• Title/Summary/Keyword: crystalline regions

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Studies on Silk Contraction Treated with Neutral Salts (중성염에 의한 견사의 수축작용)

  • Lee, Gwang-Gil;Lee, Yong-U;Nam, Jung-Hui
    • Journal of Sericultural and Entomological Science
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    • v.39 no.1
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    • pp.44-55
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    • 1997
  • This study was carried out to find out the relationship between qualities and contraction phenomenon of silk fibers by treatment of concentrated neutral salts. The contraction effects of silk fibers showed the critical point on the treatment conditions of concentration, temperature and time, among three kinds of neutral salts such as calcium nitrate, calcium chloride and lithium bromide. But, The silk fibers, pretreated with bromide and/or formaldehyde, did not show the contraction upon treating with calcium nitrate. This indicates that tyrosine and serine can be correlated with the contraction reaction because of coupling these amino acids with bromide and formaldehyde. In conclusion, a mechanism for the contraction of silk fiber with highly concentrated calcium nitrate solution is supposed as follows. At the initial stage of ration, the water was penetrated into the amorphous regions and fibers swollen, therefore, the contraction took place mainly in amorphous regions, which have plenty of functional groups with hydroxyl residues. Then, as the calcium nitrate is penetrated into the microfibril, the gydrogen bonds of tyrosine and serine residues and broken and crystalline regions are more and more influenced by increasing concentration of calcium nitrate solution. Microgibrils of crystalline regions become entangled, contracted to linear direction and rearranged to form new stable hydrogen bonds.

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The Effects on the Crystal Structure of LDPE thin film exposed Radiation (방사선이 LDPE박막의 결정구조에 미치는 영향)

  • 강전홍;김한준;유광민;박강식;김종석;한상옥
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.181-184
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    • 2000
  • LDPE pelet is distilled to make 0.5 Wt% solutions and fabricated as LDPE thin film by dropping the solution onto glass substrate, and then annealed the film to be crystalline. The structure is observed as crystalline regions and non-crystalline regions. The crystalline region is exposed at radiation and as the result, there appeared degradation at the total region of the crystal structure. It is considered therefore that radiation exposure at the crystal structure is badly effected on insulation property and lifetime of materials.

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Layout of Long-pass-edge Filter Correspond with the Optical Transmission in Crystalline (수정체 광투과에 대응하는 LPE Filter 설계)

  • Kim, YongGeun
    • Journal of Korean Ophthalmic Optics Society
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    • v.4 no.2
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    • pp.57-63
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    • 1999
  • The optical absorption and transmittance of cow' crystalline were measured by spectrophotometer in the 200~800nm wavelength regions. The optical absorptions of crystalline composed of a high absorption band in the UV-A, UV-B, and appeared the light transmittance edge in the 400nm wavelength region, and completely transmitted without the absorption in the high wavelength regions than 400nm. Also, the optical absorption and transmittance had no temperature dependence. The optical transmittance spectrum of crystalline concord with the thin film structure of $n_0/(0.5H)L(LH)^6(0.5H)/n_s$ and $n_0{\mid}(0.5LH0.5L)^kL/1.25{\mid}4.0$ of long-pass edge filter form. In the artificial crystalline and inter lens layout, long-pass edge filter layout can UV cut off.

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The study of damage regions on the aging conditions of the silk dyeing traditional pigment (전통 염색견의 열화조건에 따른 손상원인 연구)

  • Lee, Hye-Yun;Han, Min-Su;Chung, Yong-Jea;Song, Jeoung-Ju
    • 보존과학연구
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    • s.26
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    • pp.77-101
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    • 2005
  • In ancient times, many kinds of difference inorganic and organic pigment were used as colorants for making objects. This study has proved the damage regions on the aging conditions of the silk dyeing traditional pigment. so whiteness, tensile strength and digital-microscope were measured to examine the state of silk dyeing traditional pigments pretreated under each aging condition. From the result examining the state, all the silk dyeing traditional pigments were best condition at low temperature(-20/RT)and normal condition and damaged at high temperature($60^{\circ}C$) and 2ppm $SO_2$condition and UV condition. As a result of X-ray diffraction analysis of crystalline structure for the silk dyeing traditional pigments, most of specimens have nearly changed crystalline structure despite specimens had each other different conditions and times. Especially, specimens which was passing of 4-8 months have not changed in its crystalline structure. But some specimens like a Unghwang and Seokcheong have a little changed in its intensity in the XRD peak. Consequently, If we want to find out alteration of crystalline structure for the silk dyeing traditional pigments using scientific method according to change of environmental conditions, we must guarantee of equal state and strengthen of environmental conditions in specimen. Additionally, the term of experiment need to belong, and specimens which was experimented and analyzed must be same.

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Low temperature solid phase crystallization of amorphous silicon thin film by crystalline activation

  • Kim, Hyung-Taek;Kim, Young-Kwan
    • Journal of Korean Vacuum Science & Technology
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    • v.2 no.2
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    • pp.97-100
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    • 1998
  • We have investigated the effects of crystalline activation on solid phase crystallization (SPC) of amorphous silicon (a-Si) thin films. Wet blasting and self ion implantation were employed as the activation treatments to induce macro or micro crystalline damages on deposited a-Si films. Low temperature and larger grain crystallization were obtained by the applied two-step activation. High degree of crystallinity was also observed on both furnace and rapid SPC. crystalline activations showed the promotion of nucleation on the activated regions and the retardation of growth in an amorphous matrix in SPC. The observed behavior of two-step SPC was strongly dependent on the applied activation and annealing processes. It was also found that the diversified effects by macro and micro activations on the SPC were virtually diminished as the annealing temperature increased.

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Dislocation Density Propagation adjacent to the Low Angle Grain Boundaries of Polycrystalline Materials (다결정 미세입자 소각입계면에서의 전위밀도 확산)

  • Ma, Jeong-Beom
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.20 no.5
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    • pp.618-622
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    • 2011
  • Specialized large-scale computational finite-element and molecular dynamic models have been used in order to understand and predict how dislocation density emission and contact stress field due to nanoindentation affect inelastic deformation evolution scales that span the molecular to the continuum level in ductile crystalline systems. Dislocation density distributions and local stress fields have been obtained for different crystalline slip-system and grain-boundary orientations. The interrelated effects of grain-boundary interfaces and orientations, dislocation density evolution and crystalline structure on indentation inelastic regions have been investigated.

Numerical Analysis about the Time Characteristics of Space Charge Distribution and Measured Current in LDPE (LDPE에서 공간전하분포와 측정전류의 시간특성에 대한 수치해석)

  • Hwang, Bo-Seung;Park, Dae-Hui;Nam, Seok-Hyeon;Gwon, Yun-Hyeok;Han, Min-Gu
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.9
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    • pp.502-509
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    • 2000
  • In this paper in order to evaluat quantitavely the formation mechanism of space charge and its effects on the conduction characteristics in LDPE we have carried out the numerical analysis on the basis of experimental results of space charge distribution cathode field and current with time which had been simultaneously measured at applied field of 50kV/mm and room temperature. As the models for numerical analysis we employ the Richarson-Schottky theory for charge injection from electrode into LDPE and the band-tail conduction at crystalline regions and the hopping conduction by traps which mainly exist at the interface regions of crystalline-amorphous region for charge transport in LDPE. Futhermore in order to investigate the influence of physical parameters on the time characteristcs of space charge distribution and measured current we have changed the values of trap density activation energies for charge injection and transport and have analyzed their effects.

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Two-dimensional model simulation for reflectance of single crystalline silicon solar cell (단결정 실리콘 태양전지 2차원 모델의 반사율 시뮬레이션)

  • Lee, Sang-Hun;Kang, Gi-Hwan;Yu, Gwon-Jong;Ahn, Hyung-Keun;Han, Deuk-Young
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.237-242
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    • 2012
  • At present, crystalline solar cells take up a significant percentage of the solar industry. The ways of increasing the efficiency of crystalline solar cell are texturing and AR(Anti-Reflection) coating, and the purpose of these technologies is to increase the amount of available light on the solar cell by reducing the reflectivity. The reflectance of crystalline silicon solar cell combined with such technologies will be able to predict using the proposed simulation in this paper. The simulation algorithm was made using MATLAB, and it is a combination of the theories of reflection in textured wafer and in anti-reflection coated wafer. The simulation results were divided into three wavelength band and were compared with actual reflectance measured by a spectrometer. The wavelength band from 300 to 380 was named ultraviolet region and the wavelength band from 380 to 780 is named visible region. Finally, the wavelength band from 780 to 1200 named infrared region. When compared with measured reflection data, the simulation results had a small error from 0.4 to 0.5[%] in visible region. The error occurred in the rest two regions is larger than visible region. The extreme error occurred the infrared region is due to internal reflection effect, but in the ultraviolet region, the rationale on reduction phenomenon of reflectance occurred in small range did not proved. If these problem will be solve, this simulation will have high reliability more than now and be able to predict the reflectance of solar cells.

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Dust Around T Tauri Stars

  • Suh, Kyung-Won;Kwon, Young-Joo
    • Journal of Astronomy and Space Sciences
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    • v.28 no.4
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    • pp.253-260
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    • 2011
  • To reproduce the multiple broad peaks and the fine spectral features in the spectral energy distributions (SEDs) of T Tauri stars, we model dust around T Tauri stars using a radiative transfer model for multiple isothermal circumstellar dust shells. We calculate the radiative transfer model SEDs for multiple dust shells using the opacity functions for various dust grains at different temperatures. For six sample stars, we compare the model results with the observed SEDs including the Spitzer spectral data. We present model parameters for the best fit model SEDs that would be helpful to understand the overall structure of dust envelopes around classical T Tauri stars. We find that at least three separate dust components are required to reproduce the observed SEDs. For all the sample stars, an innermost hot (250-550 K) dust component of amorphous (silicate and carbon) and crystalline (corundum for all objects and forsterite for some objects) grains is needed. Crystalline forsterite grains can reproduce many fine spectral features of the sample stars. We find that crystalline forsterite grains exist in cold regions (80-100 K) as well as in hot inner shells.

Structural Characterization of Silk Fiber Treated with Calcium Nitrate (질산칼슘 처리 농도에 따른 수축견사의 구조특성)

  • 이광길;이용우
    • Journal of Sericultural and Entomological Science
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    • v.39 no.2
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    • pp.186-196
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    • 1997
  • The IR crystallinity index of Calcium nitrate treated silk fiber decreased proportionally to the concentration of calcium nitrate. A partial change of conformation was observed in the concentration of over 46.4-47.6% changing from $\beta$-sheet or to random coil in the crystalline region. This is in coincidence with the result of crystallinity index, which was started to be reduced in the concentration range of 46.4-47.6%. A same trend was observed for the X-ray order factor, birefringence, degree of orientation and surface structure. These structural parameters were remarkably changed on the treatment of silk fibers with concentration of 46.4-17, 6% calcium nitrate. Therefore, it seems that there exists a critical concentration of calcium nitrate in affection the structure and morphology of silk fibers. According to the examination of surface morphology, the fine stripe was observed in the direction of fiber axis at 46.4% concentration. However, the treated concentration was exceeded by 47.6%, the cracks were appeared severely on the fiber surface in the transverse direction as well as fiber axis direction. This result might be related to the tensile properties, specially a tenacity of silk fibers. As a result of quantitative analysis of a dilute acid hydrolysis, three different regions, which are known as a amorphous, semi-crystalline and crystalline region, could be obtained. The hydrolysis rate curves were different with various concentrations of treatment and the relative contents of each region could be calculated.

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