• Title/Summary/Keyword: critical concentration

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Generation of Microcellular Foams in Viscoelastic Polymer Solutions (점탄성 폴리머 용액에서의 초미세 폼의 생성)

  • Kang, Sung- Lin;Kim, Ki-Young;Kwak, Ho-Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.6
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    • pp.726-733
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    • 2004
  • The growth of the critical size bubble by diffusion process in viscoelastic medium was treated by an integral method for the concentration boundary layer adjacent to the bubble wall. In this study, we obtained a set of the first order time dependent equations to obtain bubble radius and gas pressure inside the bubble simultaneously. The calculated final cell sizes depending on the initial saturation pressure are in close agreement with the observed ones. The governing equations developed in this study may be used in polymer processing of microcellular foams.

Characteristics of a Bimetal-Layer Chip of a Surface Plasmon Resonance Sensor in the Intensity Interrogation for Tumor Marker Detection

  • Kim, Hyungjin;Kim, Chang-duk;Sohn, Young-Soo
    • Journal of Sensor Science and Technology
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    • v.25 no.4
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    • pp.243-246
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    • 2016
  • The characteristics of a bimetallic surface plasmon resonance (SPR) chip were investigated to detect a tumor biomarker, carcinoembryonic antigen (CEA). The linewidth and the tangential slope of the reflectance curve of the bimetallic SPR chip was compared with those of the reflectance curve of a conventional gold (Au) SPR chip. The changes in reflectance in response to the variation in CEA in the critical concentration range were analyzed at an angle where the tangential slope of the reflectance curve was maximum. From linear regression analysis, the sensitivity of the bimetallic SPR chip with respect to the CEA in critical concentration was obtained.

A Study on the Fracture Phenomena in Optical Disks Due to Increase of the Rotating Speed (회전속도 증가에 의한 광디스크의 파괴현상에 관한 연구)

  • 조은형;좌성훈;정진태
    • Journal of KSNVE
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    • v.11 no.3
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    • pp.437-442
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    • 2001
  • In this study, the fracture phenomena of optical disks are discussed by theoretical and experimental approaches and then some recommendations are presented to prevent the fracture. Linear equations of motion are discretized by using the Galerkin approximation. From the discretized equations, the dynamic responses are computed by the generalized- time integration method. As a fracture criterion for optical disks, the critical crack length is presented. From experimental methods, the fracture procedure is analyzed. The fracture occurs when disks have crack on the inner radius of the disks. Since the crack growth and the fracture result from the stress concentration on the tip of the crack, a measure should be taken to overcome the stress concentration. This problem can be resolved by the structural modification of a disk. This study proposes 3 types of improved optical disks.

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Partial Charge and CMC Characteristics of Hydrophilic and Hydrophobic Group of Surfactants (Cationic and Amphoteric Surfactant) (계면활성제의 친수.소수성 그룹의 부분전하와 CMC특성 (양이온 및 양쪽성 계면활성제))

  • 하윤식
    • Journal of Environmental Science International
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    • v.9 no.5
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    • pp.403-408
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    • 2000
  • On the basis of theory of Bratsch's electronegativity equalization the electronegativity equalization the group electronegativities and the group partial charges for cationic and amphoteric surface and amphoteric surfactants could be calculated using Pauling's electronegativity parameters. From calculated output we have investigated relationships between CMC(critical micelle concentration) and partial charge and group electronegativity of hydrophilic and hydrophobic groups structural stability of micelle for cationic and amphoteric surfactants. As a result CMC depends upon partial charge and electronegativity of hydrophilic group is decreased. With increasing the carbon number of hydrophilic group for cationic surfactant its partial charge is increased but CMC and its electronegativity are decreased. With increasing the carbon number of hydrophobic group for cationic and amphoteric surfactant its partial charge is increased but CMC andits electronegativity are decreased.

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Hydrogen concentration and critical epitaxial thicknesses in low-temperature Si(001) layers grown by UHV ion-beam sputter deposition.

  • Lee, Nae-Eung
    • Journal of Korean Vacuum Science & Technology
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    • v.3 no.2
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    • pp.139-144
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    • 1999
  • Hydrogen concentration depth profiles in homoepitaxial Si(001) films grown from hyper-thermal Si beams generated by ultrahigh vacuum (UHV) ion-beam sputtering have been measured by nuclear reaction analyses as a function of film growth temperature and deposition rate. Bulk H concentrations CH in the crystalline Si layers were found tio be below detection limits, 1${\times}$1019cm-3, with no indication of significant H surface segregation at the crystalline/amorphous interface region. This is quite different than the case for growth by molecular-beam epitaxy (MBE) where strong surface segregation was observed for similar deposition conditions with average CH values of 1${\times}$1020cm-3 in the amorphous overlayer. The markedly decreased H concentrations in the present experiments are due primarily to hydrogen desorption by incident hyperthermal Si atoms. Reduced H surface coverages during growth combined with collisionally-induced filling of interisland trenches and enhanced interlayer mass transport provide an increase in critical epitaxial thicknesses by up to an order of magnitude over previous MBE results.

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A Study on the Corrosive Wear Mechanism on Atmospherical Temperature of STS 304 Steel (STS 304강의 분위기온도에 따른 부식마멸기구에 관한 연구)

  • 전태옥;박흥식;주창식
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.2
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    • pp.399-406
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    • 1990
  • This paper is studied to know corrosive wear mechanism of STS304 steel on atmospherical temperature against mating material as the same. The corrosive test was carried out by rubbing the annular surface of two test pieces in distilled water and NaCl aqueous solution. The corrosive wear mechanism was investigated by S.E.M. The experimental results show that there is one Lcr transferring from severe wear to mild wear on change of NaCl concentration and atmospherical temperature, and which is the other still remaining in server wear state. It was found that the critical sliding distance Lcr shorten with increasing NaCl concentration but it is longer with ascending atmospherical temperature and the mild wear state still continues under the condition of high generation rate and elimination rate of the corrosive product. Considering upon the result, the model of corrosive wear mechanism is proposed.

Isolation, Characterization, and Investigation of Surface and Hemolytic Activities of a Lipopeptide Biosurfactant Produced by Bacillus subtilis ATCC 6633

  • Dehghan-Noudeh Gholamreza;Housaindokht Mohammadreza;Bazzaz Bibi Sedigeh Fazly
    • Journal of Microbiology
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    • v.43 no.3
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    • pp.272-276
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    • 2005
  • Bacillus subtilis ATCC 6633 was grown in BHIB medium supplemented with $Mn^{2+}$ for 96 h at $37^{\circ}C$ in a shaker incubator. After removing the microbial biomass, a lipopeptide biosurfactant was extracted from the supernatant. Its structure was established by chemical and spectroscopy methods. The structure was confirmed by physical properties, such as Hydrophile-Lipophile Balance (HLB), surface activity and erythrocyte hemolytic capacity. The critical micelle concentration (cmc) and erythrocyte hemolytic capacity of the biosurfactant were compared to those of surfactants such as SDS, BC (benzalkonium chloride), TTAB (tetradecyltrimethylammonium bromide) and HTAB (hexadecyltrimethylammonium bromide). The maximum hemolytic effect for all surfactants mentioned was observed at concentrations above cmc. The maximum hemolytic effect of synthetic surfactants was more than that of the biosurfactant produced by B. subtilis ATCC 6633. Therefore, biosurfactant would be considered a suitable surface-active agent due to low toxicity to the membrane.

Influence of Various Waxes on Consistency of W/O Type Cream (왁스류(類)가 유중빙형(油中氷型)크림의 조도(稠度)에 미치는 영향)

  • Bae, Bong-Jean;Choi, Young-Uk;Kim, Johng-Kap
    • Journal of Pharmaceutical Investigation
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    • v.15 no.3
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    • pp.121-129
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    • 1985
  • Influences of various waxes on the consistency of cream was investigated by inspections through microscope, rheometer and sensory test. Fatty acids, higher fatty alcohols, hydrocarbons, and some of natural waxes were used in this experiment. Most above waxes showed good state of emulsion at low concentration, but at higher concentration $(7.0{\sim}8.0%)$, they showed not only an unstable emulsion state but also a critical point of content in consistency. At this critical point of content, the consistency of w/o type cream was increased irregularly. So, it could be identified that consistency of a w/o type cream was strongly dependent on kinds and contents of waxes in continuous phase.

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Sensitivity Analysis of Parameters in a Depth Averaged Two-Dimensional Sediment Transport Model (수심적분 2차원 유사이동모형에 관계된 인자들의 민감도분석에 관한 연구)

  • Seo, Sang-Won;Yun, Byeong-Man
    • Journal of Korea Water Resources Association
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    • v.31 no.1
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    • pp.115-120
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    • 1998
  • In this paper, a depth-averaged two-dimensional transport model is introduced, and its error bound is presented as the results of sensitivity analysis. The results show that the calculated SS concentration is highly dependant on Manning roughness coefficient, mixing coefficient. fall velocity. and critical shear stress. On the other hand, water level and dispersion coefficient are proved to be less significant in the variation of SS concentration.

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Synergistic Effect of Mixed Anionic/Nonionic Surfactant Micelles (음이온/비이온 계면활성제의 미셀상승 효과)

  • Kwon, Soun-Il;Kwack, Kwang-Soo;Nam, Ki-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.4
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    • pp.249-253
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    • 2001
  • A proposed method of determining the composition of mixed micelles in equilibrium with monomer of known composition is described. The systems were sodium ${\alpha}-sulfonated$ dodecanoyl ethyl esther (${\alpha}-SR_{12}Et$) or sodium dodecyl sulfate(SDS)-polyoxyethylene 23 lauryl ether (Brij 35) un water and in 0.1M sodium chloride solution at $25^{\circ}C$. This technique applies the Gibbs-Duhem equation to the mixed micelles, which is treated as a pseudophase. This proposed methodology, which needs only critical micelle concentration data as a function of monomer composition, is applied to an anionic/nonionic surfactant pair. The calculated monomer-micelle equilibrium is found to be very similar to the much-used regular solution for nonideal systems.