• 한국분말재료학회지
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• 제19권4호
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• pp.297-303
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• 2012

In this study, voltammetry system for realizing high sensitivity nano-labeled sensor of detecting heavy metals was designed, and optimal system operating conditions were determined. High precision digital to analog converter (DAC) circuit was designed to control applied unit voltage at working electrode and analog to digital converter (ADC) circuit was designed to measure the current range of $0.1{\sim}1000{\mu}A$ at counter electrode. Main control unit (MCU) circuit for controlling voltammetry system with 150 MHz clock speed, main memory circuit for the mathematical operation processing of the measured current value and independent power circuit for analog/digital circuit parts to reduce various noise were designed. From result of voltammetry system operation, oxidation current peaks which are proportional to the concentrations of Zn, Cd and Pb ions were found at each oxidation potential with high precision.

• Fibers and Polymers
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• 제7권2호
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• pp.105-111
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• 2006

Coating the fibre surface by in situ oxidative chemical polymerisation of polypyrrole (using $FeCl_3$ as oxidant) is a readily industrial applicable way to give electrical properties to wool with good ageing stability [1], although pre-treatments are required to avoid damage of the cuticle surface due to the acidic condition of the process. FT-IR and EDX analysis reveal that organic sulphonates and sulphates, used as dopants, are absorbed by wool, while chlorine ions are preferably embedded on the polypyrrole layer. The resulting electrical conductivity seems mainly due to the presence of chlorine as counter-ion of polypyrrole; nevertheless, the presence of arylsulphonate in the polymerisation bath increases the electrical conductivity of the coating layer.

• 약학회지
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• 제27권2호
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• pp.125-131
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• 1983

Whether ($AB_{w}$) may be neglected against ($A_{w}^{+}$) in the calculation of the extraction coefficient of ion-pairs was criticized by both experiments and theoretical consideration, where ($AB_{w}$) and ($A_{w}^{+}$) mean the molar concentration of ion-pair AB and cation $A^{+}$ in the aqueous phase. Ion-pair complexes were partitioned between phosphate buffer (pH 7.4) and n-octanol. Tetrabutylammonium, isopropamide and methylene blue were selected as cations and benzoic acid, p-toluenesulfonic acid, salicylic acid and taurodeoxycholic acid were selected as counter ions (anions). As a result, conventional methods which assume no existence of ($AB_{w}$) were proven to lack generality. The equation proposed in my earlier report was confirmed to be valid as a general method.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2008년도 추계학술대회 초록집
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• pp.105-106
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• 2008

Nanotube morphology change of Ti-Ta-Zr alloy as Zr content increase has been researched using various experimental methods. Ti-Ta-Zr(3, 7 and 15 wt%) alloys were prepared by arc melting and nano-structure controlled for 24 hr at $1000^{\circ}C$ in argon atmosphere. Formation of oxide nanotubes are conducted by anodizing a Ti-Ta-Zr alloy in $H_3PO_4$ electrolytes with small amounts of fluoride ions at room temperature. Electrochemical experiments were carried out with conventional three-electrode configuration with a platinum counter electrode and a saturated calomel reference electrode. The samples were embedded with epoxy resin, leaving a square surface area of $10mm^2$ exposed to the anodizing electrolyte, 1.0M $H_3PO_4$ containing 0.8wt% NaF.

• Bulletin of the Korean Chemical Society
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• 제20권11호
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• pp.1303-1308
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• 1999

Conducting poly(3,4-ethylenedioxythiophene) (PEDT) films with metalloporphyrins incorporated as the counter ions were prepared by electropolymerization of the monomer in the presence of metal-tetra(sulfonatophenyl) porphyrin anions. Cathodic reduction of oxygen on the resulting conducting polymer films was studied. The overpotential for O2 reduction on electrodes with cobalt-porphyrin complex was significantly smaller in acidic solutions than on gold. In basic solutions, the overpotential at low current densities was close to those on platinum and gold. Polymer electrode with Co-complex yielded higher limiting currents than with Fe-complex, although the Co-complex polymer electrode was a poorer electrocatalyst for O2 reduction in the activation range of potential than the Fe counterpart. From the rotating ring-disk electrode experiments, oxygen reduction was shown to proceed through either a 4-electron pathway or a 2-electron pathway. In contrast to the polypyr-role-based electrodes, the PEDT-based metalloporphyrin electrodes were stable with wider potential windows, including the oxygen reduction potential. Their electrocatalytic properties were maintained at temperatures up to 80℃ in KOH solutions.

• 분석과학
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• 제10권5호
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• pp.343-349
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• 1997

역상 이온쌍 고성능액체크로마토그래피(RP-IPC)에 의한 살균제 농약 kasugamycin(5-amino-2-methy-6-(2,3,4,5,6-pentahydroxy cyclohexyloxy) tetrahydropyran-3-yl-amino-${\alpha}$-iminoacetic acid)의 정량분석법을 확립하였다. Ksugamycin의 정량분석법을 확립하기 위해 RP-IPC에서 organic modifier의 농도, 용리액의 pH 및 상대이온(counter ion)의 종류와 농도에 의한 시료의 머무름 거동에 대한 영향을 조사 검토하였다. 확립된 최적 변수를 바탕으로 개발된 이 분석법은 kasugamycin의 품질관리에 활용할 수 있음을 확인하였다.

• 폴리머
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• 제35권2호
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• pp.171-175
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• 2011

Isophorone diisocyanate(IPDI), polytetramethylene glycol 1000(PTMG 1000), 그리고 N-methyl diethanol amine(MDEA)을 사용하여 양이온성 수분산 폴리우레탄을 제조하였다. 중화제와 사슬연장제의 구조변화에 따른 입도, 점도, $T_g$, 인장강도 그리고 수 팽윤도와 같은 물성의 변화를 알아보기 위해 여러 가지 중화제와 사슬연장제를 도입하였다. Acetic acid(AA)를 사용하여 중화한 수분산 폴리우레탄은 전형적인 elastomer의 거동을 보이는 반면, hydrochloric acid (HCI)로 중화한 경우에는 crystalline polymer의 거동을 보였다. 사슬연장제 중에서는 isophorone diamine(IPDA)이 가장 우수한 기계적 물성을 나타내었다. HCl로 중화하였을 경우 acetic acid로 중화하였을 때보다 압도가 감소함을 확인하였는데 이는 중화제의 반대이온(counter ion) 크기 차이 때문으로 여겨지며 hydrazine으로 사슬연장하였을 때 가장 작은 입도값을 나타내었다.

• 전기전자학회논문지
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• 제24권1호
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• pp.132-139
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• 2020

공기청정기에 사용되는 이오나이저 모듈은 권선형 transformer를 사용하여 방전전극인 HV+/HV-에 3.5KV/-4KV의 고전압을 공급하여 carbon fiber brush의 전계 방사에 의해 양이온과 음이온을 발생시킨다. 기존의 MCU를 이용한 이오나이저 모듈 회로는 PCB 사이즈가 크고 가격이 비싼 단점이 있고, 기존의 ring oscillator를 이용한 게이트 구동 칩은 oscillation 주기가 PVT(Process-Voltage-Temperature) 변동에 민감하고 HV+와 GND, HV-와 GND의 단락에 의한 fault detection 기능이 없으므로 화재나 감전의 위험이 있다. 그래서 본 논문에서는 7bit binary UP counter를 이용하여 PVT 변동이 있더라도 oscillation 주기를 조절하여 HV+ 전압이 목표 전압에 도달하게 한다. 그리고 HV+와 GND 사이의 단락을 검출하기 위한 HV+ short fault detection 회로, HV-와 GND 사이의 단락을 검출하기 위한 HV- short fault detection 회로와 HV+가 과전압 이상으로 올라가는 것을 검출하기 위한 OVP(Over-Voltage Protection) 회로를 새롭게 제안하였다.

• Bulletin of the Korean Chemical Society
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• 제9권6호
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• pp.338-341
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• 1988

Two crystal structures of fully dehydrated silver and potassium exchanged zeolite A, stoichiometries of $Ag_{9.3}K_{{2.7}^-}A$ (${\alpha}$ = 12.282(2) ${\AA}$) and $Ag_{10.7}K_{{1.3}^-}{\AA}$ (${\alpha}$ = 12.287(2) A) per unit cell, have been determined from 3-dimensional x-ray diffraction data gathered by counter methods. All structures were solved and refined in the cubic space group Pm3m at 21(1)$^{\circ}C$ . The crystals of $Ag_{9.3}K_{{2.7}^-}A$ and $Ag_{10.7}K_{{1.3}^-}A$ were prepared by flow method using exchange solutions in which mole ratios of $AgNO_3$ and $KNO_3$ were 1:10 and 1:5, respectively, with total concentration of 0.05M. The structures of the dehydrated $Ag_{9.3}K_{{2.7}^-}A$ and $Ag_{10.7}K_{{1.3}^-}A$ were refined to yield the final error indices $R_1$ = 0.037 and $R_2$ = 0.040 with 321 reflections, and $R_1$ = 0.042 and $R_2$ = 0.043 with 371 reflections, repectively, for which I > 3${\sigma}$(I). In both structures, eight $Ag^+$ ions are found nearly at 6-ring centers and each $Ag^+$ ion is nearly in the (1 1 1) plane at its O(3) ligands. The 8-ring sites are preferentially occupied by $K^+$ ions in both structures. 1.3 and 1.7 reduced silver atoms per unit cell were found inside of sodalite units of $Ag_{9.3}K_{{2.7}^-}A$ and that of $Ag_{10.7}K_{{1.3}^-}A$, respectively. These reduced silver species were presumably formed from the reduction of $Ag^+$ ions by oxide ions of residual water molecule or of the zeolite framework. These two crystals may be presented as hexasilver cluster in 21.7% and 28.3% of sodalite unit cells for $Ag_{9.3}K_{{2.7}^-}A$ and $Ag_{10.7}K_{{1.3}^-}A$, repectively.

• 센서학회지
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• 제23권3호
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• pp.197-201
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• 2014

TEPC (Tissue Equivalent Proportional Counter) was usually used for high LET radiation dosimetry. We developed a prototype TEPC for micro-dosimetry in the range of $0.2{\sim}300 keV/{\mu}m$. And, the simulated site diameter of the TEPC is $2{\mu}m$, of similar size to a cell nucleus. For purposes of characterization the response for high LET radiation of the TEPC has been investigated under 135MeV/u Carbon ions in HIMAC (Heavy Ion Medical Accelerator). We determined the gas multiplication factor and measured the lineal energy spectrum [yd(y)] of 135 MeV/u Carbon ions. The value of the gas multiplication factor was 315 at 700 V bias voltage. As a result of the experiment, we could more understand the performance of the TEPC for high LET (Linear Energy Transfer) radiation. And the procedure of high LET radiation dosimetry using TEPC is established.