• 제목/요약/키워드: crystal transition

검색결과 628건 처리시간 0.022초

Change in the Order of the Phase Transition in Triglycine Selenate Crystal

  • Song, Yong-Won
    • The Korean Journal of Ceramics
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    • 제6권1호
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    • pp.6-8
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    • 2000
  • The specific heat of a partly deuterated triglycine selenage (DTGSe) crystal under $\gamma$-irradiation was measured. It was shown that $\gamma$-irradiation defects changed the thermodynamic behavior of DTGSe crystal in a small dose region. The order of the phase transition changed from the first to the second at D=0.3 MR.

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$a-In_{2}Se_{3}$ 단결정의 전기전도도 특성 연구 (Electrical Conductivity Properties of the $a-In_{2}Se_{3}$ Single Crystal)

  • 김형곤;김남오;이우선
    • 한국전기전자재료학회논문지
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    • 제14권8호
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    • pp.629-633
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    • 2001
  • Electrical properties of the $\alpha$-In$_2$Se$_3$ single crystals grown by use of the Bridgman technique were examined in the transition temperature range between $\alpha$-phase and $\beta$-phase. $\alpha$-In$_2$Se$_3$ single crystal has ' the rhombohedral structure and lattice constants are a=4.025 $\AA$, c=28.771 $\AA$ in c-axis. The transition temperatures of the stoichiometric $\alpha$-In$_2$Se$_3$ single crystal is 198.8$^{\circ}C$ according to the specimens. The temperature of $\alpha$longrightarrow$\beta$ phase transition decreased but the temperature of $\beta$longrightarrow$\alpha$ phase transition increased as the number of heating-cooling cycle increased.

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Crystal Growth of Transition Metal Ion Doped Rutile

  • Y.M. Yu;Kim, J.Y.;S.J. Jeong
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1998년도 PROCEEDINGS OF THE 15TH KACG TECHNICAL MEETING-PACIFIC RIM 3 SATELLITE SYMPOSIUM SESSION 4, HOTEL HYUNDAI, KYONGJU, SEPTEMBER 20-23, 1998
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    • pp.71-71
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    • 1998
  • Transition metal ions, such as Sc, V, Cr and Fe, doped rutile crystals were grown by Floating Zone method. Growth conditions for high quality of crystals depending on the concentration of doped ions were investigated. Grown crystals were cut and polished to thin wafers, and then various types of defects such as homogeneities, low angle grain boundaries, scattering centers, and oxygen vacancies were analyzed. The effects of transition metal ions on defect formation are discussed. Results and discussions on absorption and fluorescence spectra and electrical properties of grown crystals were also reported.

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액정박막에서의 2차원 상전이 (Two dimensional Phase Transition of Liquid Crystal Film)

  • 정치섭;;김만원
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1993년도 춘계학술대회 논문집
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    • pp.119-121
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    • 1993
  • Two dimensional phase transition and three dimensional propagation of layer structures of liquid crystal film are investigated by using surface second harmonic generation method. We have found a distinctive first order phase transition between a monolayer phase and a stable 3-layer phase of 8CB liquid crystal film.

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표면상변이의 강인력 의존성 : 점유통계를 이용한 정성적 고찰 (On the strong attractive force dependence of the surface phase transition : Qualitative consideration from the occupation statistics)

  • 김철호
    • 한국결정성장학회지
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    • 제7권4호
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    • pp.573-577
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    • 1997
  • 표면상변이 현상은 표면 흡착입자들 사이에 강력한 인력포텐셜이 존재할 경우 일어나는 것으로 알려져 있다. 본 논문에서는 표면상변이 현상의 강인력 의존성을 간단한 점유통계를 이용하여 고찰하였다. 압력이 임계점에 도달하였을 때 표면 결정화가 급속히 진행되는 상변이 효과가 나타났으며, 온도가 증가함에 따라서 상변이가 일어나는 임계압력은 증가하였다. 이러한 결과는 표면상변이 현상에 대한 정성적 고찰로 사료된다.

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SI(superconductor-insulator) Transitions in Bi-superconducting Mixed Crystal Thin Films

  • Park, No-Bong;Yang, Sung-Ho;Park, Yong-Pil
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집
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    • pp.486-489
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    • 2002
  • Temperature(T) dependence of the sheet resistance( $R_{$\square$}$) has been investigated on the c-axis oriented thin films of the (Bi2212/Bi2201) mixed crystal with different molar fractions. The $R_{$\square$}$-T superconducting characteristic deteriorated with reduction of the Bi2212 fraction, and almost disappears at 48 mol% where a superconductor-to-insulator transition took place, with the resistance on the normal state, RN, reaching 4.l㏀ at 80 K. This $R_{N}$ value is close to the universal quantum number, h/(2e)$^2$≡6.5㏀ predicted by the Kosterlitz-Thouless(KT) transition theory. The $R_{$\square$}$-T characteristics of the 48 mol% thin film can be elucidated as a competitive process of KT transition brought about by charge or vortex in the two-dimensional layer structure.e.

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Sl Transitions in BSCCO Mixed Crystal Thin Films

  • Ahn, Joon-Ho;Yi, Keon-Young;Park, Yong-Pil
    • Transactions on Electrical and Electronic Materials
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    • 제3권2호
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    • pp.20-23
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    • 2002
  • Temperature (T) dependence of the sheet resistance (R$\_$$\square$/) has been investigated an the c-axis oriented thin films of the (Bi2212/Bi2201) mixed crystal with different molar fractions. The R$\_$$\square$/-T superconducting characteristic deteriorated with reduction of the Bi2212 fraction, and almost disappears at 48 mol% where a superconductor-to-insulator transition too k place, with the resistance on the normal state, R$\_$N/, reaching 4.1 kΩka at 80 K. This R$\_$$\square$/ value is close to the universal quantum number, h/(2e)$_2$≡ 6.5 kΩ predicted by the Kosterlitz-Thouless (KT) transition theory. The R$\_$$\square$/-T characteristics of the 48 mol% thin film can be elucidated as a competitive process of KT transition brought about by charge or vortex in the two-dimensional layer structure.

The Physical Properties of Thermotropic Side-Chain Triblock Copolymers of n-Butyl Acrylate and a Comonomer with Azobenzene Group

  • Dan, Kyung-Sik;Kim, Byoung-Chul;Han, Yang-Kyoo
    • Macromolecular Research
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    • 제17권5호
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    • pp.313-318
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    • 2009
  • The side chain liquid crystal triblock copolymers (TBCs), which underwent phase transitions below their decomposition temperature, were prepared by copolymerization of poly(n-butyl acrylate) and a comonomer containing the mesogenic azobenzene group. The physical properties of TBCs in the distinctive transition temperature ranges were investigated in terms of the liquid crystal (LC) content in the copolymers. The phase transition temperatures traced optically, thermally and rheologically were well coincided one another and clearly exhibited the phase transition of smectic-nematic-isotropic with increasing temperature. In the smectic phase, increasing temperature made the liquid crystal system more elastic, but viscosity (${\eta}'$) remained almost constant. In the nematic phase, increasing temperature abruptly decreased ${\eta}'$ and G', ultimately leading to isotropic phase. Both smectic and nematic phases exhibited Bingham viscosity behavior but the former gave much greater yield stress at the same LC content.

초크랄스키 공정에서의 천이예측 (Prediction of transition in Czochralski process)

  • 최정일;성형진
    • 한국결정성장학회지
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    • 제7권1호
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    • pp.108-116
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    • 1997
  • 초크랄스키 대류에서의 동적 천이과정에 대한 실험 및 수치해석 연구가 수행되었다. 결정의 회전에 의한 강제대류와 결정/용융 경계면과 도가니 외벽간의 온도차에 의한 자연대류의 상호작용에 의해서 결정되어지는 유동구조와 천이현상을 해석하기 위해 도가니 내의 온도진동 특성을 시간주기($t_p$)와 진동크기($Delta\theta$)에 의해 검토하였다. 혼합대류인자에 따른 천이현상의 체계적인 연구가 수행되었으며($0.134\le Ra/PrRe^2 \le3.804$), 천이현상에 대한 Pr수의 영향을 조사하였다. 천이 메카니즘을 이해하기 위해, 자오면상의 온도장과 중심축에서의 축방향 속도에 대한 해석이 부가되었다.

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Cobalt dodecanesulfate의 구조변화 (Structural change of cobalt dodecanesulfate)

  • 허영덕;권석순;김지현
    • 한국결정성장학회지
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    • 제14권2호
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    • pp.63-67
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    • 2004
  • 층상 구조의 cobalt dedecanesulfate 화합물을 합성하였다. 여러 온도 영역에서 상 전이가 일어나면서 층간 거리의 큰 변화가 생겼다. 상온에서 단일 층 구조의 cobalt dodecanesulfate 화합물이 고온에서 탈수된 화합물의 이중층의 구조로 변화되었다.