• Title/Summary/Keyword: controlled synthesis

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Synthesis of CNT Arrays with Controlling Morphology for High Spinnablility (방적성 향상을 위한 탄소나노튜브 어레이의 형상제어 및 특성평가)

  • Jeong, Seung Pil;Ryu, Seongwoo;Moon, Sook Young
    • Composites Research
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    • v.32 no.5
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    • pp.265-269
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    • 2019
  • The direct spinning of carbon nanotube (CNT) fibers is a promising method in the high performance composite materials. However, most of the reported CNT arrays do not have spinning properties because of their limited synthesis conditions. In this study, we investigate the properties of spinnable CNT arrays, which is closely related to the morphology of CNT array. The array morphology controlled by controlling the conditions of catalyst, carbon source, etc. By additional carbon source of ethylene and changing the composition of the catalyst, the waviness of the CNT array can be remarkably reduced, which leads to improve of the spinning properties. The synthesized CNT arrays were well aligned along c-axis and the synthesis conditions of the spinning array could be derived.

Effects of Electroacupuncture and Electrical Stimulation on VEGF Expression After Muscle Crush Injury in Rats (전침 자극과 전기 자극의 적용이 근육압좌손상이 유발된 흰쥐의 골격근 내 혈관내피성장인자 발현에 미치는 영향)

  • Kim, Min-Hee;Lee, Hyun-Min;Park, Eun-Se;Nam, Ki-Won;Kim, Jin-Sang
    • Physical Therapy Korea
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    • v.13 no.2
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    • pp.9-15
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    • 2006
  • Skeletal muscle injury occurs frequently in sports medicine and is the most general form of injury followed by physical impact. There are growth factors which conduct proliferation, differentiation, and synthesis of myogenic prodromal cells and regulate vascular generation for the continued survival of myocytes. The purpose of the present study was to confirm the effects of electroacupuncture (EA) and electrical stimulation (ES) on muscle recovery processes according to vascular endothelial growth factor (VEGF) expression. Eighteen Sprague-Dawley rats were separated into 2 experimental groups and a controlled group. All animals had suffered from crush damage in the extensor digitorum longus for 30 seconds and were killed 1, 3, and 7 days after injury. 30 Hz and 1 mA impulsion for 15 minutes was applied to the EA experimental groups Zusanli (ST36) and Taichong (LR3) using electroacupuncture and the same stimulation was applied to the ES group using an electrical node. Hematoxyline-Eosin staining and VEGF immunohistochemistry were used to ascertain the resulting muscle recovery. There were few morphological differences between the EA and ES groups, and both groups were observed to have tendencies to decrease atrophy as time passed. In the controlled group, gradually diminishing atrophy could be observed, but their forms were mostly disheveled. There were few differences in VEGF expression between the EA and ES groups, and tendencies to have an increased quantity of VEGF with the lapse of time were observed in both groups. In the controlled group, a little VEGF expression could be observed merely 7 days after injury. In conclusion, EA and ES contributed to muscle recovery processes and could be used for the treatment of muscle injury.

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Design of the Voltage Controlled Oscillator for Low Voltage (저전압용 전압제어발진기의 설계)

  • Lee, Jong-In;Jung, Dong-Soo;Jung, Hak-Kee;Yoon, Young-Nam;Lee, Sang-Young
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.16 no.11
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    • pp.2480-2486
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    • 2012
  • The design of low voltage LC-VCO(LC Voltage Controlled Oscillator) has been presented to optimize the phase noise and power consumption for the block of frequency synthesis to satisfy WCDMA system specification in this paper. The parameters for minimum phase noise has been obtained in the region of design, using the lines of the tuning range and the excess gain in the plane of the inductance and the transconductance of MOS transistor to compensate the loss of LC-tank. As a result of simulation, the phase noise characteristics is -113dBc/Hz for offset of 1MHz. The optimum designed LC-VCO has been fabricated using the process of 0.25um CMOS. As a result of measurement for fabricated chip, the phase noise characteristics is -116dBc/Hz for offset of 1MHz. The power consumption is 15mW, and Kvco is 370MHz/V.

Applications of Triple Controlled Type DDFS-driven PLL Frequency Synthesizer to Broadband Wireless Systems (3중조절 DDFS 구동 PLL 주파수 합성기의 광대역 무선 통신시스템에 응용)

  • Heung-Gyoon Ryu;Byeong-Rok An
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.13 no.6
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    • pp.546-551
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    • 2002
  • In this paper, a triple controlled type DDFS-driven PLL frequency synthesizer with reduced complexity is used to show its applications for broadband wireless communication systems by frequency synthesis control. Since the proposed DDFS-driven PLL synthesizer is very simplified to use only phase accumulator in DDFS, it improves the switching speed and power consumption than the conventional DDFS-driven PLL frequency synthesizer. It is appropriate for applications with requirements of broadband, low-power consumption and high switching speed, since the proposed synthesizer can cover a wide range of frequency bands by the triple frequency control parameters. Method and results of frequency control parameters assignment are shown for the several frequency bands applications such as GSM, IMT-2000, Bluetooth and PCS system.

Preventive Effects of Fluoride Gel Application on Dental Caries in the Permanent Tooth: A Systematic Review of Randomized Controlled Trials

  • Do, Kyung-Yi;Lee, Eun-Sun
    • Journal of dental hygiene science
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    • v.19 no.1
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    • pp.9-22
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    • 2019
  • Background: The purpose of this systematic review was to investigate the effects of topical fluoride gel application on dental caries prevention in the permanent teeth of children and adolescents. Methods: We searched the EMBASE, PubMed, and Cochrane Library databases for randomized controlled trials (RCTs) assessing the effects of self-applied or professionally applied topical fluoride gels in patients <18 years of age; the search was completed on April 1, 2018. All included trials involved an experimental group (fluoride gel application) and a control group (placebo or no treatment). The outcome measures were the D(M)FS and D(M)FT indices, which were compared between the two groups. Review Manager software was used for quantitative synthesis of the final selected articles, and a forest plot was generated via a meta-analysis conducted using a random effects model. Results: The results showed that the D(M)FS and D(M)FT indices were lower in the fluoride application group than in the control group, thus indicating that fluoride gel application was effective in dental caries prevention. We also performed a subgroup analysis to determine whether the effects of fluoride application differed if patients received oral prophylaxis (self or professional) before fluoride gel application. Therefore, the two groups showed slightly larger differences when studies without oral prophylaxis before fluoride gel application were considered; however, the difference was not statistically significant. Conclusion: These findings should be utilized to raise awareness about the caries-prevention effects of topical fluoride application among patients and guardians. Further RCTs should evaluate the effects of fluoride application with or without preceding oral prophylaxis, and appropriate fluoride application guidelines should be developed to maximize the effects of fluoride application in clinical practice.

pH-Controlled Synthesis of Carbon Xerogels for Coin-Type Organic Supercapacitor Electrodes (pH를 조절하여 제조한 카본제어로젤을 이용한 코인타입 유기계 슈퍼커패시터 전극)

  • Ji Chul Jung;Wonjong Jung
    • Korean Journal of Materials Research
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    • v.33 no.10
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    • pp.430-438
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    • 2023
  • In this study, we synthesized pH-controlled resorcinol-formaldehyde (RF) gels through the polymerization of two starting materials: resorcinol and formaldehyde. The prepared RF gels were dried using an acetone substitution method, and they were subsequently carbonized under nitrogen atmosphere to obtain carbon xerogels (CX_Y) prepared at different pH (Y). The carbon xerogels were utilized as active materials for coin-type organic supercapacitor electrodes to investigate the influence of pH on the electrochemical properties of the carbon xerogels. The carbon xerogels prepared at lower pH (CX_9.5 and CX_10) exhibited sufficient particle growth, with a three-dimensional network of particles during the RF gel formation, resulting in the development of abundant mesopores. Conversely, the carbon xerogels prepared at higher pH (CX_11 and CX_12) retained densely packed structures of small particles, leading to pore collapse and low specific surface areas. Consequently, CX_9.5 and CX_10 showed high specific surface areas, and provided ample adsorption sites for the formation of electric double layers with electrolyte ions. Moreover, the three-dimensional particle network in CX_9.5 and CX_10 significantly enhanced electrical conductivity. The presence of well-developed mesopores in these materials further facilitated the effective transport of electrolyte ions, contributing to their superior performance as organic supercapacitor electrodes. This study confirmed that pH-controlled carbon xerogels are one of the promising active materials for organic supercapacitor electrodes. Furthermore, we concluded that pH during RF gel formation is a crucial factor determining the electrode performance of the carbon xerogels, highlighting the need for precise pH control to obtain high-performance carbon xerogel electrodes.

Reaction Characterization of Y2Ba1CU1O5 Oxides by Solid State Reaction Method and Pyrophoric Synthesis Method (고상반응법과 발화합성법에 의한 Y2Ba1CU1O5 산화물의 반응특성)

  • Park, Jeong-Shik
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.772-777
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    • 1999
  • $Y_2Ba_1Cu_1O_5(Y211)$ powders were prepared by pyrophoric synthesis method and by solid state reaction method using $Y_2O_3(99.9%)$, $BaCO_3(99.9%)$, and CuO(99.9%) powders in both of these processes. The phase formation and reaction kinetics of $Y_2Ba_1Cu_1O_5$ powders have been studied using X-ray diffraction analysis(XRD) of samples at various heat treatment temperatures and reaction time. The reaction characterization suggested that the phase formation rate is mainly controlled by the particle size of Y211 powders. The activation energy(${\Delta}E_a$) of Y211 phase formation in this pyrophoric synthesis method was found to be 136.42 kJ/mol compared with 149.46 kJ/mol for that of solid state reaction method. These results data showed that the pyrophoric synthesis method is kineticaly more efficient than the solid state reaction method in this $Y_2Ba_1Cu_1O_5$ system.

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Effect of SiC Crystal Phase on Growing ZSM-5 on the Surface of SiC (탄화규소 결정상의 종류가 탄화규소 표면에 ZSM-5가 형성되는데 미치는 영향)

  • Jung, Eunjin;Lee, Yoon Joo;Kim, Younghee;Kwon, Woo Teck;Shin, Dong-Geun;Kim, Soo Ryong
    • Korean Chemical Engineering Research
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    • v.53 no.2
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    • pp.247-252
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    • 2015
  • ZSM-5 crystals grew on the surface of ${\alpha}$-SiC and ${\beta}$-SiC particles by hydrothermal synthesis method. SiC particles which were > $50{\mu}m$ of size were used, and oxide layer were developed on the surface of the particles to induce growth of ZSM-5 from the surface. Then, synthesis time and temperature condition were considered growing ZSM-5. In this study, oxide layer was formed on ${\beta}$-SiC at $900^{\circ}C$ in air, and it was controlled to grow ZSM-5 grew from the ${\beta}$-SiC surface with $150^{\circ}C$ synthesis condition. This is due to Si-O-Si or Si-O-Al bond, which is basic framework of ZSM-5 can be easily formed, from the silicon oxide film on the surface of ${\beta}$-SiC. When the synthesis temperature was $200^{\circ}C$, the size of ZSM-5 was increased, and it covered much area of the SiC surface with better crystal shapes with longer synthesis time.

Synthesis and Thermoelectric Properties of Zn4Sb3 by Mechanical Alloying Process (기계적 합금화에 의한 Zn4Sb3 열전소재의 합성 및 열전 특성)

  • Ur Soon-Chul
    • Korean Journal of Materials Research
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    • v.14 no.8
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    • pp.535-541
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    • 2004
  • Thermoelectric $Zn_{4}Sb_3$ alloy powders were synthesized from elemental powders by mechanical alloying process and consolidated by hot pressing under controlled atmosphere. Single phase $Zn_{4}Sb_3$ was not obtained using a nominal stoichiometric composition, but near single phase $Zn_{4}Sb_3$ with remnant elemental Zn having a relatively high density was produced using a nominally 11.7 $at.\%$ Zn rich powders. Phase transformations during mechanical alloying were systematically investigated using XRD and SEM. Thermoelectric and transport properties were evaluated for the hot pressed specimens and compared with results of analogous studies.

Polymeric Nano-materials: Applications & Research Trends (고분자 나노 소재의 응용 및 연구 현황)

  • 박영준
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.28 no.2
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    • pp.55-57
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    • 2002
  • The fabrication, characterization and manipulation of nanosystems brings together physics, chemistry, materials science and biology in an unprecedented way, Phenomena occurring in such systems are fundamental to the workings of electronic devices, but also to living organisms. The ability to fabricate nanostructures is essential in the further development of functional devices that incorporate nanoscale features. Even more essential is the ability to introduce a wide range of chemical and materials flexibility into these structures to build up more complex nanostructures that can ultimately rival biological nanosystems. In this respect, polymers are potentially ideal nanoscale building blocks because of their length scale, well-defined architecture, controlled synthesis, ease of processing and wide range of chemical functionality that can be incorporated. In this presentation, we will look at a number of promising polymer-based nanofabrication strategies that have been developed recently, with an emphasis on those techniques that incorporate nanostructured polymers into devices and that exploit intrinsic polymer properties.