• Title/Summary/Keyword: cone-calorimeter

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Preparation & Properties of the Flame Retarded NBR Foams with Phosphorus/Nitrogen-Containing Flame Retardants (인/질소계 난연제를 포함한 난연 NBR 발포체의 제조 및 특성)

  • Jo, Byung-Wook;Moon, Sung-Chul;Choi, Jae-Kon
    • Elastomers and Composites
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    • v.39 no.2
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    • pp.105-120
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    • 2004
  • The flame retarded NBR foams were prepared with metal hydroxides and various phosphorus/nitrogen-contain ing flame retardants. The dependency of the phosphorus content on thermal properties, flame retardancy, smoke density, and foaming properties were investigated in the foams. Foaming properties and morphology of the flame retarded NBR foams with P/N flame retardants( ${\le}10 phr$) were similar to those of the foams without P/N ones but containing metal hydroxides The flame retardancy of the foams was improved with increasing the phosphorus content and char formation under combustion atmosphere. The cone-calorimeter test and LOI index were also coincided with the TGA analysis quite well. The heat release rate (HRR), total heat release (THR), and effective heat of combustion (EHC) were decreased, whereas the carbon monoxide yield was increased with increase of the phosphorus content of P/N flame retardant. The smoke density values were closely related with CO yield values obtained by the cone-calorimeter test due to the high and hard char formation.

Analysis of Heat Release Rate with Various Diameter of Heptane Pool Fire Using Large Scale Cone Calorimeter (헵탄의 화원 직경 변화를 고려한 대형콘칼로리미터의 발열량 측정 결과 분석)

  • You, Woo Jun;Nam, Dong-Gun;Youm, Moon Cheon;Kim, Sung-Chan;Ryou, Hong-Sun
    • Fire Science and Engineering
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    • v.28 no.5
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    • pp.1-7
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    • 2014
  • The present study has been conducted to analyse the effects of various pool diameters on the measurement of heat release rate (HRR) of heptane fire using large scale cone calorimeter (LSC). The burning rate which is the major parameter for HRR compared with the previous model suggested by A. Hamins. The combustion efficiency for heptane by oxygen consumption method is about 91%, which is almost same with the previous results of 92% suggested by J. Gore. The convective HRR by enthalpy consumption method was 54% lower than HRR by oxygen consumption method. This results are practical use for establishing the reliability of heat release rate for fire experiment.

Combustion Characteristics and Thermal Properties for Wood Flour-High Density Polyethylene Composites (목분-고밀도폴리에틸렌 복합체의 연소성 및 열적특성)

  • Shin, Baeg-Woo;Chung, Kook-Sam
    • Fire Science and Engineering
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    • v.26 no.1
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    • pp.89-95
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    • 2012
  • In this study, we were manufactured wood flour-HDPE composites by modular co-rotating twin screw extruder with L/D ratio of 42. We was measured cone calorimeter test and thermogravimetric analysis (TGA) to find the combustion characteristics and thermal properties for wood flour-HDPE composites. We then evaluated the effect of three additive-type flame retardants on fire resistance performance. The cone calorimeter test showed that the heat release rate (HRR) of untreated composites was the highest Peak HRR ($446.6kW/m^2$) as well as Mean HRR ($185.5kW/m^2$). From the TGA, it was shown that composites added flame retardants began early thermal decomposition and improved thermal stability.

A Study on Combustion Characteristics of Wood-Plastic Composites (합성목재의 연소특성에 관한 연구)

  • Shin, Baeg-Woo;Song, Young-Ho;Rie, Dong-Ho;Chung, Kook-Sam
    • Fire Science and Engineering
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    • v.24 no.6
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    • pp.120-125
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    • 2010
  • Wood-Plastic Composites (WPCs) are one of spotlighting materials for the residential construction and the industry for furniture. At this study, the limiting oxygen index (LOI) was measured by ASTM D 2863 and the cone calorimeter test was done by ISO 5660-1 to find the combustion characteristics of WPCs. In addition, the identical test was implemented to compare the combustion characteristics between the red pine and the antiseptic wood. The result of LOI measurement showed that the LOI of WPCs was lower than that of red pine or antiseptic wood. The cone calorimeter test showed that the heat release rate (HRR) of WPCs was the highest and the Peak HRR as well as the average HRR and total heat release of WPCs was higher than those of red pine or antiseptized wood

A Study on the Analysis of Smoke Density Characteristics for Wood-Plastic Composites (합성목재의 연기밀도특성 분석에 관한 연구)

  • Shin, Baeg-Woo;Song, Young-Ho;Rie, Dong-Ho;Chung, Kook-Sam
    • Fire Science and Engineering
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    • v.25 no.3
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    • pp.119-124
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    • 2011
  • In this study, we measured the smoke density characteristics to find the fire risk of Wood-Plastic composites (WPCs) which are one of spotlighting materials for landscape architecture and residential construction material with the cone calorimeter tester (by ISO 5660-2) and the smoke density tester (by ASTM E 662). In addition, the identical test was implemented to compare the smoke density characteristics between the red pine and the antiseptic wood. The result of cone calorimeter test showed that emissions of carbon monoxide, carbon dioxide and total smoke production rate of WPCs were higher than those of red pine and antiseptic wood. And the result of smoke density test showed that maximum specific optical smoke density(Dm) of WPCs was higher than that of red pine and antiseptic wood as well.

Study on the Application of Cone Calorimeter for Building of Data-Bases for Fire Safety (화재안전 데이터베이스 구축을 위한 콘칼로리미터의 활용성 연구)

  • Hong, Hwa-Young;Lee, Jong-Sung;Park, Su-Jin;Kwon, In-Kyu
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2011.04a
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    • pp.325-329
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    • 2011
  • Fire has developed from the inter-action of heat at the early state and it is very difficult to estimate the magnitude of the fire. Cone Calorimeter can obtain the important material properties from the exposed part of it. It can be contained that ignition, loss of mass, heat release rate, smoke generation, and gas analysis. The purpose of this study is emphasize on the properties of structural steels in terms of physical, mechanical and that will be important way to build the databases of fire safety.

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Ignition and Heat Release Rate of Wood-based Materials in Cone Calorimeter Tests

  • Park, Joo-Saeng;Lee, Jun-Jae
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.2
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    • pp.1-8
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    • 2008
  • This study was performed to evaluate the burning characteristics of wood-based materials and the effect of surface treatment of fire retardant using cone calorimeter. Four types of wood-based materials, such as Plywood, Oriented Strand Board (OSB), Particle Board (PB) and Medium Density Fiberboard (MDF), were tested at a constant heat flux of $50kW/m^2$ to investigate the time to ignition, mass loss rate, heat release rate, effective heat of combustion, etc. In addition, each type of wood-based material was tested at the same heat flux after fire retardant treatment on the surface to evaluate the effect of this treatment on the burning characteristics. The surface treatment of fire retardant, by the amount of $110g/m^2$, delayed the time to ignition almost twice. However, it was indicated that heat release rate, mass loss rate, and effective heat of combustion were not significantly affected by fire retardants treatment for all types of wood-based materials.

A STUDY ON THE FLAMMABILITY OF NON-FLAME-RETARDANT AND FLAME-RETARDANT MATERIALS BY USING CONE CALORIMETER

  • Yanai, Eiji;Suzuki, Takeshi;Yamada, Tokiyoshi
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.85-92
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    • 1997
  • Flammability of non-flame-retardant and flame-retardant materials was studied by using cone calorimeter Also, relations between the results obtained by using cone calorimeter and those obtained by the flammability test of japanese fire Service Law were examined. The results are as follows: 1) The ignition time of the molten specimens is relatively long, whereas the ignition time of the non-molten specimens is short. None of remarkable difference of the ignition time has been found between non-flame-retardant and flame-retardant materials specimens. 2) The peak heat release rates of flame-retardant materials are smaller than those of non-flame- retardant materials. 3) The carbon monoxide and smoke evolved from flame-retardant materials generate much more than those evolved from non-flame-retardant materials. 4) Even if flame-retardant materials are passed by the flammability test of Japanese Fire Service Law, they burn easily under external radiative heating condition.

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Flame Retardant Properties of Polyurethane by the Addition of Phosphorus Compounds (인계 화합물의 첨가에 의한 폴리우레탄의 난연성)

  • Chung, Yeong-Jin
    • Fire Science and Engineering
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    • v.20 no.4 s.64
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    • pp.110-115
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    • 2006
  • Polyurethane(PU) was mixtured by the treatment with flame retardants such as Tri(chloroisopropyl) phosphate(TCPP), Triethyl phosphate(TEP) and Trimethyl phosphate(TMP) at about $90^{\circ}C$. Rigid polyurethane foam was produced using the mixured products as flame retardants. The mechanical property and flammability of rigid polyurethane was investigated. The mixtured polyurethane shows reduced flammability over virgin polyurethane. Mechanical strength of mixtured polyurethane also shows as high as that of virgin polyurethane. In order to evaluate flame retardant properties of the mixtured polyurethane foams, heat release rate(HRR) of the foam was measured by cone calorimeter. Scanning electron micrograph of mixtured PU shows uniform cell morphology as virgin PU.

Combustion Characteristics of Fiber Reinforced Plastic by Cone Calorimeter (콘칼로리미터를 이용한 섬유강화플라스틱(FRP)의 연소특성)

  • 이근원;김관응;이두형
    • Fire Science and Engineering
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    • v.18 no.2
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    • pp.67-72
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    • 2004
  • This study describes to assess combustion characteristics of fiber reinforced plastic (FRP) that is used an elements of building or structure in workplace. The combustion characteristics of the fiber reinforced plastic were carried out using by a Cone Calorimeter according to ISO 5660 standard. As the results of this study, the time to ignition and heat release rate of the fiber reinforced plastic was differ with heat flux of irradiance and content of flame retardant agent. The heat release rate of the fiber reinforced plastic was increased with increasing heat flux of irradiance. The flashover propensity of the fiber reinforced plastic using time to ignition and peak heat release rate was examined according to classification method by R.V. Petrella.