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Compositions for Photosensitive Polymer Resistor Paste Using Epoxy Acrylates  

Kim, Dong Kook (Department of Chemistry & Applied Chemistry, Hanyang University)
Park, Seong-Dae (Department of Chemistry & Applied Chemistry, Hanyang University)
Lee, Kyu-Bok (Korea Electronics Technology Institute)
Kyoung, Jin-Bum (Department of Chemistry & Applied Chemistry, Hanyang University)
Publication Information
Applied Chemistry for Engineering / v.23, no.2, 2012 , pp. 157-163 More about this Journal
Abstract
Using six kinds of epoxy acrylates and a conductive carbon black, photosensitive resistor pastes were fabricated and then their developability in alkaline aqueous solution and the resistance values after thermal curing were evaluated. In order to impart the photocurability by UV exposure and the developability on alkaline solution, epoxy acrylate oligomers with carboxyl group, acrylate monomers, a photoinitiator and so forth were used. In addition, an organic peroxide was added into the paste to get a thermally curable composition. As a result, some of the pastes were not developed depending on the kinds of oligomers and, in the developed pastes, the measured resistance showed the different values depending on their compositions, even though they contain the same amount of carbon black. Finally, the optimum oligomer was selected and then, by adjusting the amount of carbon black, the kind of monomer and the curing temperature, the photosensitive resistor paste composition which showed the sheet resistance of about 0.5 $k{\Omega}/sq.$ could be obtained.
Keywords
photosensitive; thick film; resistor; epoxy acrylate oligomer; carbon black;
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