the method of droplet application in UV NIL with non-vacuum environment are experimentally studied. The effects of the volume of droplet and the number of dispensing points on air bubble formation are investigated.

Study on the Hybrid Passivation layer of OLEDs using the Organic/Inorganic Thin Film (유/무기 복합 박막을 이용한 유기발광 소자의 보호층에 관한 연구)

  • Bae, Sung-Jin;Lee, Joo-Won;Lee, Young-Hoon;Kang, Nam-Soo;Kim, Dong-Young;Hwang, Sung-Woo;Kim, Jai-Kyung;Ju, Byeong-Kwon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.04a
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    • pp.78-80
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    • 2006
  • The hybrid thin-film (HTF) passivation layer composed of the Ultra Violet (UV) curable acrylate layer and MS-31 (MgO:$SiO_2$=3:1wt%) layer was adopted in organic light emitting device (OLEO) to protect organic light emitting materials from penetrations of oxygen and water vapors. The results showed that the HTF layer possessed a very low WVTR value of lower than $0.007gm/m^{2+}day$ at $37.8^{\circ}C$ and 100% RH. This value was within the limited range of the sensitivity of WVTR measurements. And the lifetime of the HTF passivated device became almost three times longer than that of the bare device. The HTF on the OLEO was found to be very effective in protect what from the penetrations of oxygen and moisture.

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Electro-Optic Characteristics of Polymer Dispersed Liquid Crystal Cell with Transparent State Initially (초기에 투명한 상태인 고분자 분산형 액정셀의 전기 광학 특성)

  • 김미숙;원해경;송성훈;이명훈;이승희
    • Polymer(Korea)
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    • v.28 no.4
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    • pp.298-304
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    • 2004
  • We fabricated a polymer dispersed liquid crystal (PDLC) cell using LC with negative dielectric anisotropy and UV curable monomer exhibiting transparent state initially (called normally transparent (NT)) and studied the electro-optic characteristics. The NT PDLC cell made with the ratio of LC : monomer = 70/30 wt%, curing temperature of 20 $^{\circ}C$ and strong UV intensity of 198 ㎽/$\textrm{cm}^2$ had high contrast ratio and showed good electro-optic characteristics. In this condition, LC is aligned vertically on the substrate due to the vertical alignment layer and the polymer made with the UV exposure does not influence the alignment of the LC much. Therefore, the transmittance at the zero voltage is very high and the scattering state of the cell is good after applying the voltage because LC with negative dielectric anisotropy tries to align perpendicular to the field. And also, the NT PDLC cell showed better viewing angle characteristics than that in the normally scattering (NS) PDLC.

Compositions for Photosensitive Polymer Resistor Paste Using Epoxy Acrylates (에폭시 아크릴레이트를 이용한 감광성 폴리머 저항 페이스트 조성)

  • Kim, Dong Kook;Park, Seong-Dae;Lee, Kyu-Bok;Kyoung, Jin-Bum
    • Applied Chemistry for Engineering
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    • v.23 no.2
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    • pp.157-163
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    • 2012
  • Using six kinds of epoxy acrylates and a conductive carbon black, photosensitive resistor pastes were fabricated and then their developability in alkaline aqueous solution and the resistance values after thermal curing were evaluated. In order to impart the photocurability by UV exposure and the developability on alkaline solution, epoxy acrylate oligomers with carboxyl group, acrylate monomers, a photoinitiator and so forth were used. In addition, an organic peroxide was added into the paste to get a thermally curable composition. As a result, some of the pastes were not developed depending on the kinds of oligomers and, in the developed pastes, the measured resistance showed the different values depending on their compositions, even though they contain the same amount of carbon black. Finally, the optimum oligomer was selected and then, by adjusting the amount of carbon black, the kind of monomer and the curing temperature, the photosensitive resistor paste composition which showed the sheet resistance of about 0.5 $k{\Omega}/sq.$ could be obtained.

Comparison of Seropositivity to Trichomonas vaginalis between Men with Prostatic Tumor and Normal Men

  • Kim, Jung-Hyun;Moon, Hong-Sang;Kim, Kyu-Shik;Hwang, Hwan-Sik;Ryu, Jae-Sook;Park, Sung-Yul
    • Parasites, Hosts and Diseases
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    • v.57 no.1
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    • pp.21-25
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    • 2019
  • Trichomoniasis is the most common curable sexually-transmitted infection. Most Trichomonas vaginalis-infected men are asymptomatic and can remain undiagnosed and untreated, and this has been thought to result in chronic persistent prostatic infection. Chronic inflammation is regarded as the major factor in the pathogenesis and progression of benign prostatic hyperplasia (BPH) and prostatic cancer (PCa). The aim of this study is to identify seropositivity to T. vaginalis in men with prostate tumors (BPH or PCa) visited to Hanyang University Hospital. A total of 183 men were enrolled between October 2013 and November 2014. They consisted of 139 with BPH (mean age: $64.0{\pm}0.07$) and 44 with prostate cancer (mean age: $73.3{\pm}0.18$). We carried out ELISA to identify the seropositivity to T. vaginalis. Mixed lysate antigen extracted from 8 strains of T. vaginalis was used in the ELISA. Also 58 male outpatients visited to Health Promotion Center in Hanyang University Hospital were evaluated for comparing group. As a results, seropositivity to T. vaginalis in patients with prostatic diseases was 19.7% (BPH: 18.7%, PCa: 22.7%) and it was significantly higher than the 1.7% of the comparing healthy group (P=0.001). Therefore, prostatic tumor showed higher seropositivity against T. vaginalis than normal men. As far as we know, this is the first report about seroprevalence in prostatic tumor in Korea.

ACOX1 destabilizes p73 to suppress intrinsic apoptosis pathway and regulates sensitivity to doxorubicin in lymphoma cells

  • Zheng, Fei-Meng;Chen, Wang-Bing;Qin, Tao;Lv, Li-Na;Feng, Bi;Lu, Yan-Ling;Li, Zuo-Quan;Wang, Xiao-Chao;Tao, Li-Ju;Li, Hong-Wen;Li, Shu-You
    • BMB Reports
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    • v.52 no.9
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    • pp.566-571
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    • 2019
  • Lymphoma is one of the most curable types of cancer. However, drug resistance is the main challenge faced in lymphoma treatment. Peroxisomal acyl-CoA oxidase 1 (ACOX1) is the rate-limiting enzyme in fatty acid ${\beta}$-oxidation. Deregulation of ACOX1 has been linked to peroxisomal disorders and carcinogenesis in the liver. Currently, there is no information about the function of ACOX1 in lymphoma. In this study, we found that upregulation of ACOX1 promoted proliferation in lymphoma cells, while downregulation of ACOX1 inhibited proliferation and induced apoptosis. Additionally, overexpression of ACOX1 increased resistance to doxorubicin, while suppression of ACOX1 expression markedly potentiated doxorubicin-induced apoptosis. Interestingly, downregulation of ACOX1 promoted mitochondrial location of Bad, reduced mitochondrial membrane potential and provoked apoptosis by activating caspase-9 and caspase-3 related apoptotic pathway. Overexpression of ACOX1 alleviated doxorubicin-induced activation of caspase-9 and caspase-3 and decrease of mitochondrial membrane potential. Importantly, downregulation of ACOX1 increased p73, but not p53, expression. p73 expression was critical for apoptosis induction induced by ACOX1 downregulation. Also, overexpression of ACOX1 significantly reduced stability of p73 protein thereby reducing p73 expression. Thus, our study indicated that suppression of ACOX1 could be a novel and effective approach for treatment of lymphoma.