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A Study on Voltammetry System Design for Realizing High Sensitivity Nano-Labeled Sensor of Detecting Heavy Metals

중금속 검출용 고감도 나노표지센서 구현을 위한 볼타메트리 시스템 설계 연구

  • Received : 2012.07.10
  • Accepted : 2012.08.08
  • Published : 2012.08.28

Abstract

In this study, voltammetry system for realizing high sensitivity nano-labeled sensor of detecting heavy metals was designed, and optimal system operating conditions were determined. High precision digital to analog converter (DAC) circuit was designed to control applied unit voltage at working electrode and analog to digital converter (ADC) circuit was designed to measure the current range of $0.1{\sim}1000{\mu}A$ at counter electrode. Main control unit (MCU) circuit for controlling voltammetry system with 150 MHz clock speed, main memory circuit for the mathematical operation processing of the measured current value and independent power circuit for analog/digital circuit parts to reduce various noise were designed. From result of voltammetry system operation, oxidation current peaks which are proportional to the concentrations of Zn, Cd and Pb ions were found at each oxidation potential with high precision.

Keywords

References

  1. J. Wang, J. Lu, S. B. Hocevar and P. A. M. Farias: Anal. Chem., 72 (2000) 3218. https://doi.org/10.1021/ac000108x
  2. J. Wang, J. Lu, S. B. Hocevar and B. Ogorevc: Electroanal., 13 (2001) 13. https://doi.org/10.1002/1521-4109(200101)13:1<13::AID-ELAN13>3.0.CO;2-F
  3. J. Wang, J. Lu, Ü. A. Kirgöz, S. B. Hocevar and B. Ogorevc: Anal. Chim. Acta, 434 (2001) 29. https://doi.org/10.1016/S0003-2670(01)00818-2
  4. G. Kefala, A. Economou, A. Voulgaropoulos and M. Sofoniou: Talanta, 61 (2003) 603 https://doi.org/10.1016/S0039-9140(03)00350-3
  5. G. Kefala, A. Economou and A. Voulgaropoulos: Analyst, 129 (2004) 1082. https://doi.org/10.1039/b404978k
  6. J. Kruusma, C. E. Banks and R. G. Compton: Anal. Bioanal. Chem., 379 (2004) 700.
  7. J. Wang: Electroanal., 17 (2005) 1341. https://doi.org/10.1002/elan.200403270
  8. C. E Banks, J. Kruusma, R. R. Moore, P. Tomeik, J. Peters, J. Davis, S. Komorsky-Lovrie and R. G. Compton: Talanta, 65 (2005) 423. https://doi.org/10.1016/j.talanta.2004.06.038
  9. J. Wang: Electroanal., 17 (2005) 1341. https://doi.org/10.1002/elan.200403270
  10. R. Pauliukaite and C. M. A. Brett: Electroanal., 17 (2005) 1354. https://doi.org/10.1002/elan.200403282
  11. I. Svancara, L. Baldrianova, E. Tesarova, S. B. Hocevar, S. A. A. Elsuccary, A. Economou, S. Sotiropoulos, B. Ogorevc and K. Vytras: Electroanal., 18 (2006) 177. https://doi.org/10.1002/elan.200503391
  12. G.-J. Lee, H. M. Lee and C. K. Rhee: Electrochem. Commun., 9 (2007) 2514. https://doi.org/10.1016/j.elecom.2007.07.030
  13. G.-J. Lee, H. M. Lee, Y. R. Uhm, M. K. Lee and C. K. Rhee: Electrochem. Commun., 10 (2008) 1920. https://doi.org/10.1016/j.elecom.2008.10.015
  14. H. M. Lee, G.-J. Lee, H. J. Kim, Y. R. Uhm, H. J. Kim, M. K. Lee and C. K. Rhee: J. Nanosci. Nanotechnol., 10 (2010) 309. https://doi.org/10.1166/jnn.2010.1502
  15. G.-J. Lee, C. K. Kim, M. K. Lee and C. K. Rhee: Electroanal., 22 (2010) 530. https://doi.org/10.1002/elan.200900356
  16. G.-J. Lee, C. K. Kim, M. K. Lee and C. K. Rhee: J. Electrochem. Soc., 157(7) (2010) J241. https://doi.org/10.1149/1.3413998
  17. G.-J. Lee, C. K. Kim, M. K. Lee and C. K. Rhee: J. Korean Phys. Soc., 57(6) (2010) 1667. https://doi.org/10.3938/jkps.57.1667
  18. G.-J. Lee, C. K. Kim, M. K. Lee and C. K. Rhee: Talanta, 83 (2010) 682. https://doi.org/10.1016/j.talanta.2010.10.007
  19. D. Krulic, N, Fatouros and J. Chevalet: J. Electroanal. Chem., 287 (1990) 215. https://doi.org/10.1016/0022-0728(90)80003-O
  20. D. Desmond, B. Lane, J. Alderman, M. Hill, D. W. M. Arrigan and J. D. Glennon: Sensors and Actuators B, 48 (1998) 409. https://doi.org/10.1016/S0925-4005(98)00078-1
  21. Gunther Weber and Jurgen Messerschmidt: Analytica Acta, 545 (2005) 166. https://doi.org/10.1016/j.aca.2005.04.082
  22. Djenaine De Souza, Dergio A. S. Machado and Roberto C. Pires: Talanta, 69 (2006) 1200. https://doi.org/10.1016/j.talanta.2005.12.045
  23. K. Christidis, P. Robertson, K. Gow and P. Plooard: J. measurement, 40 (2007) 690.
  24. Anastasiadou Z. D., Sipaki I. and P. D. Jannakoudakis: Analytical letters, 44(5) (2011) 761. https://doi.org/10.1080/00032711003790023