• 폴리머
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• 제26권1호
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• pp.88-97
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• 2002

ortho-cresol novolac형 에폭시/페놀 경화제/triphenylphosphine 수지 시스템의 화학 레올로지 특성에 미치는 아민 실록산 개질제의 영향을 검토하였다. DSC측정으로부터 아민 개질제에 의해 경화 속도와 전환량이 증가하였으며 유리전이온도의 증가도 관찰할 수 있었다. 또한, 저장 탄성률과 손실 탄성률의 교차점으로부터 구한 겔화 시간 및 임계 전환량의 감소를 확인할 수 있었다. 이것으로부터 등온 경화반응이 빠르게 진행됨으로써 점도가 상승하는 것을 알 수 있었다. 전환량의 함수로 얻어진 유리전이온도와 측정된 점도로부터 modified WLF 방정식에서의 $C_1$ 및 $C_2$를 온도 함수로써 나타낼 수 있었으며, 유리전이온도와 $C_1$ 및 $C_2$를 modified WLF 방정식에 적용함으로써 등온 경화반응에 따른 점도변화를 정확히 예측할 수 있었다.

• Geomechanics and Engineering
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• 제36권5호
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• pp.465-474
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• 2024

Uniaxial compressive strength (UCS) is a critical geomechanical parameter that plays a significant role in the evaluation of rocks. The practice of indirectly estimating said characteristics is widespread due to the challenges associated with obtaining high-quality core samples. The primary aim of this study is to investigate the feasibility of utilizing the gene expression programming (GEP) technique for the purpose of forecasting the UCS for various rock categories, including Schist, Granite, Claystone, Travertine, Sandstone, Slate, Limestone, Marl, and Dolomite, which were sourced from a wide range of quarry sites. The present study utilized a total of 170 datasets, comprising Schmidt hammer (SH), porosity (n), point load index (Is(50)), and P-wave velocity (Vp), as the effective parameters in the model to determine their impact on the UCS. The UCS parameter was computed through the utilization of the GEP model, resulting in the generation of an equation. Subsequently, the efficacy of the GEP model and the resultant equation were assessed using various statistical evaluation metrics to determine their predictive capabilities. The outcomes indicate the prospective capacity of the GEP model and the resultant equation in forecasting the unconfined compressive strength (UCS). The significance of this study lies in its ability to enable geotechnical engineers to make estimations of the UCS of rocks, without the requirement of conducting expensive and time-consuming experimental tests. In particular, a user-friendly program was developed based on the GEP model to enable rapid and very accurate calculation of rock's UCS, doing away with the necessity for costly and time-consuming laboratory experiments.

• 대한기계학회논문집B
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• 제41권5호
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• pp.353-363
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• 2017

부하변동과 외란에 따른 관류보일러 물-증기 계통의 동적 거동을 물리적 모델링 접근방법으로 모사하였다. 본 논문에서는 수관의 질량, 에너지와 운동량 방정식을 고려한 아임계 영역의 동적 모사를 보고한다. 500MWe 급의 절탄기, 증발기와 과열기로 이루어진 단순한 보일러 시스템을 가정하였고, 증발기 모델링은 참고문헌 데이터와 검증을 진행 하였다. 이 시스템에 대하여 외란에 따른 정량적 응답특성을 살펴보았다. 또한, 수연비(증기량과 연료의 유량비)가 설계조건과 크게 다른 탈 설계 운전 사례에 대한 보일러 시스템의 동적 응답평가를 진행 하였다. 그 결과를 통해 적절한 수연비의 제어와 재순환 시스템과 분무 감온기 설계의 중요성이 재확인 되었다.

• Korean Membrane Journal
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• 제7권1호
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• pp.1-18
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• 2005

The permeate flux decline due to membrane fouling can be addressed using a variety of theoretical stand-points. Judicious selection of an appropriate theory is a key toward successful prediction of the permeate flux. The essential criterion f3r such a decision appears to be a detailed characterization of the feed solution and membrane properties. Modem theories are capable of accurately predicting several properties of colloidal systems that are important in membrane separation processes from fundamental information pertaining to the particle size, charge, and solution ionic strength. Based on such information, it is relatively straight-forward to determine the properties of the concentrated colloidal dispersion in a polarized layer or the cake layer properties. Incorporation of such information in the framework of the standard theories of membrane filtration, namely, the convective diffusion equation coupled with an appropriate permeate transport model, can lead to reasonably accurate prediction of the permeate flux due to colloidal fouling. The schematic of the essential approach has been delineated in Figure 5. The modern approaches based on appropriate cell models appear to predict the permeate flux behavior in crossflow membrane filtration processes quite accurately without invoking novel theoretical descriptions of particle back transport mechanisms or depending on adjust-able parameters. Such agreements have been observed for a wide range of particle size ranging from small proteins like BSA (diameter ${\~}$6 nm) to latex suspensions (diameter ${\~}1\;{\mu}m$). There we, however, several areas that need further exploration. Some of these include: 1) A clear mechanistic description of the cake formation mechanisms that clearly identifies the disorder to order transition point in different colloidal systems. 2) Determining the structure of a cake layer based on the interparticle and hydrodynamic interactions instead of assuming a fixed geometrical structure on the basis of cell models. 3) Performing well controlled experiments where the cake deposition mechanism can be observed for small colloidal particles (< $1\;{\mu}m$). 4) A clear mechanistic description of the critical operating conditions (for instance, critical pressure) which can minimize the propensity of colloidal membrane fluting. 5) Developing theoretical approaches to account for polydisperse systems that can render the models capable of handing realistic feed solutions typically encountered in diverse applications of membrane filtration.

• Journal of Pharmaceutical Investigation
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• 제4권1_2호
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• pp.39-45
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• 1974

According to previous paper, the hardness of semi-solid as ointments and suppositories causes the tough or skin, the pain and connected with absorption, the state of spread or the efficiency of drug. When the hardening agent or the softening agent is added to ointment whid, is registered on the pharmacopeia of the republic of Korea, the experimertal data by apparent logarithmic hardness are shown is Table 1. The results are as the folloring. 1) In case of the softening agent which is added to ointment base, each has shown two different equation with differnented slope as $K_1$ and $K_2$ value determined (Fig. 1,2). 2) When the hardening agent is added to same ointment base, these studies indicated that there is a direct correlation between $K_1$ and $K_2$. However, in case of softening agent $K_1$ and $K_1$ are not correlated as indicated in Fig. $3{\sim}8$. 3) On condition of same ointment base, the critical poit is proportional to $K_1$ 4) The second effect is at least $3{\sim}17$ times more. sensitive than the first effect or in average 8.3 times more sensitive, Therefore, the results presented in this paper. Suggest that, when the drug is added to a certain ointment base, it should be added within this first effect before the critical point is reached.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 1991년도 가을 학술발표회 논문집
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• pp.133-138
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• 1991

The aim of the present paper is to develop a computer program predicting ultimate fracture strength of initially cracked structure under monotonically increasing external loads. For this purpose, two kinds of 3-D isoparametric solid elements, one 6-node wedge element and another 8-node brick element are formulated along the small deformation theory. Plasticity in the element is checked using von Mises' yield criterion. Elasto-plastic stiffness matrix of the element is calculated taking account of strain hardening effect. If the principal strain at crack tip which is one nodal point exceeds the critical strain dependin on the material property, crack tip is supposed to be opened and the crack tip node which was previously constrained in the direction perpendicular to the crack line is released. After that, the crack lay be propagated to the adjacent node. Once a crack tip node is fractured, the energy of the newly fractured node should be released which is to be absorbed by the remaining part. The accumulated reaction force which was carried by the newly fractured node so far is then applied in the opposite direction. During the action of crack tip relief force, since unloading may be occured in the plastic element, unloading check should be made. If a plastic element unloads, elastic stress-strain equation is used in the calculation of the stiffness matrix of the element, while for a loading element, elasto-plastic stress-strain equation is continuously used. Verification of the computer program is made comparing with the experimental results for center cracked panel subjected to uniform tensile load. Also some factors affecting ultimate fracture strength of initially cracked plate are investigated. It is concluded that the computer program developed here gives an accurate solution and becomes useful tool for predicting ultimate fracture load of initially cracked structural system under monotonically increasing external loads.

• Elastomers and Composites
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• 제49권1호
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• pp.13-23
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• 2014

본 연구에서는 생체분해성 폴리에스터 계열의 glycolide, L-lactide 및 ${\varepsilon}$-caprolactone 단량체를 이용하여 2단계 중합법에 의한 삼원 공중합체를 제조하여, DSC를 이용한 비등온 결정화 거동을 고찰하였다. 보다 더 정확한 거동을 검토하기 위하여 Avrami 식과 Ozawa 식을 조합하여 비등온 결정화 거동을 고찰하였다. 과냉각도를 분석한 결과 PGCLA21의 값이 가장 큰 값을 보이고 있으며 L-lactide 함량이 증가함에 따라 과냉각도는 증가하는 경향을 보이고 있다. 수정된 Avrami 식을 이용하여 다양한 냉각속도에서 비등온 결정화 거동 결정화 속도 상수는 큰 경향을 보이고 있지 않는 것을 알 수 있었다. Avrami 및 Ozawa 식을 조합하여 특정한 상대적 결정화도에서의 냉각함수를 구한결과 L-lactide 함량이 증가하면서 PGCL과 비교시 결정화 속도를 향상시키는 역할을 하고 있는 것으로 여겨지는 반면 PGCLA41과 PGCLA21을 비교시 L-lactide 함량이 일정 이상 증가시 logF(T) 값이 큰 것을 확인 할 수 있는데 이는 동일한 결정을 얻는데 더 많은 냉각 속도를 필요로 한다는 것을 의미하며 결정화 속도 향상에 부정적인 영향을 미치는 것으로 판단된다.

• International Journal of Concrete Structures and Materials
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• 제10권4호
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• pp.407-424
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• 2016

This study tests ten full-size simple-supported beam specimens with the high-strength reinforcing steel bars (SD685 and SD785) using the four-point loading. The measured compressive strength of the concrete is in the range of 70-100 MPa. The main variable considered in the study is the shear-span to depth ratio. Based on the experimental data that include maximum shear crack width, residual shear crack width, angle of the main crack and shear drift ratio, a simplified equation are proposed to predict the shear deformation of the high-strength reinforced concrete (HSRC) beam member. Besides the post-earthquake damage assessment, these results can also be used to build the performance-based design for HSRC structures. And using the allowable shear stress at the peak maximum shear crack width of 0.4 and 1.0 mm to suggest the design formulas that can ensure service-ability (long-term loading) and reparability (short-term loading) for shear-critical HSRC beam members.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2007년도 춘계학술대회 논문집
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• pp.1319-1324
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• 2007

Many researches have been performed to analyze the smoke movement in tunnel fires by using field model. Recently, FDS(Fire Dynamics Simulator) v.4, which is one of the field model and developed from NIST(National Institute of Standards and Technology), is widely used. In tunnel fires, FDS can show detail results in local point, but it has difficulties in boundary condition and taking long computing time as the number of grid increases. So, there is a need to use alternative method for tunnel fire simulation. A zone model is different kind of CFD method and solves ordinary differential equation based on conservation and auxiliary equations. It shows good macroscopic view in less computing time compared to field model. In this study, therefore, to confirm the applicability of CFAST in tunnel fire analysis, numerical simulations using CFAST are conducted to analyze smoke movement in longitudinal ventilation reduced-scale tunnel fires. Then the results are compared with experimental results. The differences of temperature and critical velocity between numerical results and experimental data are over $30^{\circ}C$ and 0.9m/s, respectively. These values are out of error range. It shows that CFAST 6.0 is hard to be used for tunnel fire simulation.

• 천문학회지
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• 제31권1호
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• pp.27-37
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• 1998

We have made semi-analytical studies to investigate the configurations of caustics and the probability distribution of the flux factor K for the binary microlensing including external shears. A parametric equation of critical curve is derived in a 4th order complex polynomial. We present the topological dependencies of the caustics for selected gamma parameters (0, 0.3, 0.6, 1.3, 2.0, and 2.5) and convergence terms (0., 0.4, 0.8, 1.2, 1.6, and 2.0). For the purpose of analyzing the efficiency of High Amplification Event (HAE) on each caustics, we examine the probability distribution of the flux factor by a Monte Carlo method. Changing the separation of the binary system from 0.8 to 1.3 (in normalied unit), we examine the probability distribution of the K-values in various gamma parameters. The relationship between gamma parameters, seperations and their probabilties of the flux factor K have been studied. Our results show that the relatively higher K values (K>1.5) are increased as increasing the separation of the binary system. We therfore conclude that, in the N-body microlensing, the probabilities of higher HAEs are inversely proportional to the star density as well. We also point out that the present research might be used as a preliminary step toward investigating heavy N-body microlensing simulations.