• Title/Summary/Keyword: content analyses

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Isolation and Characterization of a Water-Soluble Polysaccharide from the Mycelia of Solid Cultured Agaricus blazei Murill

  • Chung, Ha-Yull;Cho, Young-Jun;Kim, Tae-Wook
    • Food Science and Biotechnology
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    • v.14 no.2
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    • pp.259-262
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    • 2005
  • A fraction (CMEx-AH-${\beta}$) of water-soluble polysaccharides, showing selective antitumor activities, was isolated from the mycelia of solid cultured Agaricus blazei Murill by hot-water extraction, ethanol precipitation, and series of chromatography. Chemical characteristics of CMEx-AH-${\beta}$, were as follows: carbohydrate content, 48%; monosaccharide composition, Man:Glu:Gal (2:93:5); molecular weight, $2{\times}10^5$; uronic acid content, 6.2%. Fundamental structure of CMEx-AH-${\beta}$, was deduced as ${\beta}-(1\;{\rightarrow}\;6)$-D-glucan with ${\beta}-(1\;{\rightarrow}\;3)$-D-glucosidic side chains based on results of methylation and $^{13}C$ NMR spectroscopic analyses.

Evaluation of White-rot Fungi for Biopulping of Wood

  • Kang, Kyu-Young;Sung, Jung-Suk;Kim, Dae-Young
    • Mycobiology
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    • v.35 no.4
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    • pp.205-209
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    • 2007
  • Ergosterol involves in fungal cell growth as a major component in fungal cell membranes. It can be an indicator that shows the fungal activity, and its content depends on the fungal strains, culture, growth conditions and so on. In this study, fungal activities and growth patterns of three white-rot fungi strains isolated in Korea were evaluated by determination of ergosterol contents during the incubation. Wood decay test and chemical analyses of wood were also performed to verify the relationship between fungal activity and wood degrading capacity of white-rot fungi for 60 days. In the results of experiments, it is considered that the test strains selectively degrade large amount of lignin in wood at the early stage of decay. Especially, Phanerochaete chrysosporium showed the best capability on selective degradation of lignin among the test fungi. It is suggested that the determination of ergosterol content in the fungal culture during the incubation is the simple and effective screening method of white-rot fungi for the application to biopulping of wood.

Deposition Behaviors of Ti-Si-N Thin Films by RF Plasma-Enhanced Chemical Vapor Deposition. (RF-PECVD법에 의한 Ti-Si-N 박막의 증착거동)

  • 이응안;이윤복;김광호
    • Journal of the Korean institute of surface engineering
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    • v.35 no.4
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    • pp.211-217
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    • 2002
  • Ti-Si-N films were deposited onto WC-Co substrate by a RF-PECVD technique. The deposition behaviors of Ti-Si-N films were investigated by varying the deposition temperature, RF power, and reaction gas ratio (Mx). Ti-Si-N films deposited at 500, 180W, and Mx 60% had a maximum hardness value of 38GPa. The microstructure of films with a maximum hardness was revealed to be a nanocomposite of TiN crystallites penetrated by amorphous silicon nitride phase by HRTEM analyses. The microstructure of maximum hardness with Si content (10 at.%) was revealed to be a nanocomposite of TiN crystallites penetrated by amorphous silicon nitride phase, but to have partly aligned structure of TiN and some inhomogeniety in distribution. and At above 10 at.% Si content, TiN crystallite became finer and more isotropic also thickness of amorphous silicon nitride phase increased at microstructure.

Composition Dependence and Optical Properties of Polymethyl Methacrylate/Alumina Nanocomposite in the IR Region Determined by Kramers-Kronig Relation

  • Ghamari, Misagh;Ghasemifard, Mahdi
    • Journal of the Korean Ceramic Society
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    • v.54 no.2
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    • pp.102-107
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    • 2017
  • The dependence of the IR optical properties of PMMA/$Al_2O_3$ nanocomposite on the alumina content was investigated in the wavelength range of $3500-2800cm^{-1}$. The samples were prepared via emulsion polymerization technique using oleic acid as a coupling agent. Grafting density calculations were carried out by means of elemental analysis CHN to yield the best coupling agent content. FTIR analysis confirmed the existence of a chemical bond between aluminum oxide and oleic acid. The outcomes of XRD analyses showed the presence of cubic gamma aluminum oxide in the nanocomposite, in contrast to the amorphous nature of PMMA. TEM images showed the core-shell morphology of the particles other than pristine PMMA. Optical constants of the nanocomposite were calculated based on FTIR spectra and the Kramers-Kronig equations. The presence of nano alumina modified some of the optical indexes in IR region.

The Preparation of Non-aqueous Supercapacitors with Lithium Transition-Metal Oxide/Activated Carbon Composite Positive Electrodes

  • Kim, Kyoung-Ho;Kim, Min-Soo;Yeu, Tae-Whan
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3183-3189
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    • 2010
  • In order to increase the specific capacitance and energy density of supercapacitors, non-aqueous supercapacitors were prepared using lithium transition-metal oxides and activated carbons as active materials. The electrochemical properties were analyzed in terms of the content of lithium transition-metal oxides. The results of cyclic voltammetry and AC-impedance analyses showed that the pseudocapacitance may stem from the synergistic contributions of capacitive and faradic effects; the former is due to the electric double layer which is prepared in the interface of activated carbon and organic electrolyte, and the latter is due to the intercalation of lithium ($Li^+$) ions. The specific capacitance and energy density of a supercapacitor improved as the lithium transition-metal oxides content increased, showing 60% increase compared to those of supercapacitor using a pure activated carbon positive electrode.

Analysis of Trends in Research on Creativity of Preschool Children (유아 창의성에 관한 연구동향 분석)

  • Lee, Chae-Ho;Choe, In-Soo
    • Korean Journal of Child Studies
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    • v.30 no.5
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    • pp.1-8
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    • 2009
  • For the purpose of this analysis of trends in research on creativity of preschool children, 98 volumes with articles on the creativity of preschool children were selected from 6 reliable Korean academic journals. Analysis was for year, content, research methods, research design, and subjects. Results showed that (1) the changes by year were that the number of qualitative researches increased from 4 articles in 1998 to 24 articles in 2006. (2) The greatest amount of research content concerned educational methods for the generation of creativity. (3) Most research methods were empirical studies. (4) The most used measurement scale was the Korean Comprehensive Creativity Test for Young Children (Jeon, 2000). (5) Most data analyses were by t-test.

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Polymerizations of Propylene with Unsymmetrical ($\alpha$-Diimine)nickel(II) Catalysts

  • Jeon Man-Seong;Han Chul-Jong;Kim Sang-Youl
    • Macromolecular Research
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    • v.14 no.3
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    • pp.306-311
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    • 2006
  • New unsymmetrical ($\alpha$-Diimine)nickel(II) catalysts having different pendent groups at the ortho positions on aromatic rings were synthesized and subjected to propylene polymerizations with MAO (methylaluminoxane). Structural analyses of the resulting polypropylenes by $^1H\;and\;^{13}C\;NMR$ showed that the ortho substituents on aromatic rings of ($\alpha$-diimine)nickel(II) catalyst affected significantly the polypropylene microstructure. While $C_s$ symmetric catalyst afforded a syndiotactic polypropylene (rr triad content=66%) due to the syndiospecific chain end control, $C_1$ symmetric catalysts produced much less stereoregular polypropylenes (rr triads content <50%), presumably because of collision of the isospecific site control with the syndiospecific chain end control.

Application of Dielectric Spectroscopy Measurements for Estimating Moisture Content in Power Transformers

  • Ekanayake, Chandima;Gubanski, Stanislaw M.;Fernando, M.A.R.M.
    • KIEE International Transactions on Electrophysics and Applications
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    • v.4C no.3
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    • pp.81-89
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    • 2004
  • Frequency Domain Spectroscopy (FDS) measurements were performed on pressboard samples containing different moisture contents and on insulation system of power transformers. The results were used for evaluating sensitivity of the so-called X - Y model, which is applied for estimating moisture content in transformer insulation using the results of FDS measurements. Based on the observations of this analysis a simplified model, called X model, was introduced in which the presence of spacers in transformer insulation has been neglected. Finally, reliability of the X model was assessed by comparing estimates of moisture contents based on FDS measurements on field installed power transformers with moisture contents obtained from chemical analyses of their oil samples.

A Study on the Development of Web-based Education Service for the Blind (시각장애 사용자를 위한 웹 기반 교육서비스 구현 방안에 관한 연구)

  • Park, Seong-Je;Kang, Young-Moo
    • Journal of Information Technology Services
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    • v.6 no.1
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    • pp.17-30
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    • 2007
  • The rapid development of information and communication technologies has resulted in rapid increase in the qualitative and quantitative information that can be accessed by information technology. Furthermore an enormous amount of information is provided in various formats. However, there are a group of people who are not able to even approach to targeted information due to physical or environmental problems. Visually handicapped users constitute a class of these users. In this paper, a method of developing user interface for web-based education service is described for the visually handicapped users to access information more efficiently. First, this paper analyzed the problems of visually handicapped users to access information targeting representative domestic sites that supply education services. And based on the results of the above analyses, Nest, this paper explains the web-based education service interface implementation method according to types of the content to be delivered. Lastly, the validity of this method is provided by testing a web page based on the implementation method according to the types of content.

Synthesis, Structural and Electrical Characterizations of $Pr_{2-x}Ba_xNiO_{4{\pm}\delta}{^\$}$

  • 장영기;권영구;변송호
    • Bulletin of the Korean Chemical Society
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    • v.16 no.2
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    • pp.120-125
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    • 1995
  • Solid solutions of Pr2-xBaxNiO4±δ with K2NiF4-type structure were prepared in air and characterized by powder X-ray diffraction, Rietveld refinements, iodometry titrations, and conductivity measurements. The range of the solid solution was 0 ≤ x < 0.5. The crystal structure changes from orthorhombic (Fmmm) for x ≤ 0.1 to pseudo-tetragonal (I4/mmm) for x ≥ 0.2. The orthorhombic structure of x=0.1 transforms to tetragonal at low temperature. The bond distances obtained from the Rietvel analyses did not vary significantly with the Ba content except that of Ni-O (parallel to the c-axis) which showed an abrupt increase from x=0.1 to 0.2. The excess oxygen content (δ) decreases from 0.241 to 0.03 with increasing substituted Ba contents within the solution range. The samples are all semiconductors at the temperature range 4 < T < 300 K.