• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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• pp.75-80
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• 2001

This paper investigates the flexural behavior of reinforced concrete beams strengthened with externally bonded fiber reinforced plastic (FRP) sheets is investigated in this work. FRP is attractive for strengthening the RC beams due to its good tensile strength, low weight, resistance to corrosion, and easy applicability. A simple and direct analytical procedure for evaluating the ultimate flexural capacity of FRP strengthened reinforced concrete (SRC) beams is presented using the equilibrium equations and compatibility of strains. Upper and lower limits of FRP sheet area to ensure the ductile behavior are established. A parametric study is conducted to investigate the effects of design variables such as sheet area, sheet stiffness and strength, concrete compression strength, and steel reinforcement ratio. The analytical procedure is compared with results of experimental data available in the literature.

• 한국압력기기공학회 논문집
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• 제18권2호
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• pp.61-68
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• 2022

Accurate evaluation of residual stress is important for stress corrosion cracking assessment. In this paper, electron beam welding experiment is simulated via finite element analysis and the sensitivity of the parameters related to the combined heat source model is investigated. Predicted residual stresses arecompared with measured residual stresses. It is found that the welding efficiency affects the size of the tensile residual stress area and the magnitude of maximum longitudinal residual stress. It is also found that the parameter related to the ratio of energy distributed to the two-dimensional heat source has little effect on the size of tthe tensile residual stress area, but affects the size of the longitudinal residual stress in the center of the weld.

• 한국해양공학회:학술대회논문집
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• 한국해양공학회 2004년도 학술대회지
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• pp.242-246
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• 2004

Effects of circumferentially local wall thinning on the fracture behavior of pipes were investigated by monotonic four-point bending. Local wall thinning was machined on the pipes in order to simulate erosion/corrosion metal loss. The configurations of the eroded area included an eroded ratio of d/t= 0.2, 0.5, 0.6, and 0.8, and an eroded length of I = 10 mm, 25 mm, and 120 mm. Fracture type could be classified into ovalization, local buckling, and crack initiation depending on the eroded length and eroded ratio. Three-dimensional elasto-plastic analyses were also carried out using the finite element method, which is able to accurately simulate fracture behaviors excepting failure due to cracking. It was possible to predict the crack initiation point by estimating true fracture ductility under multi-axial stress conditions at the center of the eroded area.

• Corrosion Science and Technology
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• 제17권3호
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• pp.138-145
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• 2018

The aim of this work is the attainment of the $TiO_2-nanotube$ photocatalytic-growth condition using anodization, whereby the $NH_4F-H_2O$ weight ratio is appropriately controlled. We fabricated the $TiO_2$ nanotubes using a two-step anodization (first step is 1 hr; second step is 30 hr) under the ambient pressure and the room temperature at 60 V in ethylene-glycol solutions to investigate the effects of the $NH_4F$(0.1,0.3,0.5wt%) and $H_2O$(1-3wt%) on the $TiO_2-nanotube$ geometry and the photocatalytic efficiency. Further, the decomposition efficiency of the methylene blue on the $TiO_2$ nanotubes by the UN radiation depended on the geometrical change of the nanotube geometry, indicating the proportionality of the decomposition efficiency to the surface area that was affected by the $NH_4F$ and $H_2O$ concentrations. As the $NH_4F$ weight was increased, the surface area initially decreased but slightly increased later, and the length consistently increased. As the $H_2O$ weight was increased, the surface area and length initially increased, but later decreased with the 3 wt% $H_2O$.

• Corrosion Science and Technology
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• 제4권6호
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• pp.236-241
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• 2005

Hydrogen induced cracking (HIC) is one of the hydrogen degradation phenomena of linepipe steels caused by $H_2S$ gas in the crude oil or natural gas. However, NACE TM0284-96 standard HIC test method is hard to satisfy the steel requirements for sour service application since it uses more severe environmental conditions than actual conditions. Therefore, in order to use steels effectively, it is required to evaluate HIC resistance of steels in the practical range of environmental severity. In this study, HIC resistance of two high strength low alloy (HSLA) steels being used as line pipe steels was evaluated in various test solutions with different $H_2S$ pressures and pH values. The results showed that the key parameter affecting crack area ratio (CAR) is $H_2S$ partial pressure of test solution when the pH value of test solution is not over 4. Hydrogen diffusivity was not a constant value, but it was rather affected by the hydrogen ion concentration (pH value) in the solution.

• Journal of Welding and Joining
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• 제27권6호
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• pp.74-79
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• 2009

Titanium and titanium alloy can be reproduced immediately even if oxide films($TiO_2$) break apart in sea water. Therefore, since titanium demonstrates large specific strength and outstanding resistance to stress corrosion cracking, crevice corrosion, pitting and microbiologically influenced corrosion in sea water environment, it has been widely applied to heat exchanger for ships. In particular, with excellent elongation, pure titanium may be deemed as optimal material for production of heat exchanger plate which is used with wrinkles formed for efficient heat exchange. Conventional plate type heat exchanger prevented leakage of liquid through insertion of gasket between plates and mechanical tightening by bolts and nuts, but in high temperature and high pressure environment, gasket deterioration and leakage occur, so heat exchanger for LPG re-liquefaction device etc do not use gasket but weld heat exchanger plate for use. On the other hand, since welded plate cannot be separated, it is important to obtain high quality reliable welds. In addition, for better workability and production performance, lasers that can obtain weldment with large aspect ratio and demonstrate fast welding speed even in atmospheric condition not in vacuum condition are used in producing products. So far, 1st report and 2nd report compared and analyzed embrittlement degrees by bead colors of weldment through quantitative analysis of oxygen and nitrogen and measurement of hardness as fundamental experiment for the evaluation of titanium laser welding, and evaluated the welding performance and mechanical properties of butt welding. This study welded specimens in various conditions by using laser and GTA welding machine to apply edge welding to heat exchanger, and evaluated the mechanical strength through tensile stress test. As a result of tensile test, laser weldment demonstrated tensile strength 4 times higher than GTA welds, and porosity could be controlled by increasing and decreasing slope of laser power at overlap area.

• 한국방재학회 논문집
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• 제2권1호
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• pp.143-152
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• 2002

본 연구는 서울시내 위치한 39개 콘크리트 고가차도의 중성화 깊이, 가용성 염화물량 및 철근의 자연전위 등을 측정하여 열화의 원인을 분석하기 위한 기초자료를 얻고자 하였다. 전체 조사대상 구조물 가운데 철근위치까지 중성화 깊이가 진행된 구조물은 약 25%에 해당되었으며 중성화 속도는 물-시멘트비 60%, R=1의 조건인 kishitani의 제안식 3.727 $\sqrt{t}$ 보다 5%가 빠른 3.92 $\sqrt{t}$로 나타났다. 콘크리트의 염화물량의 조사결과에서는 전체 측정부위의 24%가 임계염화물량을 초과하였으며 철근의 자연전위는 -350mV(vs. CSE)이하로 측정된 것이 약 31%에 해당되는 구조물로서 과다한 염화물량이 철근부식의 주요 원인이 되는 것으로 조사되었다. 자연전위 -350mV 이하인 구조물에 한한 철근부식의 주요요인을 추정한 결과, 약 60%에 해당하는 부위가 치대 허용염화물량을 초과하였기 때문으로 분석된다.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2018년도 춘계학술대회 논문집
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• pp.101-101
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• 2018

Quantitative measurement of chloride ion concentration has an important role in various fields of electrochemistry, medical science, biology, metallurgy, architecture, etc. Among them, its importance of architecture is ever-growing due to unexpected degradations of building structure. These situations are caused by corrosion of reinforced concrete (RC) structure of buildings. And chloride ions are the most powerful factors of RC structure corrosion. Therefore, precise inspection of chloride ion concentration must be required to increase the accuracy of durability monitoring. Multi-walled Carbon nanotubes (MWCNTs) have high chemical resistivity, large surface area and superior electrical property. Thus, it is suitable for the channels of electrical signals made by the sensor. Silver nanoparticles were added to giving the sensing property. CuBTC, one of the metal organic frameworks (MOFs), was employed as a material to improve the sensing property because of its hydrophilicity and high surface area to volume ratio. In this study, sensing element was synthesized by various chemical reaction procedures. At first, MWCNTs were functionalized with a mixture of sulfuric acid and nitric acid because of enhancement of solubility in solution and surface activation. And functionalized MWCNTs, silver nanoparticles, and CuBTC were synthesized on PTFE membrane, one by one. Electroless deposition process was performed to deposit the silver nanoparticles. CuBTC was produced by room temperature synthesis. Surface morphology and composition analysis were characterized by scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS), respectively. X-ray photoelectron spectroscopy (XPS) was also performed to confirm the existence of sensing materials. The electrical properties of sensor were measured by semiconductor analyzer. The chloride ion sensing characteristics were confirmed with the variation of the resistance at 1 V.

• 대한치과보철학회지
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• 제33권3호
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• pp.584-609
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• 1995

The purpose of this study was to evaluate the difference of the galvanic corrosion behaviour of the titanium in contact with gold alloy, silva-palladium alloy, and nickel-chromium alloy using the immersion and electrochemical method. And the effects of galvallit couples between titanium and the dental alloys were assessed for their usefulness as materials for superstructure. The immersion method was performed by measuring the amount of metal elementsreleased by Inductivey coupled plasma emission spectroscopy(ICPES) The specimen of fifteen titanium plates, the five gold alloy, five silver-palladium, five nickel-chromium plates, and twenty acrylic resin plates ware fabricated, and also the specimen of sixty titanium plugs, the thirty gold alloy, thirty silver-palladium, and nickelc-hromium plugs were made. Thereafter, each plug of gold alloy, silver-palladium, and nickel-chromium inserted into the the titanium and acrylic resin plate, and also titanium plug inserted into the acrylic resin plate. The combination specimens uf galvanic couples immersed in 70m1 artificial saliva solution, and also specimens of four type alloy(that is, titanium, gold, silver-palladium and nickel-chromium alloy) plugs were immersed solely in 70m1 artificial sativa solution. The amount of metal elements released was observed during 21 weeks in the interval of each seven week. The electrochemical method was performed using computer-controlled potentiosta(Autostat 251. Sycopel Sicentific Ltd., U.K). The wax patterns(diameter 11.0mm, thickness,in 1.5mm) of four dental casting alloys were casted by centrifugal method and embedded in self-curing acrylic resin to be about $1.0cm^2$ of exposed surface area. Embedded specimens were polished with silicone carbide paper to #2,000, and ultrasonically cleaned. The working electrode is the specimen of four dental casting alloys, the reference electrode is a saturated calmel electrode(SCE) and the ounter electrode is made of platinum plate. In the artificial saliva solution, the potential scanning was carried out starting from-700mV(SCE) TO +1,000mV(SCE) and the scan rate was 75mV/min. Each polarization curve of alloy was recorded automatically on a logrithmic graphic paper by XY recorder. From the polarization curves of each galvanic couple, corrosion potential and corrosion rates, that is, corrosion density were compared and order of corrosion tendency was determined. From the experiments, the following results were obtained : 1. In the case of immersing titanium, gold alloy, silver-palladium alloy, and nickel-chromium alloysolely in the artificial saliva solution(group 1, 2, 3, and 4), the total amount of metal elements released was that group 4 was greater about 2, 3 times than group 3, and about 7.8 times than group 2. In the case of group 1, the amount of titanium released was not found after 8 week(p<0.001). 2. In the case of galvanic couples of titanium in contact with alloy(group 5, 6), the total amount of metal elements released of group 5 and 6 was less than that of group 7, 8, 9, and 10(p<0.05). 3. In the case of galvanic couples of titanium in contact with silver-palladium alloy(group 7, 8), the total amount of metal elements released of group 7 was greater about twice than that of group 5, and that of group 8 was about 14 times than that of group 6(p<0.05). 4. In the case of galvanic couples of titanium in contact with nickel-chromium alloy(group 9, 10), the total amount of metal elements released of group 9 and 10 was greater about 1.8-3.2 times than that of group 7 and 8, and was greater about 4.3~25 times than that of group 5 and 6(p<0.05). 5. In the effect of galvanic corrosion according to the difference of the area ratio of cathode and anode, the total amount of metal elements released was that group 5 was greater about 4 times than group 6, group 8 was greater about twice than group 7, and group 10 was greater about 1.5 times than group 9(p<0.05). 6. In the effect of galvanic corrosion according to the elasped time during 21 week in the interval of each 7 week, the amount of metal elements released was decreased markedly in the case of galvanic couples of the titanium in contact with gold alloy and silver-palladium alloy but the total amount of nickel and beryllium released was not decreased markedly in the case of galvanic couples of the titanium in contact with nickel-chromium alloy(p<0.05). 7. In the case of galvanic couples of titanium in contact with gold alloy, galvanic current was lower than any other galvanic couple. 8. In the case of galvanic couples of titanium in contact with nickel-chromium alloy, galvanic current was highest among other galvanic couples.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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• pp.371-374
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• 2005

In this study, calcium chloride($CaCl_2$), sodium chloride (NaCl), organic acids-containing deicer(NS 40, NS 100), mixed deicier($NaCl\;70\%\;+\;CaCl_{2}\;30\%,\;NS\;40\;70\%\;+\;CaCl_{2}\;30\%,\;NaCl\;70\%\;+\;NS\;40\;30\%,\;NS\;40\;70\%\;+\;NaCl\;30\%$) is investigated based on the laboratory test for deicing performance. Test items for deicing performance were ice melting and ice penetration, freezing point depressions and eutectic points, pH, thermal properties for selected deicing chemicals. As a test results, in case of the use chloride-containing deicier in area that concrete structures has subjected to freez-thaw reaction in winter season, it showed desirable method that use deicing chemicals mixed with optimum ratio rather than use one deicing chemicals when is consider to deicing performance and effects, corrosion of steel materials, freez-thaw resistance of concrete. When use various deicing chemicals mixed, NS40($70\%$)+Calcium chloride($30\%$) showed the best effective method.