• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2018년도 추계 학술논문 발표대회
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• pp.40-41
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• 2018

The purpose of this study is to compare the amount of critical chloride of rebar embedded in concrete according to the substitution rate of admixture. In order to determine the starting point of corrosion of rebar, electrodes were embedded in concrete, chloride was supplied, and OCP of rebar was observed in real time. The amount of the contaminants in the concrete surrounding the rebar was judged to be the critical corrosion chloride contents of the rebar at the start of the corrosion. As a result of the comparative evaluation, it was confirmed that the critical chloride contents of the rebar decreased with increasing the substitution ratio of the admixture.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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• pp.613-616
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• 2006

The purpose of the this study of to define the critical corrosion amount of the steel cause the cracking of concrete cover. The major variables of the critical corrosion amount are concrete strength and thick of the concrete cover. In this experiment, the constant of stress concentration is added by a new variable. As a result of the experiment, it is confirmed to less decrease in the critical corrosion amount following the constants of stress concentration increased. Besides, electric currents were measured through a generator of constant voltage. When connecting constant voltage with corrosion circuit, it was discovered that magnitude of the change come out similarly between displacement on the concrete cover and electric current according to time.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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• pp.361-366
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• 2002

The deterioration of concrete structure due to corrosion of the reinforcement has created big financial losses on the overall industries. The volume expansion of the corrosion products causes internal pressure to concrete wall around reinforcing bar. If the maximum principal stress induced by internal pressure exceeds the tensile strength of the concrete at any point of time, a crack forms at any point of material. Therefore, in terms of life assessment of concrete structure, it is very important to predict the amount of corrosion products which induces initial concrete cracking. With this objective, this paper proposes the critical amount of corrosion products at interface between reinforcement and concrete using finite element analysis. If an actual survey of corrosion rates could be made, the model might supply information for condition assessment of existing concrete structure. As the mechanical properties of corrosion product and instantaneous geometry of corroded steel are considered in the analysis, the value obtained will be more realistic.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2014년도 추계 학술논문 발표대회
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• pp.59-60
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• 2014

To prevent the rusting of steel, a variety of finishing materials has been applied. When steel is exposed to an extreme chloride environment, however, the thermal performance and aging of the finishing materials cause the material to lose its rust protective performance. In this study, an accelerated corrosion test was performed on five different finishing materials for steel, to determine the critical values of corrosion. As the result, the critical value of corrosion was found with no coat between 0.58mg/d㎡ and 0.73mg/d㎡, with urethane coat between 7.89mg/d㎡~8.46mg/d㎡, with one-layered red lead coat between 57.95mg/d㎡ and 69.48mg/d㎡, and with staleness201 between 80.73mg/d㎡ and 89.35mg/d㎡.

• 콘크리트학회논문집
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• 제14권6호
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• pp.851-863
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• 2002

철근의 부식에 의해 발생하는 부식생성물은 부피팽창으로 인하여 주위의 콘크리트에 압력을 가한다. 이 팽창압은 철근 주의의 콘크리트에 인장응력이 생기게 하며 결국 콘크리트의 피복에 균열을 발생시킨다. 콘크리트 피복의 균열발생은 콘크리트 구조물의 사용수명을 감소시킬 뿐만 아니라 안전성에도 영향을 미친다. 본 연구의 목적은 콘크리트 피복에 균열을 일으키는 임계부식량을 조사하는 것이다. 이를 위하여 포괄적인 실험 및 이론적 연구를 수행하였다. 주요 실험변수로는 콘크리트의 강도와 피복두께이고 부식량의 증가에 따른 콘크리트 피복 표면의 인장변형률을 측정하였다. 철근 팽창에 의한 팽창압의 계산에 공극 및 균열 속으로 흡수되는 부식생성물을 고려하였다. 본 연구를 통하여 균열을 일으키는 임계부식량은 콘크리트 압축강도가 커짐에 따라 증가한다는 사실을 확인하였다. 부식층 내의 팽창압과 변형 사이의 관계를 유도하였으며 부식생성물층의 강성을 결정하였다. 팽창압과 변형 사이의 관계를 설명하기 위하여 압력을 유발하지 않는 변형량의 개념을 도입하였다. 본 연구에서 제안된 이론은 실험결과와 잘 일치하며 콘크리트 구조물의 내구성 설계에 기초가 될 수 있을 것이다.

• Tribology and Lubricants
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• 제15권4호
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• pp.335-342
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• 1999

Corrosion of the disk has been an ongoing concern for the manufacturers of hard disk drives. With the advent of magnetoresistive (MR) head, very low levels of corrosion and contamination become more critical since the raised defects and corrosion products on the disk surface-anything that heats the MR sensor due to the contact-can distort the output signal of the head. This phenomenon is called as thermal asperity. In this paper, the effect of corrosion as a form of Co migration on the occurrence of thermal asperity in MR drives was investigated. The corrosion test at high temperature (60$^{\circ}C$) and high relative humidity (80%) was emphasized in this study and the testing results at ambient condition were compared. The corrosion on the disks was characterized as the amount of Co ion migration using an ion chromatography (IC) and a time-of-flight secondary ion mass spectroscopy (TOF-SIMS). It is proved that corrosion on the disk surface after storage testing is closely correlated to the amount of Co ions migration from the magnetic layer to disk surfaces and higher Co migration causes more thermal asperities in the drive. In order to reduce Co migration, several methods such as burnishing process and structure of the carbon overcoat were investigated. It is found that the hydrogenated carbon overcoat shows the least Co migration among different types of overcoat layer. However, the most effective way to reduce Co migration is the application of Cr layer between the overcoat and the magnetic alloy layer.

• Computers and Concrete
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• 제21권4호
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• pp.419-429
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• 2018

Climate changes, such as increasing of $CO_2$ concentration and global warming, will impact on the carbonation service life of concrete structures. Moreover, slag blended concrete has a lower carbonation resistance than control concrete. This study presents a probabilistic numerical procedure for evaluating the impact of climate change on carbonation service life of slag blended concrete. This numerical procedure considers both corrosion initiation period and corrosion propagation period. First, in corrosion initiation period, by using an integrated hydration-carbonation model, the amount of carbonatable substances, porosity, and carbonation depth are calculated. The probability of corrosion initiation is determined through Monte Carlo method. Second, in corrosion propagation period, a probabilistic model is proposed to calculate the critical corrosion degree at surface cracking, the probability of surface cracking, and service life. Third, based on the service life in corrosion initiation period and corrosion propagation period, the whole service life is calculated. The analysis shows that for concrete structures with 50 years service life, after considering climate changes, the service life reduces about 7%.

• Corrosion Science and Technology
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• 제5권1호
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• pp.27-32
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• 2006

One of the critical issues in the coating specification is the allowable limit of surface contaminant(s) - such as soluble salt(s), grit dust, and rust - after grit blasting. Yet, there is no universally accepted data supporting the relationship between the long-term coating performance and the amount of various surface contaminants allowed after grit blasting. In this study, it was attempted to prepare epoxy coatings applied on grit-blasted steel substrate dosed with controlled amount of surface contaminants - such as soluble salt(s), grit dust, and rust. Then, coating samples were subjected to 4,200 hours of cyclic test(NORSOK M-501), which were then evaluated in terms of resistance to rust creepage, blistering, chalking, rusting, cracking and adhesion strength. Additional investigations on the possible damage at the paint/steel interface were carried out using an Electrochemical Impedance Spectroscopy(EIS) and observations of under-film-corrosion. Test results suggested that the current industrial specifications were well matched with the allowable degree of rust, whereas the allowable amount of soluble salt and grit dust after grit blasting showed a certain deviation from the specifications currently employed for fabrication of marine vessels and offshore facilities.

• 한국표면공학회지
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• 제36권6호
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• pp.423-429
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• 2003

It has been investigated corrosion resistance and crystal structure of Zn-Cr coatings fabricated by electroplating method and electron-beam physical vapor deposition method(EB-P VD). The electroplated Zn-Cr alloy consists mainly of η'-Zn phase for the lower Cr content than 7.9 wt% Cr and ${\gamma}$'-ZnCr phase for the higher Cr content. In the Zn-Cr alloy fabricated by EB-PVD the ${\gamma}$'-ZnCr phase appeared clearly at 3 wt% Cr and it became the sole phase at 50 wt%Cr. The amount of η'-Zn phase decreased obviously with increasing Cr content when it exceeded 15 wt% Cr. The electrochemical measurement of the electroplated Zn-Cr film has shown corrosion potential of about -1000 mV. The current density of active region and the amount of dissolved Zn and Cr decreased significantly with increasing Cr content. The electrochemical characteristics of Zn-Cr alloy fabricated by EB-PVD have shown that the alloy of 50 wt% Cr had the highest corrosion potential(-500 mV) and the lowest critical passive current density than that of the electroplated.

• 콘크리트학회논문집
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• 제20권4호
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• pp.415-421
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• 2008

콘크리트 중의 철근부식은 콘크리트 제조시 초기부터 콘크리트 중에 존재하는 염소이온과 기상작용 등의 환경요인에 의하여 외부로부터 침투하는 염소이온이 어느 값 (임계염화물량) 이상의 경우에 발생한다. 이 때문에 각 국에서는 콘크리트 중의 염소이온량의 상한치를 규제하고 있으며, 국가별 상황에 적절하게 상이한 방법으로 규제하고 있다. 따라서 본 연구에서는 콘크리트 중 염소이온량의 합리적인 규제방법을 제안하기 위하여, 단위시멘트량이 다른 콘크리트 중의 염소이온에 의한 철근부식 임계 염화물량을 실험적으로 산출하였다. 그 결과, 철근부식 임계염화물량은 단위시멘트량의 변화에 따라 크게 변화하는 것을 알 수 있었다. 또한, 실험으로부터 얻어진 철근부식 임계염화물량은 기존의 모델계산의 결과와 잘 일치함을 알 수 있었다. 현행과 같이 철근부식 임계염화물량을 콘크리트 단위체적 당의 양 (콘크리트 총량표기)으로 단위시멘트량에 관계없이 일률적으로 관리하면, 단위시멘트량 등의 콘크리트 배합조건, 환경조건의 변화 등이 철근부식 임계염화물량에 미치는 영향을 고려할 수 없을 것으로 판단된다. 따라서, 철근부식 임계염화물량을 단위시멘트량 당의 양 (시멘트 종량표기)으로 표기하는 것으로, 단위시멘트량에 관계없이 일정한 값으로 표시할 수 있기 때문에 합리적이라고 판단된다.