• Tribology and Lubricants
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• 제12권2호
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• pp.32-40
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• 1996

The tribological role of copper alloy fine particles in an additive is not well known compared to solid lubricants such as $MoS_{2}$ and PTFE. In this experimental investigation, a series of friction and wear test was undertaken to gain a better understanding of an additive containing copper alloy fine particles and to identify the effectiveness of copper alloy particles in improving tribological performance of the lubricant. Friction and wear of specimens under lubricated contact condition were studied and the worn surfaces were characterized by AES (Auger Electron Spectroscopy), SEM (Scanning Electron Microscopy) and optical microscopy. It was revealed that a copper-contained layer was formed and this layer resulted in considerable reduction in both friction and wear due to its lubricity and anti-wear property. The analysis of worn surface revealed that copper of the fine alloy particles in the additive helps healing the worn surface by plating and filling wear pits.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2016년도 추계학술대회 논문집
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• pp.194.1-194.1
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• 2016

The present study investigated the effect of zincate treatment time on the dissolution behavior and the deposition of copper by immersion process and electroplating process on AZ31 Mg alloy substrate in a copper pyrophosphate bath. Without zincate pretreatment, the AZ31 Mg substrate quickly dissolved in the copper pyrophosphate solution although an external cathodic current was applied. The copper layers deposited on non-zincate treated AZ31 Mg alloy substrate by both immersion and electroplating processes showed very porous structure and very poor adhesion. With increasing zincate treatment time up to 2 min, the dissolution of AZ31 substrate in pyrophosphate solution rapidly decreased and the deposited copper layer was less porous and exhibited stronger adhesion. The immersion of AZ31 Mg sample in zincate solution for 5 min was found as a critical time for producing a non-porous and adherent electrodeposited copper layer on AZ31 Mg alloy. The optimum zincating time can be determined by observing the open circuit potential (OCP) of AZ31 Mg alloy samples in a copper pyrophosphate electroplating bath. The OCP reached a stable value of about -0.10 V (vs. SCE) after 5 min of immersion in the copper pyrophosphate electroplating solution.

• 한국치위생학회지
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• 제10권3호
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• pp.531-540
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• 2010

Objectives : In this study, following the cavity restorations with low copper conventional alloy, high copper admixed one and high copper unicompositional one, which are used the most frequently in a clinical setting at the present, to experiment the time-dependent changes of strength, bubbles were examined. Besides, to examine the detrimental effects of mercury contained in dental amalgam, the amount of mercury release was evaluated. Methods : As dental amalgams which were used herein, [BESTALOY], [Hi-Aristaloy 21] and [Sybraloy] were selected for a low-copper conventional amalgam, a high-copper admixed one and a high-copper unicompositional one in the corresponding order. The formation of bubbles and the weight ratio of mercury release were evaluated using a field emission scanning electron microscope (FE-SEM). Thus, the following results were obtained: Results : 1. The time-dependent amount of mercury release reached a statistical significance in three types of alloys, which was shown in such a descending order as [BESTALOY], [Hi-Aristaloy 21] and [Sybraloy]. 2. A low-copper conventional type, BESTALOY is a cutting type and it was found to have an increased formation of fine bubbles. In the remaining two types, [Hi-Aristaloy 21] (a high-copper admixed alloy) and [Sybraloy] (a high-copper unicompositional alloy), the time-dependent changes in the formation of bubbles was negligible. Conclusions : Accordingly, this type of mercury release from amalgam alloy denotes the difference in the weight ratio of total constituents between after 24 hours and after two weeks. But further studies are warranted to examine the amount of mercury release which is detrimental to human bodies. Besides, a low-copper conventional alloy is a cutting type and it was characterized by the abundant formation of bubbles in a time-dependent manner. This implies that the strength of amalgam is impaired, which should be considered in selecting the appropriate amalgam alloy in a clinical setting.

• 한국표면공학회지
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• 제49권3호
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• pp.238-244
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• 2016

Copper electrodeposition on AZ91 Mg alloy was studied in views of preferential deposition on ${\alpha}$- or ${\beta}$- phases and how to achieve uniform deposition over the entire surface on ${\alpha}$- and ${\beta}$-phases in a cyanide solution. The inhomogeneous microstructure of AZ91 Mg alloy, particularly ${\alpha}$- and ${\beta}$-phases, was found to result in non-uniform deposition of zincate layer, preferential deposition of zincate on ${\beta}$-phases, which leads to non-uniform growth of copper layer during the following electrodeposition process. The preferential depositions of zincate can be attributed to higher cathodic polarizations on the ${\beta}$-phases. Pin-hole defects in the copper electrodeposit were observed at the center of large size ${\beta}$-phase particles which is ascribed to gas bubbles formed at the ${\beta}$-phases. The activation of AZ91 Mg alloy in hydrofluoric acid solution was used to obtain uniform growth of zincate layer on both the ${\alpha}$- and ${\beta}$-phases. By choosing an optimum activation time, a uniform zincate layer was obtained on the AZ91 Mg alloy surface and thereby uniform growth of copper was obtained in a cyanide copper electroplating solution.

• 한국수소및신에너지학회논문집
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• 제3권2호
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• pp.9-15
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• 1992

Electroless copper plating method using an alkaline bath have been employed in copper coating of the (LM)Ni4.5Co0.1MnO.2A10.2 hydrogen storage alloy powders for electrode preparation. The plating were conducted without any pretreatment of alloy powders. For the preparation of the electrodes, about 0.12g of the copper coated alloy powder (copper to alloy ratio 1/3 by weight) was compacted with pressure of 6 tons/cm2 at room temperature. The disk-type compacts had a diameter of 10mm and thickness of about 0.24mm. The electrode characteristics were examined through SEM observations and electrochemical measurements in a half cell. The electrochemical measurement showed that the maximum discharge capacity of the electrodes prepared by using alkaline bath were 245mAh per gram of coated alloy (327mAh per gram of alloy) and appeared a considerable degradation with increasing number of cycles. The decrease of the discharge capacity after 100 cycles was about 30% It can be suggested that, with a slight of improvement, this electroless copper plating method could be applied to the preparation of the rare earth-nickel based alloy electrode.

• 대한치과의사협회지
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• 제14권5호
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• pp.425-427
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• 1976

The author observed the reaction of gingval tissues which were implanted with gold, Bosung alloy and copper, the constituents of gold alloy. Pure gold and bosung alloy strips produced slight inflammation but copper had sovere inflammation. Dense fibrous fascile were formed around the gold and Bosung alloy strips on 7th day. When gold and Bosung alloy strips were implanted, eptithelial memberane were occured on 14th day, but copper strips produced eplthelial memberane on 21th day.

• 디자인학연구
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• 제16권2호
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• pp.291-300
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• 2003

동합금을 이용한 금속공예기법에는 성형기법 세공기법이 있다. 이러한 기법에는 주조기법(Metal casting)과 단금기법이 있는데, 주조기법에는 사형(Sand mould, 토범-중국은 도범, 일본은 물형, 납형), 석형, 안틀 끼우기(입형)와 안틀 깎기(삭중형) 등이 있다. 단금기법에는 단조기법 추기기법, 판금기법 등이 조사되었으며, 세공(장식)기법으로는 조금기법, 선조기법, 점선조기법 등이 조사되었다. 이와 더불어 모조기법, 축조기법, 어자문기법과 세선 세공 및 세입세공을 바탕으로 하는 누금세공기법이 주로 사용 되었음이 밝혀지고 있다. 한국의 전통적인 동합금의 방식에 있어서도 성형기법과 세공기법을 주로 사용하는 특성이 있다. 한국에서는 전통적으로 청동을 사용하여 합금을 시도한 바 있으며, 일본의 경우는 자입착색법을 바탕으로 하는 방식을 주로 하여 제작하며, 중국의 경우는 청동합금기술을 바탕으로 하는 방식을 선호하여 제작하였다. 합금방식에 있어서는 3국 모두 각기 독특한 방식을 사용하고 있으나, 한국의 경우는 청동을 주로 사용하되 현대에 와서는 동합금을 주로 사용하고 일본의 경우는 시부이치와 샤큐도우를 주로 사용하여 착색을 시도하여 그 표현방식이 독특하게 이루어 졌다. 중국의 경우는 동을 사용하되 황동과 백동을 주로 사용하여 특징적인 작품세계를 구축하였다.

• 한국분말재료학회지
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• 제11권5호
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• pp.383-390
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• 2004

In order to investigate behavior of abnormal expansion of the iron-copper compacts, we compared the dilatometric curves of the compacts which mixed the copper powder to the iron powder with those of compacts which mixed the copper powder to the iron-copper alloy powder. The dilatometric curves were obtained below the sintering conditions, which heated up to 115$0^{\circ}C$ by a heating rate of 1$0^{\circ}C$/min, held for 60min at 115$0^{\circ}C$ and cooled down at a rate of 2$0^{\circ}C$/min to room temperature. The dilatometric curves of the compacts showed the different expansion behavior at temperatures above the copper melting point in spite of same chemical composition. All of the compacts of former case showed large expansion, but all of the compacts in latter case showed large contraction. The microstructures of sintered compacts also showed the different progress in alloying of the copper into the iron powder. Namely we could observe the segregation at alloy part of copper into iron powder in case of the sintered compacts, which mixed the copper powder to the iron powder, but could not observe the segregation in compacts which mixed the copper powder to the iron-copper alloy powder. But the penetration of liquid copper into the interstices between solid particles was occurred at both cases. Therefore, the showing of the different dimensional changes in the compacts in spite of same chemical composition is due to more the alloying of copper into iron powder than the penetration of liquid copper into the interstices between solid particles.

• 열처리공학회지
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• 제26권4호
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• pp.173-177
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• 2013

Separation and recovery of valuable metals such as zinc, nickel or tin from copper alloy dross has recently attracted from the viewpoints of environmental protection and resource recycling. In this report, preliminary study on concentration and separation of tin from copper alloy dross using selective dissolution method was performed. The tin in the copper alloy dross did not dissolve in the nitric acid solution which could allow the concentration and separation of the tin from the copper alloy dross. Precipitation of tin as $H_2SnO_3$ (metastannic acid) occurred in the solution and transformed to tin dioxide ($SnO_2$) after drying process. The dried sample was heat-treated at low temperature and its phase characteristics, surface morphology and chemical composition were investigated.

• 한국결정성장학회지
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• 제24권2호
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• pp.84-87
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• 2014

Separation/recovery of valuable metals such as zinc, nickel or tin from copper alloy dross has recently attracted from the viewpoints of environmental protection and resource recycling. In this study, preliminary investigation on separation of tin (Sn) from copper alloy dross using selective dissolution method was performed. The tin in the copper alloy dross did not dissolve in an aqueous nitric acid solution which could allow the concentration/separation of tin from the copper alloy dross. Precipitation of tin as $H_2SnO_3$ (meta stannic acid)occurred in the solution and transformed to tin dioxide ($SnO_2$) after drying process. The dried sample was heat-treated at low temperature and its crystal structure, surface morphology and chemical composition were investigated.