• Title/Summary/Keyword: cross-layer

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Investigating the Au-Cu thick layers Electrodeposition Rate with Pulsed Current by Optimization of the Operation Condition

  • Babaei, Hamid;Khosravi, Morteza;Sovizi, Mohamad Reza;Khorramie, Saeid Abedini
    • Journal of Electrochemical Science and Technology
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    • v.11 no.2
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    • pp.172-179
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    • 2020
  • The impact of effective parameters on the electrodeposition rate optimization of Au-Cu alloy at high thicknesses on the silver substrate was investigated in the present study. After ensuring the formation of gold alloy deposits with the desired and standard percentage of gold with the cartage of 18K and other standard karats that should be observed in the manufacturing of the gold and jewelry artifacts, comparing the rate of gold-copper deposition by direct and pulsed current was done. The rate of deposition with pulse current was significantly higher than direct current. In this process, the duty cycle parameter was effectively optimized by the "one factor at a time" method to achieve maximum deposition rate. Particular parameters in this work were direct and pulse current densities, bath temperature, concentration of gold and cyanide ions in electrolyte, pH, agitation and wetting agent additive. Scanning electron microscopy (SEM) and surface chemical analysis system (EDS) were used to study the effect of deposition on the cross-sections of the formed layers. The results revealed that the Au-Cu alloy layer formed with concentrations of 6gr·L-1 Au, 55gr·L-1 Cu, 24 gr·L-1 KCN and 1 ml·L-1 Lauryl dimethyl amine oxide (LDAO) in the 0.6 mA·cm-2 average current density and 30% duty cycle, had 0.841 ㎛·min-1 Which was the highest deposition rate. The use of electrodeposition of pure and alloy gold thick layers as a production method can reduce the use of gold metal in the production of hallow gold artifacts, create sophisticated and unique models, and diversify production by maintaining standard karats, hardness, thickness and mechanical strength. This will not only make the process economical, it will also provide significant added value to the gold artifacts. By pulsating of currents and increasing the duty cycle means reducing the pulse off-time, and if the pulse off-time becomes too short, the electric double layer would not have sufficient growth time, and its thickness decreases. These results show the effect of pulsed current on increasing the electrodeposition rate of Au-Cu alloy confirming the previous studies on the effect of pulsed current on increasing the deposition rate of Au-Cu alloy.

Application of Artificial Neural Network for estimation of daily maximum snow depth in Korea (우리나라에서 일최심신적설의 추정을 위한 인공신경망모형의 활용)

  • Lee, Geon;Lee, Dongryul;Kim, Dongkyun
    • Journal of Korea Water Resources Association
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    • v.50 no.10
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    • pp.681-690
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    • 2017
  • This study estimated the daily maximum snow depth using the Artificial Neural Network (ANN) model in Korean Peninsula. First, the optimal ANN model structure was determined through the trial-and-error approach. As a result, daily precipitation, daily mean temperature, and daily minimum temperature were chosen as the input data of the ANN. The number of hidden layer was set to 1 and the number of nodes in the hidden layer was set to 10. In case of using the observed value as the input data of the ANN model, the cross validation correlation coefficient was 0.87, which is higher than that of the case in which the daily maximum snow depth was spatially interpolated using the Ordinary Kriging method (0.40). In order to investigate the performance of the ANN model for estimating the daily maximum snow depth of the ungauged area, the input data of the ANN model was spatially interpolated using Ordinary Kriging. In this case, the correlation coefficient of 0.49 was obtained. The performance of the ANN model in mountainous areas above 200m above sea level was found to be somewhat lower than that in the rest of the study area. This result of this study implies that the ANN model can be used effectively for the accurate and immediate estimation of the maximum snow depth over the whole country.

Effect of Priming and Seed Pellet Technique for Improved Germination and Growth in Fraxinus rhynchophylla and Alnus sibirica (프라이밍 및 종자펠렛 제조를 통한 물푸레나무와 물오리나무의 발아율 향상 및 생장증대 효과)

  • Park, Hae Il;Shim, Hoon Seob;Choi, Li Na;Jo, Hyeon Gil;Han, Seung Ho;Lee, Jae Geun;Yu, Chang Yeon;Lim, Jung Dae
    • Korean Journal of Medicinal Crop Science
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    • v.21 no.1
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    • pp.7-19
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    • 2013
  • This study was carried out to select new pelleting binder and material for seeds from Fraxinus rhynchophylla Hance and Alnus sibirica Fisch. ex Turcz. The optimum treatments of the various concentrations and species of priming agents to improve seed germination of both woody medicinal plants were also estimated. Germinability was increased when the seeds of Fraxinus rhynchophylla Hance was soaked in -1.0 MPa of PEG6000 solution at $15^{\circ}C$ for 4 days significantly, the optimum treatment for improving germination of Alnus sibirica Fisch. ex Turcz was observed when the tested seeds was soaked in 100 mM of KCl at $15^{\circ}C$ for 4 days. The influence of physical and chemical properties of pelleting solid materials, the mixture of gypsum, diatomaceous earth, dalma ceramic and vermicuolite (6:1:1:1 ratio) were found as the best pelleting materials for Fraxinus rhynchophylla Hance and Alnus sibirica Fisch. ex Turcz. seeds. To satisfy the requirements of absorption and compatibility for multi-layer seed pelleting, SGPA (Starch-grafted cross-linked polyacrylates) hydrogel was prepared using starch, acrylonitrile, ceric ammonium nitrate, nitric acid, methyl alcohol and potassium hydroxide. The resulting SGPA hydrogel showed high water absorption but not plant compatibility. It suggested that seed pelleting using pelleting materials and SGPA hydrogel (multi-layer coating) after priming agent treatment is to increase germinability and seedling growth and it can reduced irrigation labours and can also save seed.

Acoustic Target Strength of the Pelagic Fish in the Southern Waters of Korea I. In situ Measurement of Target Strength of Anchovy (Engraulis japonica) (한국 남해안 부어류의 음향반사강도에 관한 연구 I. 멸치 (Engraulis japonica)의 in situ 반사강도 측정)

  • YOON Gab Dong;KIM Zang Geun;CHOI Young Min
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.29 no.1
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    • pp.107-114
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    • 1996
  • The in situ target strength for the anchovy (Engraulis japonica) were measured by the split beam echo sounder system at 38 kHz. This study allowed us to detect the single echos from anchovy shoals which were dispersed during trawling operation in day time. The results of our study were as fellows: We found that the anchouy occupied about $95\%$ of the total catch from the detected shoals from which target strength data were collected. Length distribution of anchovy showed a mode and ranged from 13.6 to 15.4cm with a mean of 14.4cm and a standard deviation of 0.45cm, and weight distribution showed a mode and ranged from 16 to 28 g witha mean of 21.9 g and a standard deviation of 2.7 g. The target strength distribution of anchovy ranged from -40.7 dB to -69.2 dB in the water layer of ,$10\~30\;m$ -42.19 to -67.7 dB in the $30\~50\;m$ and -42.2 to -67.7 dB in $10\~50\;m$, showing 2 modes in each layer, respectively. Overall mean target strengths were -49.7 dB/fish and -33.1 dB/kg, averaged by area backscattering cross section $(\sigma)$, and the confidence interval for target strength was less than 1 dB. With the mean total length and the mean target strength, we drived the target strength-length relationship as $TS(\sigma)=20\;Log\;L-72.9$.

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An Analysis on the Spatial Scale of Yeongdong Cold Air Damming (YCAD) in Winter Using Observation and Numerical Weather Model (관측과 모델 자료를 활용한 겨울철 영동지역 한기 축적(Yeongdong Cold Air Damming; YCAD)의 공간 규모 분석)

  • Nam, Hyoung-Gu;Jung, Jonghyeok;Kim, Hyun-Uk;Shim, Jae-Kwan;Kim, Baek-Jo;Kim, Seung-Bum;Kim, Byung-Gon
    • Atmosphere
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    • v.30 no.2
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    • pp.183-193
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    • 2020
  • In this study, Yeongdong cold air damming (YCAD) cases that occur in winters have been selected using automatic weather station data of the Yeongdong region of Korea. The vertical and horizontal scales of YCAD were analyzed using rawinsonde and numerical weather model. YCAD occurred in two typical synoptic patterns such that low pressure and trough systems crossing and passing over Korea (low crossing type: LC and low passing type: LP). When the Siberian high does not expand enough to the Korean peninsula, low pressure and trough systems are likely to move over Korea. Eventually this could lead to surface temperature (3.1℃) higher during YCAD than the average in the winter season (1.6℃). The surface temperature during YCAD, however, was decrease by 1.3℃. The cold air layer was elevated around 120 m~450 m for LP-type. For LC-type, the cold layer were found at less than approximately 400 m and over 1,000 m, which could be thought of combined phenomena with synoptic and local weather forcing. The cross-sectional analysis results indicate the accumulation of cold air on the east mountain slope. Additionally, the north or northeasterly winds turned to the northwesterly wind near the coast in all cases. The horizontal wind turning point of LC-type was farther from the top of the mountain (52.2 km~71.5 km) than that of LP-type (20.0 km~43.0 km).

EFFECTS OF TITANIUM SURFACE COATING ON CERAMIC ADHESION (타이타늄 표면 코팅이 도재 결합에 미치는 영향)

  • Kim, Yeon-Mi;Kim, Hyun-Seung;Lee, Kwang-Min;Lee, Doh-Jae;Oh, Gye-Jeong;Lim, Hyun-Pil;Seo, Yoon-Jung;Park, Sang-Won
    • The Journal of Korean Academy of Prosthodontics
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    • v.45 no.5
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    • pp.601-610
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    • 2007
  • Statement of problem: The adhesion between titanium and ceramic is less optimal than conventional metal-ceramic bonding, due to reaction layer form on cast titanium surface during porcelain firing. Purpose: This study characterized the effect of titanium-ceramic adhesion after gold and TiN coating on cast and wrought titanium substrates. Material and method: Six groups of ASTM grade II commercially pure titanium and cast titanium specimens$(13mm{\times}13mm{\times}1mm)$ were prepared(n=8). The conventional Au-Pd-In alloy served as the control. All specimens were sandblasted with $110{\mu}m\;Al_2O_3$ particles and ultrasonically cleaned for 5min in deionized water and dried in air before porcelain firing. An ultra-low-fusing dental porcelain (Vita Titankeramik) was fused on titanium surfaces. Porcelain was debonded by a biaxial flexure test at a cross head speed of 0.25mm/min. The excellent titanium-ceramic adherence was exhibited by the presence of a dentin porcelain layer on the specimen surface after the biaxial flexure test. Area fraction of adherent porcelain (AFAP) was determined by SEM/EDS. Numerical results were statistically analyzed by one-way ANOVA and Student-Newman-Keuls test at ${\alpha}=0.05$. Results: The AFAP value of cast titanium was greatest in the group 2 with TiN coating, followed by group 1 with Au coating and the group 3 with $Al_2O_3$ sandblasting. Significant statistical difference was found between the group 1, 2 and the group 3 (p<.05). The AFAP value of wrought titanium was greatest in the group 5 with TiN coating, followed by the group 4 with Au coating and the group 6 with $Al_2O_3$ sandblasting. Conclusion: No significant difference was observed among the three groups (p>.05). The AFAP values of the cast titanium and the wrought titanium were similar. However the group treated with $Al_2O_3$ sandblasting showed significantly lower value (p<.05).

Anatomical Study of Chordodes koreensis in the Parasitic Phase Using Electron Microscopy (개의 구토물에서 분리한 오디흑연가시(철선충)의 전자현미경을 이용한 해부학적 소견)

  • Son, Hwa-Young;Chae, Joon-Seok;Kim, Nam-Soo;Kim, Hyeon-Cheol;Cho, Jeong-Gon;Park, Bae-Keun
    • Journal of Veterinary Clinics
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    • v.26 no.6
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    • pp.586-590
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    • 2009
  • Horsehair worms (Chordodes koreensis) develop as parasites in the bodies of grasshoppers, crickets, cockroaches, and some beetles. Chordodes koreensis is an accidental parasite of humans, livestock, or pets and poses no public health threat. The male of Chordodes koreensis in the later larval stage from canine vomitus was investigated by the scanning and transmission electron microscopy. In cross sections, the body wall is composed of four components namely epicuticle, cuticle, epidermis, and muscle layers. The parenchymal tissue fills the rest of the body and surrounds the visceral organs such as intestine, and ventral nerve cord but testes were not found. The epicuticle is a thin superficial layer whose surface shows rows of polygonal elevations called areoles. The cuticle has 17 layers of collagenous fibers spirally wound about the long axis of the worm. The section through the cuticle reveals the layers of large fibers cut obliquely lengthwise, alternating with layers of fibers sectioned obliquely crosswise. The layers of large fiber formed a double helix about longitudinal axis of the worm. The epidermis is a single layer. The muscles were interrupted by the nervous lamella in the only midventral portion. The medulla of muscle plate is composed of lightly stained cytoplasm, mitochondria, weakly developed endoplasmic reticulum, and glycogen granules. Between the medulla of a cell and the plasmalemma lies a broad cortical zone of myofilaments. The circular muscles are absent. The characteristic feature of the cytoplasm is that there was no content in peripheral mesenchyme, but was an abundance of large clear vacuoles which give the cytosome a foamy appearance. The nucleus of mesenchyme is not easily identified in our specimens.

Effect of Inorganic Salt Additives on Formation of Phase-Inversion Polyethersulfone Ultrafiltration Membrane (상변환 Polyethersulfone 한외여과막 제조시 무기염 첨가 효과)

  • 김민정;이상덕;염경호
    • Membrane Journal
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    • v.12 no.2
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    • pp.75-89
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    • 2002
  • The effect of addition of inorganic salts in polyethersulfone (PES) polymer solution on the membrane formation and ultrafiltartion performance was studied through the thermodynamic and kinetic properties of casting solution. To control the thermodynamic and kinetic properties of casting solution, various inorganic salts $[CaC1_2, LiCl, LiClO_4, ZnC1_2 $and Mg(ClO_4)_2]$ were added in the PES/NMP solution. Variation of membrane morphology and performance of the resulting membranes with change of the salt type and content added in tasting solution were discussed using viscosity, coagulation value, light transmittance measurement, overall membrane porosity, ultrafiltration experiment and cross-sectional SEM image. For all kind of inorganic salts, according as increase of the salt content in casting solution, viscosity is increased, coagulation value becomes lower, top layer thickness below the skin surface is increased, bovine serum albumin(BSA) rejection decreased and pure water flux is increased except $CaC1_2$ and LiCl. In case of $CaC1_2$ and LiCl, it is found that when the salt content is increased, the formation of macrovoids is suppressed and the precipitation rate becomes slow while instantaneous demixing of precipitation type is maintained. However, in case of $LiClO_4$ and $Mg(ClO_4)_2,$ it is found that precipitation rate becomes faster.

A Design of SPI-4.2 Interface Core (SPI-4.2 인터페이스 코어의 설계)

  • 손승일
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.8 no.6
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    • pp.1107-1114
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    • 2004
  • System Packet Interface Level 4 Phase 2(SPI-4.2) is an interface for packet and cell transfer between a physical layer(PHY) device and a link layer device, for aggregate bandwidths of OC-192 ATM and Packet Over Sonet/SDH(POS), as well as 10Gbps Ethernet applications. SPI-4.2 core consists of Tx and Rx modules and supports full duplex communication. Tx module of SPI-4.2 core writes 64-bit data word and 14-bit header information from the user interface into asynchronous FIFO and transmits DDR(Double Data Rate) data over PL4 interface. Rx module of SPI-4.2 core operates in vice versa. Tx and Rx modules of SPI-4.2 core are designed to support maximum 256-channel and control the bandwidth allocation by configuring the calendar memory. Automatic DIP4 and DIP-2 parity generation and checking are implemented within the designed core. The designed core uses Xilinx ISE 5.li tool and is described in VHDL Language and is simulated by Model_SIM 5.6a. The designed core operates at 720Mbps data rate per line, which provides an aggregate bandwidth of 11.52Gbps. SPI-4.2 interface core is suited for line cards in gigabit/terabit routers, and optical cross-connect switches, and SONET/SDH-based transmission systems.

Property Analysis of Ceramic Interconnect Prepared by Thermal Plasma Spray Coating Method for SOFC (Thermal Plasma Spray Coating 법에 의해 코팅된 SOFC용 세라믹 연결재 특성 분석)

  • Park, Kwang-Yeon;Pi, Seuk-Hoon;Lee, Jong-Won;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Song, Rak-Hyun;Shin, Dong-Ryul
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.710-714
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    • 2011
  • In present work, $La_{0.8}Ca_{0.2}CrO_{3}$(LCC), $La_{0.8}Sr_{0.2}CrO_{3}$(LSC) and $La_{0.8}Ca_{0.2}CrO_{0.9}Co_{0.1}O_{3}$(LCCC) ceramic interconnect layer for SOFC were prepared by using thermal plasma spray coating process. The LCC, LSC and LCCC powders were characterized by x-ray diffraction(XRD), scanning electron microscopy(SEM), particle counter and BET analysis. In addition, basic and essential properties such as the surface morphology, cross section, gas leak rate, and electrical conductivity of LCC, LSC, and LCCC layers coated by thermal plasma spray coating process were analyzed and discussed. Based on these experimental results, it can be concluded that the LCCC layer coated by thermal plasma spray coating process can be suitable as a ceramic interconnect of SOFC.