• Title/Summary/Keyword: congener

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Distribution Characteristics of Dioxins in Soils under Different Land Use in Busan, Korea

  • Jeong, Tae-Uk;Seo, Dong-Cheol;Jeong, Seung-Ryul;Cho, Jeong-Gu;Yoo, Pyung-Jong;Kim, Gi-Gon;Cho, Ju-Sik;Heo, Jong-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.4
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    • pp.662-666
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    • 2011
  • In this study, distribution characteristics of dioxins in soils in Busan, Korea were investigated regarding different land use types. Soil sampling sites that distributed through the Busan city showed dioxin concentration ranging from 0.489 to $322.736pg-TEQ\;g^{-1}$ dry weight with a mean value of $26.257pg-TEQ\;g^{-1}$ dry weight. The mean dioxin concentrations of investigated soils ranged from 1.554 to $50.357pg-TEQ\;g^{-1}$ dry weight in consideration of each land use type. That in metal refinery sites with $50.357pg-TEQ\;g^{-1}$ dry weight was higher than any other sites, followed by waste incinerator sites with $44.285pg-TEQ\;g^{-1}$ dry weight. The majority of soil samples had the same dioxin congener profiling despite the different range of dioxin concentration. Octa-CDD was the major contributor among seventeen dioxin congeners with the range from 29.5 to 70.1% in real values. In contrast to real values, dioxin congener profiles in TEQ values were dominated by 2,3,4,7,8-PeCDF which contributed about 35.3~43.8% to the total dioxin concentrations. It was judged by these results that penta-CDF was the major contributor of soil samples in Busan city. The mean ratio of PCDFs/PCDDs in real values was about 0.71, but that in TEQ values was, in contrast to it, approximately 3.03.

Analysis of Polycyclic Aromatic Hydrocarbons (PAHs) in Shellfishes from Korean Coastal Area (우리나라 연안해역 생산 패류 중 다환방향족탄화수소 분석)

  • Hong, Do Hee;Kang, Eun Hye;Yoon, Minchul;Jo, Mi Ra;Son, Kwang Tae;Lee, Ka Jeong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.54 no.4
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    • pp.397-403
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    • 2021
  • Polycyclic Aromatic Hydrocarbons (PAHs) were analyzed and safety evaluation was carried out in Korean coastal area. The target congeners were benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, and chrysene. The method of analysis was significant. The highest PAHs 4 congener concentrations (12.2 ㎍/kg) was found in the mussel of Gangwon area. Comparison among the average concentration of PAHs for each congener showed that, benzo[a] anthracene was found in mussel (0.276 ㎍/kg), oyster (0.463 ㎍/kg), ark shell clam (1.92 ㎍/kg), and chrysene was found in mussel (0.848 ㎍/kg), oyster (1.36 ㎍/kg), scallop (0.489 ㎍/kg), sea squirt (3.07 ㎍/kg), and ark shell clam (0.449 ㎍/kg). In addition, benzo[b]fluoranthene was found in mussel (0.253 ㎍/kg), scallop (0.244 ㎍/kg), and sea squirt (1.64 ㎍/kg). The most hazardous benzo[a]pyrene was found in mussel (0.147 ㎍/kg), and scallop (0.244 ㎍/kg), it was not detected in the other shellfishes. However, all the PAHs levels recorded in this study did not exceed international MRLs. There was no significant difference among the PAHs concentration in shellfish based on sampling area or species. Body exposure was calculated based on PAHs concentration and intake rate. The results of this study indicated that PAHs in shellfish were within acceptable safe levels.

Contamination level and congener profiles of PCBs, Co-PCBs and PCDD/DFs in transformer insulation oil samples (변압기 절연유 중 PCBs, Co-PCBs 및 PCDD/PCDFs 오염수준 및 이성체 분포)

  • Kim, Kyoung-Soo;Kim, Jong-Guk;Shin, Sun-Kyoung;Kim, Kyoung-Sim;Song, Byung-Joo
    • Analytical Science and Technology
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    • v.19 no.3
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    • pp.263-271
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    • 2006
  • The levels of total PCBs, Co-PCBs and PCDD/Fs in the transformer insulation oil samples obtained using GC/ECD and HRGC/HRMS were ranged from N.D. to 77.3 ppm, from 0.0863 to 2.49 ppm and from N.D. to 0.00241 ppm, respectively. In terms of WHO-TEQ values, Co-PCBs and PCDD/Fs were ranged from 23.3 to 600 pgTEQ/g and from N.D. to 128 pgTEQ/g, respectively (${\Sigma}Co$-PCBs+PCDD/Fs concentration was calculated 24.4~728 pgTEQ/g). Although, the contribution of PCDD/Fs was below 12% in total TEQ concentration, it is suggested contamination of PCDD/Fs in transformer insulation oils. Among 10 samples, 4 samples showed higher concentration than 2 ppm (specific waste criterion of Korea) and Aroclor 1242, 1248, 1254 and 1260 was detected in samples as a single or mixture of Aroclor. It was shown reliable relationship between concentration of Co-PCBs and those of PCDD/Fs (p<0.003), however, was not shown between production year of transformer and concentration of PCBs. The distribution pattern of Co-PCB congeners showed that the ratios of mono-ortho substituted congeners were higher than non-ortho substituted congeners. Among that, PCB-118 congener was predominant. In addition, the OCDD congener was predominated in PCDD/Fs congeners as above 53%. Moreover, the congener pattern of Co-PCBs was similar to that of Aroclor as well as ambient air, which suggested that PCBs volatilization from transformer insulation oil affected the pattern of Co-PCBs in ambient air.

Pretreatment Method Development of PCDD/Fs in Sediment Using ASE and SPMDs (ASE와 SPMDs를 이용한 퇴적물중 PCDD/Fs의 전처리법 개발)

  • Chun, Man-Young
    • Environmental Analysis Health and Toxicology
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    • v.22 no.1 s.56
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    • pp.49-55
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    • 2007
  • Three kind of ASE (Accelerated Solvent Extraction) and SPMDs (Semi-Permeable Membrane Devices) combined methods (ASE-SPMDs, ASE-accelerated SPMDs and SPMDs without extraction) and general Soxhlet-GPC were compared each other for the analysis of PCDD/FS in sediment. The average recovery rate of three types ASE and SPMDs combined methods (108.1%) were higher than that of the Soxhlet-GPC (79.5%) for three samples in each method using surrogate internal standards. The average coefficient of variation (10%, $2.1{\sim}25.2%$) for each congener of PCDD/Fs shows the reasonable results. Total PCDD/Fs concentrations after SPMDs without extraction were quite low, but those after ASE-SPMDs and ASE-accelerated SPMDs methods were close to the Soxhlet-GPC. Thus, the ASE-SPMDs and ASE-accelerated SPMDs methods are considered as the excellent pre-treatments method because they need less solvent and time without quality degradation.

Three Species of Acrolepiopsis (Lepidoptera, Glyphipterigidae, Acrolepiinae) New to Korea

  • Sohn, Jae-Cheon;Kim, Sung-Soo;Choi, Sei-Woong
    • Animal Systematics, Evolution and Diversity
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    • v.34 no.4
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    • pp.190-193
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    • 2018
  • Three species of Acrolepiopsis: A. issikiella (Moriuti, 1961), A. japonica Gaedike, 1982, and A. postomacula (Matsumura, 1931), are recorded from Korea for the first time. Acrolepiopsis issikiella is characterized by having the white costal strigulae and a large dorsal patch on the forewing. Acrolepidopsis japonica is the smallest congener in Korea. Acrolepiopsis postomacula is the only Korean species of Acrolepiinae associated with Hosta. Distributions and larval biology of the three species are summarized. Two species, A. issikiella and A. japonica, are potential pest species of yam-cultivating farms in Korea. Superficial and genital features of the species, if available, are illustrated.

Polyaromatic Resin HP-20 Induced Accumulation of Intermediate Azaphilones in Monascus purpureus 𝚫mppC and 𝚫mpp7 Strains

  • Lim, Yoon Ji;Lee, Doh Won;Choi, Jeong Ju;Park, Si-Hyung;Kwon, Hyung-Jin
    • Journal of Microbiology and Biotechnology
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    • v.29 no.6
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    • pp.897-904
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    • 2019
  • Monascus purpureus recombinant mppC and mpp7 knockout strains were subjected to extractive fermentation in the context of azaphilone pigment production. Inclusion of Diaion HP-20 resin resulted in the selective production of unreduced azaphilone congeners, in addition to the early intermediate FK17-P2a, from ${\Delta}mppC$ and ${\Delta}mpp7$ strains that would otherwise mainly produce reduced congeners. Structural determination of two novel unreduced azaphilones from the ${\Delta}mpp7$ strain was accomplished. The unreduced azaphilone compound was converted into the cognate reduced congener in recombinant M. purpureus strains, demonstrating its intermediate role in azaphilone biosynthesis. This study demonstrates the possibility that extractive fermentation with Diaion HP-20 resin can be used to obtain cryptic azaphilone metabolites.

Report of the Genus Rhodobates (Lepidoptera, Tineidae) New to Korea

  • Sohn, Jae-Cheon
    • Animal Systematics, Evolution and Diversity
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    • v.38 no.3
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    • pp.140-143
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    • 2022
  • A tineid genus, Rhodobates Ragonot, 1895 in Myrmecozelinae is reported for the first time from Korea, with a congener, R. cupulatus Li and Xiao, 2006. The voucher specimens of the species comprise four males and four females collected from Seoul City, Sejong City, Gangwon-do, Chungcheongbuk-do, and Chungcheongnam-do. Among the previously-known species of Tineidae in Korea, Rhodobates cupulatus is similar to Psychoides gosari Kim and Bae in having the uniform coloration over the body and wings, but differs from the latter in the much larger body size. External appearance and genital features of R. cupulatus are redescribed and illustrated. A COI sequence of R. cupulatus is provided for the first time and compared in the world database of DNA barcodes. The Korean records of the species represent the first evidence of its occurrence out of the type locality. Circumstances of its collecting in Korea suggest that it is possibly feeding on dead woods in damp environments.

A report of three newly recorded benthic foraminiferal species from Korea

  • Somin Lee;Fabrizio Frontalini;Wonchoel Lee
    • Journal of Species Research
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    • v.12 no.1
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    • pp.48-54
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    • 2023
  • Foraminifera are unicellular eukaryotes widely distributed in marine and transitional marine environments. They play important roles in marine food webs and geochemical cycles and have physiological properties like the formation of calcareous tests and nitrogen respiration. Research on species diversity, distribution and endemism are essential in biogeography and biodiversity conservation. Here, we report three unrecorded species of foraminifera (Hemirotalia foraminulosa, Planispirillina denticulogranulata and Oolina brevisolenia) collected from Jeju Island and the South Sea (Korea). Planispirillina denticulogranulata is the second Planispirillina species recorded in Korea, which can be distinguished from congeners by its tubercles on the ventral side and grooves on the spiral suture. Hemirotalia foraminulosa is differentiated from the only congener H. calvifacta by multiple-scattered pits on the umbilicus, and it is the first report of Hemirotalia from Korean water. Oolina brevisolenia has specific bifurcating costae that characterize it from other congeners. This study contributes to documentation of the foraminiferal biodiversity in Korea, moreover, provides an essential basis for the expanded studies on modern foraminifera.

The complete chloroplast genome of Polygonatum falcatum (Asparagaceae)

  • CHOI, Tae-Young;YUN, Se-Hyun;LEE, Soo-Rang
    • Korean Journal of Plant Taxonomy
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    • v.52 no.1
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    • pp.80-83
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    • 2022
  • Polygonatum falcatum is a perennial herb distributed in East Asia. We determined the characteristics of the complete chloroplast genome in P. falcatum for the first time, with a de novo assembly strategy. The chloroplast genome was 154,579bp in length harboring 87 protein coding genes, 38 tRNA genes and eight rRNA genes. It exhibits typical quadripartite structure comprising a large single-copy (LSC) (83,528bp), a small single-copy (SSC) (18,457bp) and a pair of inverted repeats (IRs) (26,297bp). Phylogenetic analysis of 16 chloroplast genomes from Asparagaceae reveals that the genus Polygonatum is a monophyletic group and that P. falcatum is clustered together with the congener, P. odoratum.

Dietary Risk Assessment for Polycyclic Aromatic Hydrocarbons in Foods (식품중 Polycyclic Aromatic Hydrocarbons의 위해성평가)

  • 이효민;윤은경;박경아;김윤희;정소영;권기성;김명철;송인상;이철호
    • Journal of Food Hygiene and Safety
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    • v.19 no.1
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    • pp.1-8
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    • 2004
  • This study was executed to determine the cumulative dietary risk of PAHs exposed by food ingestion. Food samples including barbecued beef, barbecued pork, grilled chicken, ham, bacon and vegetable oil which were collected from food markets. These samples were saponified, extracted and cleaned up to purify PAHs, and then the purified sample solutions were analyzed by HPLC-FL. Generally, the levels of total PAHs in barbecued beef (0.2 ppb), bacon (0.3 ppb), barbecued pork (0.7 ppb), ham (0.8 ppb), and vegetable oil (1.2 ppb) were low, whereas the level of total PAHs in grilled chicken (9.3 ppb) was significantly high. For the exposure assessment of PAHs due to food ingestion, PAHs levels converted into TEQ$_{BaP}$, the average body weight for 20-73 age group and consumed levels of food proposed from report on the National Health and Nutrition Survey were used. The estimated lifetime average daily intake of dietary PAHs was 4.32${\times}$10$^{-4}$ $\mu\textrm{g}$-TEQ$_{BaP}$kg/day as the mean value. The dietary risk adjusted to cancer potency of benzo(a)pyrene as 7.3 (mg/kg/day)$^{-1}$ was 3.44${\times}$10$^{-6}$ based on current data.ata.