• Title/Summary/Keyword: corrosion effect

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Penetration Properties of Airborne Chlorides on Concrete Exposed in Marine Environment (해안환경에 노출된 콘크리트의 비래염분 침투 특성)

  • Lee, Jong-Suk;An, Gi-Hong
    • Journal of the Korea Concrete Institute
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    • v.24 no.5
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    • pp.553-558
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    • 2012
  • Airborne chlorides are transported to inland by sea wind to be attached to seashore concrete structure surface then penetrated into concrete structure members. Since the surface attached chloride amount are dependent on the amount of airborne chlorides, the prediction of distribution of airborne chlorides is important information in preventing chloride corrosion problems in seashore concrete structures. The prediction of surface chloride amount from airborne chlorides environment is extremely difficult than concrete directly in contact with seawater. In addition, their penetrating tendency is different from that of concrete immersed in seawater. In this study, properties of surface and penetrated chlorides under airborne chlorides environment are investigated. Concrete specimens were manufactured and exposed to marine environment for 3 years. The specimens were analyzed at the time durations of 1, 2, and 3 years to check surface chloride amount to penetrated chloride depth. The results revealed that there were certain differences according to surface roughness of concrete and with and without washing effect due to rainfalls. The evaluation results showed that penetrated chlorides depend on amount of airborne chlorides and duration of exposure. In addition, a notable tendency of having deeper chloride penetration and higher chloride content in concrete members under long-term exposure was observed.

The effect of acidic drinks on the surface of tooth-colored restorative materials (산성음료가 치아색 수복재의 표면에 미치는 영향)

  • Bang, Seok-Yun;Kim, Eun-Jung;Kim, Hyun-Jung;Nam, Soon-Hyeun;Kim, Young-Jin
    • Journal of the korean academy of Pediatric Dentistry
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    • v.33 no.3
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    • pp.469-481
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    • 2006
  • Among the etiologic factors of enamel corrosion, daily intake has been considered with a profound interest, especially the intake of acidic drinks. It is thought that the rapid consumption of acidic drinks will not only results in the affection to the teeth but also to the surface of the tooth-colored restorative materials. Therefore, the puopose of this study is to examine the alterations occurred in the surface of the tooth-colored materials according to the exposed time, with 3 most common acidic drinks in contact with daily life. Resin-modified glass-ionomer, polyacid-modified composite resin, composite resin were immersed on 0.9% NaCl, Coke, orange juice, sports beverages as 4 groups in each. The surface hardness and the surface roughness of specimens were measured with following methods: before immersion, 1 day after immersion, 1-,2-,3-,4- weeks after immersion. Results were as follows. 1. Tooth-colored restorative materials, with the exception of composite resin, showed statistically significant changes in surface hardness and roughness when immersed on acidic drinks(p<0.05). 2. The degree of change in surface hardness and roughness occurred as follows, in order of severity from greatest to least resin-modified glass-ionomer, polyacid-modified composite resin, composite resin 3. Sports beverages resulted in greater alterations to surfaces than Coke and orange juice. 4. In the SEM image of the groups immersed in acidic drinks, resin-modified glass-ionomer and polyacid-modified composite resin showed loss of filer. Severe cracks were observed, especially on the resin-modified glass-ionomer.

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Engineering Characteristics of Liquid Filler Using Marine Clay and In-situ Soil (해양점토와 현장토를 활용한 유동성 채움재의 공학적 특성)

  • Oh, Sewook;Bang, Seongtaek
    • Journal of the Korean GEO-environmental Society
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    • v.21 no.9
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    • pp.25-32
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    • 2020
  • The underground utilities installed under the ground is an important civil engineering structure, such as water supply and sewerage pipes, underground power lines, various communication lines, and city gas pipes. Such underground utilities can be exposed to risk due to external factors such as concentrated rainfall and vehicle load, and it is important to select and construct an appropriate backfill material. Currently, a method mainly used is to fill the soil around the underground utilities and compact it. But it is difficult to compact the lower part of the buried pipe and the compaction efficiency decreases, reducing the stability of the underground utilities and causing various damages. In addition, there are disadvantages such as a decrease in ground strength due to disturbance of the ground, a complicated construction process, and construction costs increase because the construction period becomes longer, and civil complaints due to traffic restrictions. One way to solve this problem is to use a liquid filler. The liquid filler has advantages such as self-leveling ability, self-compaction, fluidity, artificial strength control, and low strength that can be re-excavated for maintenance. In this study, uniaxial compression strength test and fluidity test were performed to characterize the mixed soil using marine clay, stabilizer, and in-situ soil as backfill material. A freezing-thawing test was performed to understand the strength characteristics of the liquid filler by freezing, and in order to examine the effect of the filling materials on the corrosion of the underground pipe, an electrical resistivity test and a pH test were performed.

Structural Behavior of the Reinforced Concrete Filled GFRP Tube (GFRP 보강 철근콘크리트 합성부재의 구조적 거동)

  • Lee, Seung-Sik;Joo, Hyung-Joong;Kang, In-Kyu;Yoon, Soon-Jong
    • Composites Research
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    • v.23 no.4
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    • pp.44-51
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    • 2010
  • Recently, to solve the problems associated with the neutralization and corrosion of reinforced concrete compression members, the structural configurations such as CFFT (Concrete Filled GFRP Tube) and RCFFT (Reinforced Concrete Filled GFRR Tube) have been developed and applied to main members of civil engineering structure. These members can increase structural performance in terms of structural stability, ductility as well as chemical resistance compared with conventional concrete structural members. Many researches in numerous institutions to predict the load carrying capacity of the concrete compression member strengthened with FRP materials have been conducted and they have been suggested an equation for the prediction of the load carrying capacity of the members. Through the review of the research results, it was found that their results are similar each other. Moreover, it was also found that the results are not directly applicable to our specimens since the results are largely depended upon the member configurations. Also, since the accurate design criteria for the RC members strengthened with FRP such as RCFFT have not been established properly, relevant theoretical and experimental investigations must be conducted for the application to the practical structures. In this study, structural behavior of RCFFT was evaluated through compressive and quasi-static flexural tests in order to formulate design criteria for the structural design. In addition, the RCFFT members were also investigated to examine their confinement effect and the equations capable of estimating the compressive ultimate strength and flexural stiffness of the RCFFT members were proposed.

Conservation of Iron Dagger & Scabbard Excavated in Daho-ri, Changwon (다호리 출토 칠초철검(漆鞘鐵劍)의 보존)

  • Sim, Myungbo;Lim, Jihyun;Ma, Daewan;Kim, Midori
    • Conservation Science in Museum
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    • v.12
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    • pp.19-24
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    • 2011
  • This study presents an investigation into the conservation process of an iron dagger and scabbard, which are a lacquered scabbard and a dagger inserted in it, excavated in the Daho-ri relic of Changwon by Gimhae National Museum. The bronze dagger whose condition was poor due to corrosion was coated with Incralac, an intensifier, to reveal the surface patterns through a microscope. The lacquered scabbard was removed of foreign substances on the surface and coated with HPC 2%(in water) to protect the film. Applied onto the surface from which foreign substances were removed was Caparol Binder 5%(in water) two to three times to form a protective film and then faced with Korean paper. Once it was fixed in a polyurethane foam in a stable manner, it was turned over to receive the same process on the back. Three layers of Korean paper were attached to the back of the scabbard to support the thin artifact. HPC 2%(in water), which was applied to the scabbard, was also applied to the iron dagger inside for cementing effect. After all the processes were completed, the artifact was put in a transparent acrylic box for future display.

Effect of Heat Treatment on the Formation Behavior of Intermetallic Compound Layer in Fusion Bonding of Cast Iron and Al Alloy (용융 접합한 주철 - Al 합금의 금속간화합물 층 형성 거동에 미치는 열처리의 영향)

  • Kang, Sung-Min;Han, Kwang-Sik;Kang, Yong-Joo;Kim, Kwang-Won;Im, Ye-Ra;Moon, Ji-Sun;Son, Kwang-Suk;Kim, Dong-Gyu
    • Journal of Korea Foundry Society
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    • v.32 no.1
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    • pp.50-56
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    • 2012
  • Fusion bonding of cast iron and Al alloy is an effective way to improve the properties such as low inertia, high efficiency and corrosion resistance in machinery parts. In case of fusion bonding, intermetallic compound layers are formed at the interface between cast iron and Al alloy interface. It is important to control the intermetallic compound layers for improving bonding strength. The formation behavior of intermetallic compound layer by heat treatment has been investigated. Heat treatment was performed at temperature from $600^{\circ}C$ to $800^{\circ}C$ with $100^{\circ}C$ interval for an hour to investigate the phase transformation during heat treatment. Heat treated specimens were analyzed by using FE-SEM, EPMA and EDS. The EPMA/WDS results revealed that various phases were formed at the interface, which exhibited 4 distinct intermetallic compound layers such as ${\tau}_6-Al_{4.5}FeSi$, ${\tau}_2-Al_3FeSi$, ${\tau}_{11}-Al_5Fe_2Si $and ${\eta}-Al_5Fe_2$. Also, fine precipitation of ${\tau}_1-Al_2Fe_3Si_3$ phase was formed between ${\tau}_{11}$ and ${\eta}$ layer. The phase fraction in intermetallic compound layer was changed by heat treatment temperature. At $600^{\circ}C$, intermetallic compound layer of ${\tau}_6$ phase was mainly formed with increasing heat treatment time. With increasing heat treatment temperature to $800^{\circ}C$, however, ${\tau}_2$ phase was mainly distributed in intermetallic compound layer. ${\tau}_1$ phase was remarkably decreased with increasing heat treatment time and temperature.

A Study on the Mechanical Properties of Fiber Reinforced Concrete by Kenaf Dosages (양마의 혼입량에 따른 섬유보강 콘크리트의 역학적 특성에 관한 연구)

  • Kwon, Yeong-Ho;Jun, Woo-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.1
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    • pp.19-25
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    • 2014
  • The purpose of this study is to establish experimentally the mechanical properties of fiber reinforced concrete using kenaf dosages and propose the usable method of kenaf fiber in the concrete industry as natural fiber materials. Kenaf fiber help make the concrete strength including tensile and flexural stronger, more resistant to plastic and drying shrinkage, less amount of carbon dioxide because of having a rough surface and excellent tensile strength of fiber and improving the concrete's corrosion resistance. It is to select the kenaf dosages of 4 cases (0, 0.3, 0.6 and $0.9kg/m^3$ and perform various tests including slump, air content, plastic and drying shrinkage, flexural and tensile strength for fiber reinforced concrete. The results of this study are as follows : In case of increasing kenaf fiber dosages, show the slump decrease and air content increase, also take effect results for increasing concrete strength including flexural and tensile, decreasing plastic and drying shrinkage. therefore, considered test results and cost, the optimum dosages of kenaf fiber is proposed about $0.6kg/m^3$ and need to study on the site application considering concrete quality and another compared tests.

Chemical Effects on Head Loss across Containment Sump Strainer under Post-LOCA Environment (LOCA이후 환경에서 원자로건물집수조 여과기의 수두손실에 대한 화학적 영향)

  • Ku, Hee-Kwon;Jung, Bum-Young;Hong, Kwang;Jeong, Eun-Sun;Jung, Hyun-Jun;Park, Byung-Gi;Rhee, In-Hyoung;Park, Jong-Woon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.11
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    • pp.3260-3268
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    • 2009
  • A test apparatus has been fabricated to simulate chemical effect on head loss through a strainer in a pressurized water reactor (PWR) containment water pool after a loss of coolant accident (LOCA). Tests were conducted under condition of same ratio of strainer surface area to water volume between the test appratus and the containment sump. A series of tests have been performed to investigate the effects of spray, existence of calcium-silicate with tri-sodium phosphate (TSP), and composition of materials. The results showed that head loss across the chemical bed with even a small amount of calcium-silicate insulation instantaneously increased as soon as TSP was added to the test solution. Also, the head loss across the test screen is strongly affected by spray duration and is increased rapidly at the early stage, because of high dissolution and precipitation of aluminum and zinc. After passivation of aluminum and zinc by corrosion, the head loss increase is much slowed down and is mainly induced by materials such as calcium, silicon, and magnesium leached from NUKONTM and concrete. Furthermore, it is newly found that the spay buffer agent, tri-sodium phosphate, to form protective coating on the aluminum surface and reduce aluminum leaching is not effective for a large amount of aluminum and a long spray.

An Analysis of the Application Technology of Heat Recovery System from Dyeing Wastewater (염색폐수 열회시스템 적용기술 분석)

  • 장기창;박성룡;이상남;라호상;박준택;함성원;박영태
    • Journal of Energy Engineering
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    • v.10 no.3
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    • pp.195-205
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    • 2001
  • A great deal of energy is necessary with emission of lots of wastewater in dyeing and finishing process, but heat recovery from wastewater is not introduced since is technology is not developed yet. In order to obtain the method utilizing hot water produced by heat source, that is, dyeing wastewater it was investigated the characteristics of dyeing and finishing process and energy basic unit. Energy basic unit of polyester/cotton (T/C), polyester/rayon (T/R) and polyester dyeing process are higher than that of the other process. The average quantity of wastewater for each dyeing company is 20,470 ton/month, the average temperature of wastewater is about 41$^{\circ}C$. Because the SS solution of wastewater in polyester dyeing process is lower than that of the other process, the effect of corrosion in heat recovery system is low. Since the energy price for 1000 kcal produced by vapor compression heat pump is presumed to be 22.50 won, it is found to be very economic heat recovery system, and its payback is 2.09 years for the factory with LNG boiler.

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Influence of the Dental Implant Abutment Screw Coating Materials on Joint Stability (임플란트 지대주나사 코팅이 결합안정성에 미치는 영향)

  • Lim, Hyun-Pil;Park, Young-Sun;Vang, Mong-Sook;Yang, Hong-So;Park, Sang-Won;Yoon, Suk-ja
    • Journal of Dental Rehabilitation and Applied Science
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    • v.25 no.2
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    • pp.157-169
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    • 2009
  • The aim of this study was to evaluate effect of implant abutment screw coating treatment on joint stability, investigating mechanical properties of these. For this study used $ExFeel^{(R)}$ external hexed implant system and $15mm{\times}1mm$ discs. Experimental group was $1{\mu}m$ TiN, TiCN, TiC coated abutment screws and discs. To know mechanical property, i evaluated adhesion strength, surface hardness, using disc, corrosion test using screw. The results were as follows : rotation angle of coated screws increased than that of non-coated screw because of lower friction coefficient, especially TiC coated screw group had the largest value, but removal torque decreased in all coated screws (p<0.05). Torque loss before and after fatigue test was the smallest in TiC-coated screws, and the largest in non-coated screws (p<0.05), and there was no statistically significant difference between dry condition and wet condition of screws because of higher surface hardness and lower friction coefficient. From the above results, TiN, TiCN, TiC coating group had high abrasion resistance, especially TiC coated group which had low torque-consuming, high rotation angle as low friction coefficient will be considered to influence on implant abutment screw joint stability positively.