• Journal of the Korean Society of Industry Convergence
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• v.7 no.3
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• pp.299-303
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• 2004

A systematic investigation for the reactivity and solvent effect was studied on the reaction of optical resolving agents with the optically active assistant compounds. The reaction rate constants of the nucleophillic substitution reactions were determined by means of conductometric method The linear solvent energy relationship based on the solvent parameters and the thermodynamic parameters was discussed on the reactions of various physiological active compounds and optical resolving agents The reaction mechanism was discussed from the kinetic results compared with the optical purity.

• Applied Biological Chemistry
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• v.28 no.2
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• pp.56-61
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• 1985

The mass balances of calcium salts during the manufacturing processes of Tofu were established by conductometric method and chemical analysis method. During the manufacturing processes of soy milk and Tofu, 66% of solid and 63% of calcium was transfered from soy-bean to the soy milk, and 47.8% of total solid from soybean was transfered to the Tofu, respectively. When the $CaCl_2$ was used as coagulant, calcium contents in Tofu $(Y_{Tofu},\;mg{\cdot}Ca/g{\cdot}Tofu,\;wet\;basis)$ and drained solution $(Y_{drained\;soln},\;mg{\cdot}Ca/ml{\cdot}drained\;soln.)$ were linearly increased with the amounts of $CaCl_2(C,g{\cdot}CaCl_2/ml{\cdot}soy\;milk)$ added in soy milk, and correlative equations between them were obtained as $Y_{Tofu}=0.3369\;C+1.2689$ for Tofu$(moisture\;content:\;81.5{\pm}0.5%)$ with r=0.9898, and $Y_{drained\;soln}= 0.2899C+0.0399$ for drained solution with r= 0.9991. It was proved that conductometric method was reasonably applicable to the measurement of calcium contents of the products from every processes of Tofu manufacture except soy-bean. However the conductometric method was not recomendable in the case of $CaSO_4$ as coagulant due to its low solubility ana uneven distribution in soy milk and Tofu tissue.

• Journal of the Korean Chemical Society
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• v.35 no.3
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• pp.196-203
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• 1991

The $pK_a$ values of benzoic acid and meta, para-halogen substituted benzoic acids in MeOH-$H_2O$ mixtures (0∼80% of MeOH) have been determined at 25$^{\circ}$C using a conductometric method on the basis of the Fuoss-Kraus equation, and further verified using modified conductometric method of Gelb. The dependence of $pK_a$ on halogen substituents has been discussed in terms of substituent-constant (${\sigma}$), which is devided into electron-withdrawing inductive contribution (${\sigma}_1$) and electron-donating ${\pi}$-resonance one (${\sigma}_R$). The linear-dependence of ${\sigma}_1$'s on $D^{-1}$ with positive slope and that of ${\sigma}_R$'s on $D^{-1}$ with negative slope have been interpreted on the basis of field effect and through-space interaction of ${\pi}$-lone pair of halogen substituent and ionization center via ${\pi}$-system of benzene ring.

• Analytical Science and Technology
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• v.5 no.3
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• pp.269-276
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• 1992

An ion-exchange/conductometric method is applied for the determination of total acidity in simulated atmospheric samples. Non-$H^+$ cations and strong acid anions are enriched by the preconcentrator columns in series and eluted through the corresponding parallel suppressor units. The conductivities from each channel correspond to the concentrations of the resulting ionized species in equivalents per unit volume. The difference is the measure of acidity due to strong acids. With 5-min sampling at a flow rate of 0.3 mL/min, the detection limits for ${NH_4}^+$ and ${SO_4}^{2-}$ are 0.3 and $0.1{\mu}equiv/L$, respectively. The acidity for samples composed of various ions can be determined without significant error, usually less than 5%. The proposed method discriminates against the artifact from the $CO_2$ dissolution. Principles of acidity measurements are also presented.

• Journal of Sensor Science and Technology
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• v.18 no.6
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• pp.417-422
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• 2009

The problems associated with the synthesis, characterization and application of $SnO_2$-Au nanocomposites for the optimization of conductometric gas sensors have been discussed in this report. Nanocomposites have been synthesized on the surface of $SnO_2$ films using successive ionic layer deposition(SILD) method. It has been shown that the proposed approach to surface modification of metal oxide films is an excellent method for the optimization of the operating characteristics of $SnO_2$-based gas sensors, being developed for the detection of reducing gases as well as ozone.

• Journal of the Korean Chemical Society
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• v.35 no.2
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• pp.105-110
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• 1991

The dissociation constants of valine and norvaline in aqueous solution were measured by conductometric method in various temperatures and pressures. The properties of the dissociation reaction were discussed in term of the thermodynamic properties of reaction. These substituted effects on the dissociation reaction were discussed on the points of Hammett relation and net charge of the O and N-atom calculated from CNDO/2 method respectively.

• Journal of the Korean Chemical Society
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• v.35 no.5
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• pp.443-451
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• 1991

The solvation numbers of some ions in water and of KCl in mixed solvent systems were measured using the conductometric method. Stoke's radii of ions in solution were calibrated by the Nightingale method and the solvation numbers of ions in mixed solvents were deduced by simple assumptions. The deduced solvation numbers of each solvent reasonably go with its selective properties of solvation. From the isosolvation point of ions, the selective properties of ionic solvation were discussed.

• Journal of the Korean Chemical Society
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• v.25 no.2
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• pp.67-74
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• 1981

The dissociation constants of benzoic acid, p-methoxybenzoic acid and p-nitrobenzoic acid have been determined at $25^{\circ}C$ in ethanol-water mixtures containing 0, 10, 20, 30, 40, 50, 65 and 80 weight % ethanol by the direct conductance measurements and the method involving titration of the acid sample with perchloric acid reagent. The results by the two methods have been discussed and compared with those by other methods.

• Safety and Health at Work
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• v.12 no.2
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• pp.209-216
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• 2021

Background: The article presents the results of studies performed in order to develop a new method of airborne potassium bromate(V) determination at workplaces. Methods: The method is based on a collection of the inhalable fraction of potassium bromate(V) using the IOM Sampler, then extraction of bromates with deionized water and chromatographic analysis of the obtained solution. The analysis was performed using ion chromatography with conductometric detection. The tests were performed on a Dionex IonPac®AS22 analytic column (250 × 4 mm, 6 ㎛) with AG22 precolumn (50 × 4 mm 11 ㎛). Results: The method provides for potassium bromate(V) determination within the concentration range of 0.043 ÷ 0.88 mg/m³ for an air sample of 0.72 m³ in volume, i.e., 0.1-2 times the exposure limit value as proposed in Poland. The method was validated in accordance with PN-EN 482. The obtained validation data are as follows: measuring range: 3.1-63.4 ㎍/mL, limit of detection (LOD) = 0.018 ㎍/mL and limit of quantification (LOQ) = 0.053 ㎍/mL. The developed method has been tested in the work environment, on laboratory employees having contact with potassium bromate(V). Conclusion: The analytical method allowed the determination of the inhalable fraction of airborne potassium bromate(V) at workplaces and can be used to assess occupational exposure.

• Journal of the Korean Chemical Society
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• v.41 no.9
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• pp.443-448
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• 1997

Kinetics for the solvolyses of acyl chlorides and alkyl chlorides in hydroxylic solvent mixtures have been measured by conductometric method at various temperatures and pressures. The activation parameters (${\Delta}V^{\neq},\; {\Delta}H^{\neq},\; {\Delta}S^{\neq}$) were estimated from the rate constants. The reactivities of these reactions were also estimated from the correlation of the activation volumes with the activation entropies.