• Title/Summary/Keyword: contact oxidation

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Pile-up of phosphorus emitters using thermal oxidation (열산화법에 의한 phosphorus 에미터 pile-up)

  • Boo, Hyun Pil;Kang, Min Gu;Lee, KyungDong;Lee, Jong-Han;Tark, Sung Ju;Kim, Young Do;Park, Sungeun;Kim, Dongwhan
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.122.1-122.1
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    • 2011
  • Phosphorus is known to pile-up at the silicon surface when it is thermally oxidized. A thin layer, about 40nm thick from the silicon surface, is created containing more phosphorus than the bulk of the emitter. This layer has a gaussian profile with the peak at the surface of the silicon. In this study the pile-up effect was studied if this layer can act as a front surface field for solar cells. The effect was also tested if its high dose of phosphorus at the silicon surface can lower the contact resistance with the front metal contact. P-type wafers were first doped with phosphorus to create an n-type emitter. The doping was done using either a furnace or ion implantation. The wafers were then oxidized using dry thermal oxidation. The effect of the pile-up as a front surface field was checked by measuring the minority carrier lifetime using a QSSPC. The contact resistance of the wafers were also measured to see if the pile-up effect can lower the series resistance.

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The Effect of the Sn Amounts on the Microstructure of Rapidly Solidified Ag-Sn-In Alloys (급속응고한 Ag-Sn-In 미세조직에 미치는 Sn 함량 변화의 영향)

  • Cho, Dae-Hyoung;Kwon, Gi-Bong;Nam, Tae-Woon
    • Journal of Korea Foundry Society
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    • v.26 no.2
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    • pp.92-97
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    • 2006
  • Contact material is widely used as electrical parts. Ag-Cd alloy has a good wear resistance and stable contact resistance. But the disadvantages of Ag-Cd alloy are coarse Cd oxides and harmful metal, Cd. To solve the disadvantages of that, Ag-Sn alloy that has stable and fine Sn oxide at high temperature has been developed. In order to optimize Sn amount that affects the formation of the oxide layer on the surface, we worked for the microstructures and properties of Ag-Sn material fabricated by rapid solidification process. The experimental procedure were melting using high frequency induction, melt spinning, and internal oxidation. We have shown that the optimized Sn amount for high hardness is 7.09 wt%Sn. Surface oxide layer forms when Sn amount is over 9.45 wt%. The size of Sn oxide is 20 nm.

Water Quality Improvement Using a Contact Oxidation Canal with Sedimentation Basin (침전접촉산화수로를 이용한 수질 개선)

  • Kim, Won-Jang;Park, Sang-Hyun;Kim, Hyung-Joong;Kim, Tae-Kyun
    • Korean Journal of Environmental Agriculture
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    • v.20 no.3
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    • pp.143-149
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    • 2001
  • A contact oxidation canal system with sedimentation basin was installed to study the efficiency of water quality purification. The primary sedimentation basin with 60 min of HRT (Hydraulic Retention Time) included in the system was aimed to sediment pollutants in the water and the deposit being released by the drainage culvert located at the bottom of the system. The oxidation canal aerated by nozzle was to contact the pollutants and oxygen in the surface of plastic filter to purify the water. Discharge, HRT, length of the oxidation canal were $200\;m^3/day$, 90 min, 20 m, respectively. The treatment efficiency of total nitrogen was lower compared with other water quality items such as SS, BOD, TP because the anoxic condition for denitrification was not ensured after the oxidation canal. However, $25%{\sim}89.6%$ of SS, $75.0%{\sim}91.5%$ of BOD, $44.3%{\sim}95.3%$ of TP were removed in this system. Overall, the results indicates that this system appears to have a potential capability for water quality improvement of the reservoirs or the canals in the agricultural watershed.

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Process Optimization of Environment-Friendly Ag-SnO2 Electric Contact Materials through a Powder Metallurgy (친환경 Ag-SnO2 전기접점재료의 분말야금 공정 최적화)

  • Kim, Jeong-Gon
    • Journal of Powder Materials
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    • v.14 no.5
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    • pp.327-332
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    • 2007
  • In a view point of environment, the advanced electric contact material without environmental load element such as cadmium has to be developed. Extensive studies have been carried out on $Ag-SnO_2$ electric contact material as a substitute of Ag-CdO contact materials. In the present study, powder metallurgy including compaction and sintering is introduced to solve the incomplete oxidation problems in manufacturing process of $Ag-SnO_2$ electrical contact material. The $Ag-SnO_2$ contact material, fabricated in this study, was actually set in an electric switchgear of which working voltage is 462V and current is between 25 and 40A, for the purpose of testing its performance. As a result, it exceeded the existing Ag-CdO contact materials in terminal-temperature ascent and main contact resistance.

Spherical Particles Formation in Lubricated Sliding Contact -Micro-explosion due to the Thermally-activated Wear Process-

  • Kwon, O.K.
    • Tribology and Lubricants
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    • v.11 no.5
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    • pp.1-9
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    • 1995
  • The mechanism of various spherical particles formation from wide range of tribo-systerns is suggested and deduced by the action of micro-explosion on the basis of the thermally-activated wear theory, in which the flash temperature at contact could be reached clearly upto the material molten temperature due to the secondary activation energy from the exothermic reactions involving lubricant thermo-decomposition, metals oxidation, hydrogen reactions and other possible complex thermo-reactions at the contacts. Various shapes of spherical particles generated from the tribosystem can be explained by the toroidal action of micro-explosion accompanied with the complex thermo-chemical reactions at the contact surfaces or sub-surfaces.

Effects of electrochemical oxidation of carbon fibers on interfacial shear strength using a micro-bond method

  • Kim, Dong-Kyu;An, Kay-Hyeok;Bang, Yun Hyuk;Kwac, Lee-Ku;Oh, Sang-Yub;Kim, Byung-Joo
    • Carbon letters
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    • v.19
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    • pp.32-39
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    • 2016
  • In this work, we studied the effects of electrochemical oxidation treatments of carbon fibers (CFs) on interfacial adhesion between CF and epoxy resin with various current densities. The surface morphologies and properties of the CFs before and after electrochemical-oxidation-treatment were characterized using field emission scanning electron microscopy, atomic force microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and single-fiber contact angle. The mechanical interfacial shear strength of the CFs/epoxy matrix composites was investigated by using a micro-bond method. From the results, electrochemical oxidation treatment introduced oxygen functional groups and increased roughness on the fiber surface. The mechanical interfacial adhesion strength also showed higher values than that of an untreated CF-reinforced composite.

A Study on the Relationship between Oxidation and Sliding Wear Behavior of Ordered Fe-Al Intermetallic Alloys (규칙화된 Fe-Al 계 금속간 화합물의 산화특성과 미끄럼 마모거동과의 관계에 대한 연구)

  • 김용석
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.03b
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    • pp.144-148
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    • 1999
  • The relationship between oxidation and sliding wear behavior of Fe-28 at%. Al alloys with B2 ordered structure has been investigated. Sliding wear tests of the alloys have been carried out under various environmental conditions using a pin-on-disk wear tester. The wear rate of the ordered alloys in an oxygen atmoshpere was found to be much lower than in an oxygen atmosphere showed that Fe2O oxides formed on the wearing surface. The oxide layer prevented direct contact of the two mating materials and therefore improved wear resistance of the Fe-Al intermetallic alloy. It was found that the surface Al2O3 oxide layer which provides good oxidation resistance and improved mechanical properties broke down easily and didnot function properly as an oxidation barrier.

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Synthesis of Oxidation Resistant Core-shell Nanoscale Zero-valent Iron by Controlled Air Contact (공기접촉 제어를 통한 산화방지 Core-Shell 나노영가철의 제조)

  • Ahn, Jun-Young;Kim, Hong-Seok;Hwang, In-Seong
    • Journal of Soil and Groundwater Environment
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    • v.13 no.6
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    • pp.93-102
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    • 2008
  • Experimental studies were conducted to characterize the synthesized nanoscale zero-valent iron (NZVI) which is resistant to oxidation in the atmospheric environment. XRD, XPS, and TEM analyses revealed that the oxidation-resistant NZVI particles formed under various controlled air contact conditions (4, 8 and 12 mL/min) have shells with ${\sim}$5 nm thickness. The shells consist of magnetite (${Fe_3}{O_4}$) and maghemite (${\gamma}-{Fe_2}{O_3}$), predominantly. No substantial differences were found in the shell components and thickness among NZVI particles formed under the various air flow rates. On the other hand, shell was not detected in the TEM image of rapidly oxidized NZVI particles. NZVI particles synthesized under the various air flow rates showed similar TCE degradation performances ($k_{obs}$= 0.111, 0.102, and 0.086 $hr^{-1}$), which are equivalent to approximately 80% of those obtained by the fresh NZVI particles. TCE degradation efficiencies of the NZVI particles(fresh, controlled air contact and rapidly oxidized) were improved after equilibrating with water for one day, indicating that depassivation of the shells occurred. The performances of NZVI particles decreased to 90% and 50% of those of the fresh NZVI particles, when they were equilibrated with the atmosphere for a week and two months, respectively. The NZVI particles synthesized under the controlled air contact would have advantages over traditional NZVI particles in terms of practical application into the site, because of their inertness toward atmospheric oxygen.

Enhancement of light reflectance and thermal stability in Ag-Mg alloy contacts on p-type GaN

  • Song, Yang-Hui;Son, Jun-Ho;Kim, Beom-Jun;Jeong, Gwan-Ho;Lee, Jong-Ram
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.03a
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    • pp.18-20
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    • 2010
  • The mechanism for suppression of Ag agglomeration in Ag-Mg alloy ohmic contact to p-GaN is investigated. The Ag-Mg alloy ohmic contact shows low contact resistivity of $6.3\;{\times}\;10^{-5}\;{\Omega}cm^2$, high reflectance of 85.5% at 460 nm wavelength after annealing at $400^{\circ}C$ and better thermal stability than Ag contact The formation of Ga vacancies increase the net hole concentration, lowering the contact resistivity. Moreover, the oxidation of Mg atoms in Ag film increase the work function of Ag-Mg alloy contact and prevents Ag oxidation. The inhibition of oxygen diffusion by Mg oxide suppresses the Ag agglomeration, leading to enhance light reflectance and thermal stability.

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