• Progress in Superconductivity
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• v.7 no.2
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• pp.140-144
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• 2006

We fabricated the YBCO films on single crystal $LaAlO_3$ substrates via a metal organic deposition (MOD) process. In the process, $Y_2Ba_1Cu_1O_x$ and $Ba_3Cu_5O_8$ powders were dissolved in trifluoroacetic acid (TFA) followed by calcining and firing heat treatments. To evaluate the effects of the firing temperature on YBCO phase formation and critical properties, the films were fired at $750^{\circ}C,\;775^{\circ}C\;and\;800^{\circ}C$ after calcining at $430^{\cric}C$. Microstructure observation indicated that a crack-free surface formed and a strong biaxial texture was developed. The FWHM of out-of-plane texture was measured to be in the range of $4.3^{\cric}-7.0^{\circ}$ for all the films. When the YBCO film was fired at $775^{\cric}C$, it had the highest critical properties: 88.5 K of critical temperature and 16 A/cm-width of critical current ($1MA/cm^2$ as critical current density). On the other hand, those properties were degraded as firing at $750^{\circ}C\;and\;800^{\circ}C$. It is considered that the improved critical values are partly owing to dense and homogeneous microstructure, strong texture, and high oxygen content.

• Applied Chemistry for Engineering
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• v.31 no.5
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• pp.568-574
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• 2020

Gas diffusion layer (GDL) is one of the main components of PEMFC as a pathway of reactants from a flow field to an electrode, water transport in reverse direction, heat management and structural support of MEA. In this study, the effect of GDL on fuel cell performance was investigated for commercial products such as 39BC and JNT30-A3. Polarization curve measurements were performed at different flow rates and relative humidity conditions using 25 ㎠ unit cell. The parameters on operating conditions were calculated using an empirical equation. The electrical resistance increased as the GDL PTFE content increased. The crack of microporous layer had influence on the concentration loss as water pathway. In addition, the ohmic resistance increased as the relative humidity decreased, but decreased as the current density increased due to water formation. Curve fitting analysis using the empirical equation model was applied to identify the tendency of performance parameters on operating conditions for the gas diffusion layer.

• Nuclear Engineering and Technology
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• v.42 no.5
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• pp.576-581
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• 2010

KAERI (Korea Atomic Energy Research Institute) fabricated MOX (Mixed Oxide) fuel pellets as a cooperation project with PSI (Paul Scherrer Institut) for an irradiation test in the Halden reactor. The MOX pellets were fitted into fuel rods that included instrumentation for measurement in IFE (Institutt for Energiteknikk). The fuel rods were assembled into the test rig and irradiated in the Halden reactor up to 50 MWd/kgHM. The irradiated fuel rods were transported to the IFE, where ceramography was carried out. The fuel rods were cut transversely at the relatively higher burn-up locations and then the radial cross sections were observed. Micrographs were analyzed using an image analysis program and grain sizes along the radial direction were measured by the linear intercept method. Radial cracks in the irradiated MOX were observed that were generally circumferentially closed at the pellet periphery and open in the hot central region. A circumferential crack was formed along the boundary between the dark central and the outer regions. The inner surface of the cladding was covered with an oxide layer. Pu-rich spots were observed in the outer region of the fuel pellets. The spots were surrounded by many small pores and contained some big pores inside. Metallic fission product precipitates were observed mainly in the central region and in the inside of the Pu spots. The average areal fractions of the metallic precipitates at the radial cross section were 0.41% for rod 6 and 0.32% for rod 3. In the periphery, pore density smaller than 2 ${\mu}m$ was higher than that of the other regions. The grain growth occurred from 10 ${\mu}m$ to 12 ${\mu}m$ in the central region of rod 6 during irradiation.

• Korean Journal of Materials Research
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• v.17 no.2
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• pp.100-106
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• 2007

The effects of $MgO-P_2O_5$ based sintering additive on the microstructure and material and biological properties of hydroxyapatite $(HAp,\;Ca_{10}(PO_4)_6(OH)_2)$ ceramic were investigated using XRD, SEM and TEM techniques. The $MgO-P_2O_5$ sintering additive improved the material properties and increased the grain size in the sintered HAp bodies. As the content of sintering additive increased over 4 wt%, a small amount of the HAp phase was decomposed and transformed to ${\beta}-TCP$. In the 2 wt% $MgO-P_2O_5$ content HAp sintered body, the maximum values of density and hardness were respectively about 3.10 gm/cc and 657 HV. However, the maximum fracture toughness in the HAp body containing 8 wt% $MgO-P_{2}O_{5}$ was about $1.02MPa{\cdot}m^{1/2}$ due to the crack deflection effect. Human osteoblast like MG-63 cells and osteoclast like raw 264.7 cells were well grown and fully covered all of the HAp sintered bodies. The osteoblast cells were grown with spindle-shaped and the osteoclast cells had a grape-like round shape.

• Composites Research
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• v.25 no.3
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• pp.65-69
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• 2012

The main objective of this study is to investigate the effect of metal z-pinning on the failure behavior of cocured composite single-lap joints. Three different pin diameters (0.3, 0.5, and 0.7 mm) and three pin areal densities (0.5, 2.0, and 4.0%) were examined. The specimens were fabricated by T700-12K-31E#2510 unidirectional prepreg from Toray. Stainless steel pins were used for z-pinning. Test results showed that except one case with extremely low pin density of 0.5%, all other z-pinned joints exhibited lower initial crack stresses than those of the unpinned joint. However the ultimate strength of the z-pinned joint increased up to 45% at most. Furthermore, even after the complete failure of the joint, the z-pins sustained the carried load to a certain degree experiencing large deformation and provided the stable fracture behavior for the composite joint.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.40 no.5
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• pp.974-980
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• 2015

Arc thermal spray coating using Al-3%Mg thermal spray wire was carried out to prevent steel from corrosion damage under the marine environment. Post-sealing was applied to Al-3%Mg spray coating treatment using organic/inorganic composite ceramics in order to improve the corrosion resistance of the as-sprayed coating. The results of various electrochemical experiments with sealing treatment indicated that the improvement in corrosion resistance was observed due to low current density in all applied potential range during anodic and cathodic polarization experiments. Futhermore, the natural potential measurement exhibited severe potential fluctuation due to influence of micro-crack presence on the surface of sealed thermal spray coating layer. In addition, the sealed layer was easily eliminated during anodic polarization. Nevertheless, Al-3%Mg spray coating layer improved corrosion resistance by sealing treatment because the sealed coating efficiency was determined to be 92.11%, indicating the exterior environment barrier effect which is based on the Tafel analysis.

• Journal of the Microelectronics and Packaging Society
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• v.9 no.1
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• pp.35-41
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• 2002

Flip-chip interconnection that uses solder bump is an essential technology to improve the performance of micro-electronics which require higher working speed, higher density, and smaller size. In this paper, the shear strength of Cr/Cr-Cu/Cu UBM structure of the high-melting solder bump and that of low-melting solder bump after aging is evaluated. Observe intermetallic compound and bump joint condition at the interface between solder and UBM by SEM and TEM. And analyze the shear load concentrated to bump applying finite element analysis. As a result of experiment, the maximum shear strength of Sn-97wt%Pb which was treated 900 hrs aging has been decreased as 25% and Sn-37wt%Pb sample has been decreased as 20%. By the aging process, the growth of $Cu_6/Sn_5$ and $Cu_3Sn$ is ascertained. And the tendency of crack path movement that is interior of a solder to intermetallic compound interface is found.

• Journal of Welding and Joining
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• v.26 no.5
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• pp.49-59
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• 2008

Hastelloy C-276, corrosion resistant alloy at high temperature, is used in chemical plant and power generation industry. In this study, process parameter of laser welding for welding property in Hastelloy C-276 using a continuous wave Nd:YAG laser was studied. As the result of experiment, laser welding did not show segregation or crack at heat affected zone compared to conventional GTWA welding. The melting zone showed cell dendritic structure along with welding line. In addition, planer front solidification is occurred from welding structure, and it was progressed to cellular solidification. Optimal process parameter for butt welding was 1.2kW and 2.0 m/min for laser power and welding speed, respectively. While heat input, output density, tensile stress, and longitudinal strain was $441.98{\times}103$ J/cm2, $29.553{\times}103$ W/cm2, 768 MPa, and 0.689, respectively. Lap welding of the same material showed greater discrepancy in tensile property during 1 line and 2 line welding. For 1 line welding, tensile stress was about 320 MPa, and 2 line showed slightly larger tensile stress. However, strain was decreased by 20%. From this result, lap welding of the same material, Hastelloy C-276, with 2 line welding is considered to be more effective process than 1 line welding with consideration of mechanical property.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.4
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• pp.365-372
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• 2018

3D printing technology of construction field can be divided into structural materials, interior and exterior finishing materials, and is mainly done by extruding and adapting. Particularly when it is applied as an exterior materials, it is mainly applied to an unstructured exterior materials and high accuracy is required. The exterior materials can be used as a cement composite materials, it is suitable also for a additive type manufacturing, and the role of a redispersible polymer powder is important. But, high temperatures, redispersible polymer cement base material beget dehydration and micro crack of cement matrix. In this research, we developed a EVA, EVCL redispersible polymer cement base material applicable as a 3D printing exterior materials, confirmed density and strength characteristics for application as an exterior materials, a flame retardancy test for improving the fire resistance of buildings and confirmed its possibility. From the test result, developed EVCL redispersible polymer cement mortar showed good stability in high temperatures. These high temperature stability is caused by the ethylene-vinyl chloride binding. Thus, this result indicates that it is possible to fire resistant 3D printing interior and exterior finishing materials.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.3
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• pp.243-251
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• 2022

The purpose of this study is to investigate experimentally the effect of polyethylene fibers with different tensile strength and aspect ratio on the properties of cementless composite. Three types of mixtures according to the types of polyethylene fibers and water-to-binder ratio were prepared and density, compressive strength and tension tests were performed. Test results showed that the mixture reinforced by polyethylene fiber with a low tensile strength by 10 % and a high aspect ratio by 8.3 % had a high tensile strain capacity by 11.7 %, a high toughness by 12.4 %, and a low crack width by 9.1 %. It was also observed that high tensile strain capacity and better cracking pattern could be achieved by increasing the water-to-binder ratio of composite although its strength is low.