• 제목/요약/키워드: corrosion behaviors

검색결과 274건 처리시간 0.026초

인공해수의 pH에 따른 강 용접부의 응력 부식균열거동에 관한 연구 (A Study on the Stress Corrosion Cracking Behaviors for Weld Joint of Steel with Various pH Values in Synthetic Sea Water)

  • 유효선;나의균;정세희
    • Journal of Welding and Joining
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    • 제13권1호
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    • pp.78-88
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    • 1995
  • This paper was performed to study the utility of the SP(small punch) test and the AE(acoustic emission) test in the evaluation of SCC(stress corrosion cracking) susceptibility for parent metal and bond line of HT80 steel-weld joint by SAW(submerged arc welding) with the various pH values. The loading rate used was 3*10$^{-4}$ mm/min and the corrosive environment used was synthetic sea water during the SP test and the AE test. According to the test results, the SCC susceptibility of the parent metal was increased in the order of pH6.0, pH8.2 and pH10.0. On the other hand, the bond line showed almost the same high SCC susceptibility in all pH concentrations. Synthetically, from the results of the SCC susceptibility, the macro- and micro-SEM observation, the microfracture behaviors by AE test and the relationship between SCC susceptibility and displacement at incipient failure, .delta.$_{i.f-AE}$, it can be concluded that the SP test and the AE test are the good test methods to evaluate the SCC susceptibility for parent metal and bond line of the weld joint with the change of environmental factors.

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A STUDY ON WELDING RESIDUAL STRESS BY NUMERICAL SIMULATION ON FRICTION STIR WELDING

  • Bang, Han-Sur;Kim, Heung-Ju;Go, Min-Seong;Chang, Woong-Seong;Lee, Chang-Woo
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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    • pp.505-510
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    • 2002
  • The Friction Stir Welding (FSW) is a new joining method that was developed at The Welding Institute (TWI) in England in 1991. It applied heating by the rotational friction and material plastic flow. It was developed as a new joining method to solve the problems of epochally in the welding of Al alloys. In the study, 6000series of Alloy composed of AI-Mg-Si, one of the Al alloys that are utilized for shipbuilding and construction, is selected as a specimen and the numerical is executed against the welded zone of FSW. The material used in this study had the unique properties of strength and anti-corrosion, but since the welded joint of this material is easily softened by the welding heat, FSW is executed and the numerical analysis is carried out around the joint. To examine the mechanical behaviors and properties, F.E.M analysis is executed and the developed thermal-elastic-plastic [mite analysis are used.

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단일과대하중하의 부식피로균열진전거동에 관한 연구 (A Study on Corrosion Fatigye Crack Propagation Behaviors due to a Single Overload)

  • 강동명;이하성;우창기
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 1997년도 춘계학술대회 논문집
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    • pp.481-485
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    • 1997
  • 6063-T5 alloys are tested in laboratory air, water and 3% NaCl solution to investigate the effects of corrosive environment on the retardation behavior through single overload fatigue test. Also, the fatigue crack propagation and the crack closure behavior are studied. The results obtained in this experimental study are summarized as follows: 1) Behaviors of fatigue crack growth retardation are observed in water and 3% NaCl solution as they do in air. The number of delay cycles and the size of affected region by single overload decrease greatly in water and 3% NaCl compared with those in air. 2) In fractographic results, the overload marking by single overload appear remarkably in air, but indistinctly in water and 3% NaCl solution. 3) The effect of crack closure on crack propagation is most remarkable in the beginning of crack propagation. With crack propagation, the crack closure level and its effect decrease greatly.

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Ni-Cr-B-Si계 비정질 용사피막의 제조 및 특성 (Fabrication and Characteristics of Thermal Sprayed Ni-Cr-B-Si System Amorphous Coatings)

  • 정하윤;김태형;박경채
    • Journal of Welding and Joining
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    • 제17권4호
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    • pp.53-59
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    • 1999
  • Amorphous alloys have also been called glassy alloys or non-crystalline alloys. They are made by the rapid solidification. The solidification occurs so rapid that the atoms are frozen in their liquid configuration. There are unique magnetic, mechanical, electrical and corrosive behaviors which result form their amorphous structure. In the study. amorphous coatings were manufactured with Ni-Cr-B-Si powders by flame spray. Measurement of hardness, were resistance, corrosion resistance and observation of microstructures and XRD, DSC were performed to investigate characteristics of amorphous coatings. The experimental results obtained as follow: 1) Amorphous powders could not be manufactured with the spraying in the spraying in the liquid nitrogen. But, amorphous coatings could be manufactured with the rotation cooling method by liquid nitrogen. In the fabrication of amorphous coatings, major factor was the rapid cooling by rotation of the substrate. 2) Hardness of coatings was obtained Hv 960 by formation of amorphous phase. But, wear resistance decreased. That was due to porosity in the coatings by the rapid cooling. 3) In the case of corrosion resistance, amorphous coatings were superior to air-cooled coatings. That was due to formation of amorphous phase. 4) After amorphous coatings were heat-treated at 520℃ for 1hr. hardness increased 80% and wear resistance increased 30% comparing with air cooled coatings. These were due to crystallization of amorphous phase and decrease of porosity by heat-treatment.

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SA508 Gr.3 Cl.2 저합금강과 용접부의 290℃ 수화학 환경에서 피로균열거동 분석 (Fatigue crack growth behaviors of SA508 Gr.3 Cl.2 base and weld material in 290℃ water environment)

  • 조평연;김정현;장창희;조현철
    • Corrosion Science and Technology
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    • 제11권4호
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    • pp.120-128
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    • 2012
  • The fatigue crack growth behaviors of SA508 Gr.3 Cl.2 low alloy steel in high temperature water environment were investigated. Overall, weld metal showed similar crack growth rate as that of base metal. At 0.01 Hz, fatigue crack growth rate (FCGR) was higher than that in air while the difference was smaller at 0.1 Hz. Also, FCGR showed ${\Delta}K$ dependency at 0.1 Hz only, indicating that the environmental effect was much greater at slower loading frequency of 0.01 Hz. FCGR of SA508 Gr.3 Cl.2 low alloy steel was compatible to or smaller than the ASME Sec. XI fatigue reference curves in high temperature water environment.

내화물 응용을 위한 산화물 재료들과 탄소와의 고온 반응거동 (High Temperature Reaction Behaviors of Oxide Materials with Carbon for Refractory Application)

  • 최도문;이진석;김남훈;최성철
    • 한국세라믹학회지
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    • 제44권6호
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    • pp.331-337
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    • 2007
  • High temperature reaction behaviors of various oxide materials (such as bauxite, pyrophyllite, mullite and fused silica powders) used in the refractory materials for tap-hole plugging of blast furnace were investigated with varying temperature in the carbon surrounding. Kinetics of carbothermal reduction of $SiO_2$ for forming SiC with high corrosion resistance were strongly dependent on it's crystalline phase. SiC generation yield increased with increasing catalyst amount in oxide regardless of generated SiO gas amount at temperature of $<1500^{\circ}C$. However, in case of fused silica over $1500^{\circ}C$, SiC generation yield was dominantly influenced by SiO amount without catalyst effect. Bauxite showed the most effective carbothermal reduction reaction, since bauxite have a large amount of catalyst and well-dispersed $SiO_2$ phase in oxide matrix.

소성인장변형 몇 아연도금된 Fe-Mn-C계 TWIP 강의 전기화학적 수소투과거동 (Electrochemical Hydrogen Permeation Behaviors of Pre-Strained Fe-Mn-C TWIP Steel With or Without Zn Coating)

  • 김성진
    • Corrosion Science and Technology
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    • 제22권4호
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    • pp.297-303
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    • 2023
  • This study aimed to evaluate hydrogen permeation behaviors of pre-strained twinning-induced plasticity steel with or without Zn coating using electrochemical permeation technique. In contrast to un-strained and 30% strained samples, permeation current density was measured in the 60% strained sample. Tensile pre-straining at 60% involved microstructural modifications, including a high level of dislocation density and stacking fault with a semi-coherent twin boundary, which might provide a high diffusion path for hydrogen atoms. However, reproducibility of measurements of hydrogen permeation current was low due to non-uniform deformation and localized stress concentration. On the other hand, the permeation current was not measured in pre-strained TWIP steel with Zn coating. Instead, numerous blisters with some cracks were observed on the surface of the coating layer. In locally damaged Zn coating under tensile straining, hydrogen atoms could relatively easily permeate through the coating layer. However, they were trapped at the interface between the coating layer and the substrate, which might delay hydrogen penetration into the steel substrate.

감육배관의 파괴거동 평가 (Fracture Behavior Evalustion of Pipes with Local Wall Thinning)

  • 안석환;남기우;김선진;김현수;김진환;도재윤
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 추계학술대회논문집A
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    • pp.61-66
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    • 2001
  • Fracture behaviors of pipes with local wall thinning is very important for the integrity of nuclear power plant. In pipes of energy plants, sometimes, the local wall thinning may result from severe drosion-corrosion damage. However, effect of local wall thinning on strength and fracture behaviors of piping system were not well studied. In this paper, the monotonic bending tests were performed of full-scale carbon steel pipes with local wall thinning. A monotonic bending load was applied to straight pipe specimens by four-point loading at ambient temperature without internal pressure. From the tests, fracture behaviors and fracture strength of locally thinned pipe were manifested systematically. The observed failure modes were divided into four types; ovalization, ovalization+cracking, local buckling and local buckling+cracking. Also, maximum load was successfully evaluated.

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구조용 금속의 초고주기피로 거동에 대한 연구 동향 (Reviews on Very High Cycle Fatigue Behaviors of Structural Metals)

  • 한승욱;박정훈;명노준;최낙삼
    • 한국자동차공학회논문집
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    • 제22권2호
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    • pp.134-140
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    • 2014
  • The paper presents an overview of the present state of study on the fatigue behaviors at very high number of cycles ($N_f$ > $10^7$). A classification of materials with typical S-N curves and influencing factors such as notches, residual stresses, temperatures, corrosion environments and stress ratios are given. The microstructural inhomogeneities of materials and micro-cracks played an important roles in very high cycle fatigue behaviors. The failure mechanisms for the fatigue design of materials and components are mentioned.

MgO/Al2O3가 소결조제로 첨가된 Si3N4 세라믹스의 수열 조건에서의 부식열화 거동 (Corrosive Degradation of MgO/Al2O3-Added Si3N4 Ceramics under a Hydrothermal Condition)

  • 김원주;강석민;박지연
    • 한국재료학회지
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    • 제17권7호
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    • pp.366-370
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    • 2007
  • Silicon nitride ($Si_3N_4$) ceramics have been considered for various components of nuclear power plants such as the mechanical seal of a reactor coolant pump (RCP), the guide roller for a control rod drive mechanism (CRDM), and a seal support, etc. Corrosion behavior of $Si_3N_4$ ceramics in a high-temperature and high-pressure water must be elucidated before they can be considered as components for nuclear power plants. In this study, the corrosion behaviors of $Si_3N_4$ ceramics containing MgO and $Al_2O_3$ as sintering aids were investigated at a hydrothermal condition ($300^{\circ}C$, 9.0 MPa) in pure water and 35 ppm LiOH solution. The corrosion reactions were controlled by a diffusion of the reactive species and/or products through the corroded layer. The grain-boundary phase was preferentially corroded in pure water whereas the $Si_3N_4$ grain seemed to be corroded at a similar rate to the grain-boundary phase in LiOH solution. Flexural strengths of the $Si_3N_4$ ceramics were significantly degraded due to the corrosion reaction. Results of this study imply that a variation of the sintering aids and/or a control (e.g., crystallization) of the grain-boundary phase are necessary to increase the corrosion resistance of $Si_3N_4$ ceramics in a high-temperature water.