• Corrosion Science and Technology
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• v.15 no.1
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• pp.28-37
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• 2016

Due to the increased construction of offshore concrete structures and the use of de-icing salts for the purpose of snow removal, the needs for the development of anti-corrosive concrete are increasing. To solve these problems, an evaluation of the mechanical and durability properties for concrete were conducted by mixing modified-sulfur as 0 %, 5 %, 10 %, 15 % cement weight ratio. Both strengths and the properties affecting durability such as water absorption coefficient, chloride ion permeability, accelerated carbonation resistance, rapid freezing and thawing, and chemical resistance were evaluated. All evaluations performed were according to the test specifications associated KS. The results indicate that mixing of modified-sulfur lowed chloride ion permeability and improved chemical resistance.

• Proceedings of the KSR Conference
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• 2002.10a
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• pp.31-37
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• 2002

Rail cars are subject to vibration, impact and wear which can cause severe defects leading to a fatal accident. Thus, they are designed and manufactured in consideration of such factors influencing their service lifetime. Under-frames are composed of steel and support most of load imposed on the car. Steel is very sensitive to corrosive environment and corroded even in a normal service condition. Regular maintenance can Protect steel Parts from corrosion by painting. However, an exposure of defect point to corrosive agents can make corrosion proceed to a considerable depth, which may cause the structure to remain under safety standard. It is necessary to understand corrosion behavior of rail cars in order to estimate unexpected accidents by corrosion.

• Microbiology and Biotechnology Letters
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• v.51 no.4
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• pp.425-431
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• 2023

The biopolymer produced by Lysinibacillus macroides can be useful as an emulsifying agent, flocculating agent, anti-oxidative agent, and anti-corrosive agent. The present work focused on the functional activities of this biopolymer such as bioflocculant and anti-corrosion. The results of the study for the biopolymer as a bioflocculating agent reveal that the biopolymer gave 72.3% flocculating activity against activated carbon at a concentration of 5 mg/l. In the optimization study, the highest bioflocculant activity was obtained in the presence of CaCl₂ mineral at 15% biopolymer concentration, 7.0 pH, and 40℃ temperature. The biopolymer was also studied for its anti-corrosive nature and observed that it was able to prevent corrosion of steel paper clips in a 6% CaCl₂ solution at a concentration of 0.5% after 7 days.

• Computers and Concrete
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• v.20 no.2
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• pp.205-214
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• 2017

The Hydraulically driven test system and ${\Phi}100mm$ split Hopkinson pressure bar(SHPB) test device were employed to research the quasi-static and dynamic mechanical properties of concrete specimens which has been immersed for 60 days in sodium sulfate (group S1) and sodium chloride (group S2) solution, the evolution of their mass during corrosive period was explored at the same time, and the mechanism of performances lost was analyzed from the microscopic level by using scanning electron microscope. Results of the experimental indicated that: their law of mass both presents the trend of continuous rising during corrosive period, and it increases rapidly on the early days, the mass growth of group S1 and group S2 in first 7 days are 76.78% and 82.82% of their total increment respectively; during the corrosive period, the quasi-static compressive strength of specimens in two groups are significantly decreased, both of which present the trend of increase first and then decrease, the maximum growth rate of group S1 and group S2 are 7.52% and 12.71% respectively, but they are only 76.23% and 82.84% of specimens which under normal environment (group N) on day 60; after immersed for 60 days, there were different decrease to dynamic compressive strength and specific energy absorption, and so as their strain rate sensitivities. So the high salinity environment has a significant effect of weaken the quasi-static and dynamic mechanical performance of concrete.

• Corrosion Science and Technology
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• v.17 no.2
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• pp.68-73
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• 2018

Substitution of hip and knee joints by CoCr alloys is in great demand due to their high wear resistance and good biocompatibility. Understanding of tribocorrosion in joint replacements requires study of variables such as coefficient of friction and the choice of a proper corrosive medium in wear-corrosion tests carried out in the lab. The objective of this study was to characterize tribocorrosion behaviour of CoCr alloy with low (LCCoCr) and high carbon (HCCoCr) contents in several corrosive media: NaCl, Phosphate Buffer Solution (PBS), and PBS with hyaluronic acid (PBS-HA). Tribocorrosion tests were carried out on a pin-on-disk tribometer with an integrated electrochemical cell. A normal load of 5N was applied on the alumina ball counterpart at a rotation rate of 120 rpm. Coefficient of friction (COF) was measured and tribocorrosion behaviour was characterized by in situ application of electrochemical techniques. HCCoCr alloy immersed in PBS-HA showed the best tribocorrosion behaviour with the lowest COF. In this case, in situ measurement of corrosion potential and the impedance data under wear corrosion process showed an active state while passive film was continuously destroyed without possibility of regeneration.

• Journal of the Korean Society for Precision Engineering
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• v.29 no.4
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• pp.409-416
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• 2012

Recently, surface modification technology is of importance to improve the wear resistance and the corrosive resistance for high accurate mechanical parts such as LM guide, Ball Screw and Roller Bearing etc., Those has generally featured on rolling contact mechanism to improve not only the wear and the friction, but also the accuracy and the corrosion performances. For surface modifications of high accurate mechanical parts, normally thermal spray, PVD, CVD and E.P. processes have been used with many materials such as DLC, raydent, W, Ni, Ti etc. Diamondlike carbon (DLC) films possess a combination of attractive properties and have been largely employed to modify the tribological behaviors such as friction, wear, corrosion, fretting fatigue, biocompatibility, etc. However, for rolling contact mechanism mechanical parts DLC films are needed to study for commercial benefit. Rolling contact mechanism has features on effects of cyclic motions and stresses, and also not simply sliding motions. The papers focused on the performance test of wear and corrosive resistance according to Me-DLC film thickness. And also, its thickness effect of wear analysis was carried out through the simulation of the maximum shear stress under the rolling contact surface. As the results, Me-DLC films have more potential to improve the wear resistance for high precision mechanical parts than raydent films.

• Journal of the Korean Society for Nondestructive Testing
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• v.31 no.5
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• pp.543-551
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• 2011

Steam generator tubes for nuclear power plants contain the local shape transitions on their inner or outer surface such as dent, bulge, over-expansion, eccentricity, deflection, and so on by the application of physical force during the tube manufacturing and steam generator assembling and by the sludge (that is, corrosion products) produced during the plant operation. The structural integrity of tubes will be degraded by generating the corrosive crack at that location. The profilometry using the traditional bobbin probes which are currently applied for measuring the profile change of tubes gives us basic information such as axial locations and average magnitudes of deformations. However, the three-dimensional quantitative evaluation on circumferential locations, distributional angle, and size of deformations will have to be conducted to understand the effects of residual stresses increased by local deformations on corrosive cracking of tubes. Steam generator tubes of Korean standard nuclear power plants expanded within their tube-sheets by the explosive expansion method and suffered from corrosive cracks in the early stage of power operation. Thus, local deformations of steam generator tubes at the top of tube-sheet were measured with an advanced rotating probe and a laser profiling system for the two cases where the tubes expanded by the explosive expansion method and hydraulic expansion. Also, the trends of eccentricity, deflection, and over-expansion of tubes were evaluated. The advanced eddy current profilometry was confirmed to provide accurate information of local deformations compared with laser profilometry.

• Toxicological Research
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• v.32 no.4
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• pp.311-316
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• 2016

Effects of nanoparticles (NPs) on skin corrosion and irritation using three-dimensional human skin models were investigated based on the test guidelines of Organization for Economic Co-operation and Development (OECD TG431 and TG439). EpiDerm$^{TM}$ skin was incubated with NPs including those harboring iron (FeNPs), aluminum oxide (AlNPs), titanium oxide (TNPs), and silver (AgNPs) for a defined time according to the test guidelines. Cell viabilities of EpiDerm$^{TM}$ skins were measured by the 3-(4, 5-dimethylthiazol-2-yl)-2.5-diphenyltetrazolium bromide based method. FeNPs, AlNPs, TNPs, and AgNPs were non-corrosive because the viability was more than 50% after 3 min exposure and more than 15% after 60 min exposure, which are the non-corrosive criteria. All NPs were also non-irritants, based on viability exceeding 50% after 60 min exposure and 42 hr post-incubation. Release of interleukin 1-alpha and histopathological analysis supported the cell viability results. These findings suggest that FeNPs, AlNPs, TNPs, and AgNPs are 'non-corrosive' and 'non-irritant' to human skin by a globally harmonized classification system.

• Journal of Advanced Marine Engineering and Technology
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• v.39 no.5
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• pp.536-541
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• 2015

Copper has been used extensively as an electric wire or as a base material in various types of machineries owing to its good electrical and thermal conductivity and good fabricating property, as well as its good corrosion resistance compared to iron. Furthermore, the copper-nickel alloy has significant corrosion resistance in severely corrosive environments. Although, cupro-nickel alloy shows better corrosion resistance than the brass and bronze series, this alloy also corroded in severely corrosive environments, including aggressive chloride ions, dissolved oxygen, and condition of fast flowing seawater. In this study, and annealing treatment at various annealing temperatures was carried out on the cupro-nickel (Cu-10%Ni) alloy, and the effects of annealing were investigated using electrochemical methods, such as measuring the polarization and impedance behaviors under flowing seawater conditions. The corrosion resistance increased by annealing compared to non heat treatment in the absence of flowing seawater. In particular, the sample annealed at $200^{\circ}C$ exhibited the best corrosion resistance. The impedance in the presence of flowing seawater showed higher values than in the absence of flowing seawater. Furthermore, the highest impedances was observed in the sample annealed at $800^{\circ}C$, irrespective of the present of flowing seawater. Consequently, the corrosion resistance of cupro-nickel (Cu-10%Ni) alloy in a severely corrosive environment can be improved somewhat by annealing.

• Journal of Technologic Dentistry
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• v.34 no.4
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• pp.337-344
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• 2012

Purpose: This study examined the corrosion level by alloy type and pH, and used the corrosion levels as the dental health data. The study utilized one Ni-Cr alloy for the full and removable partial denture metal frameworks and two Ni-Cr alloys for porcelain-fused-to-metal crown, among the non-beryllium dental casting non-precious Ni-Cr alloys. Methods: The alloy specimens were manufactured in $10cm^2$ and stored in the corrosive solution(pH 2.2-4.4) in the electrical water bath($37^{\circ}C$) for seven days. Afterwards, the metal ions were quantitatively analyzed using the ICP. Results: Of the three metal alloys, Bellabond-Plus$^{(R)}$alloy and SOLIBOND N$^{(R)}$alloy, with 22% or higher chrome chemical contents, had higher corrosion resistance than Jdium-100$^{(R)}$alloy with 20% chrome chemical content. In all three alloys, the corrosion of Ni was highest, and metal ion corrosion was higher in the pH 2.2 corrosive solution. Conclusion: Although Ni-Cr alloy was not very corrosive, a Ni-allergic patient should not have Ni-Cr alloy prosthesis. The Ni-Cr alloy for porcelain-fused-to-metal crown should be designed for the dental porcelain to cover the whole crown.