• Title/Summary/Keyword: conducting property

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Relations Between Dispersion of CNTs and Electrical Conductivity in the Hydrophobic CNT/PVDF Composite Film (소수성 CNT/PVDF 복합막에서 CNT의 분산과 전도성의 관계)

  • Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.7
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    • pp.462-466
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    • 2015
  • In this paper, we investigated the relations between dispersion of CNTs (carbon nanotubes) and electrical conductivity in the CNT/PVDF (polyvinylidene fluoride) composite film. By adding hydrophobic CNTs as filler into the PVDF matrix, we fabricated hydrophobic and electrically conducting polymer coating film. Dispersion of CNTs in the CNT/PVDF composite film plays a significant role in terms of electrical conductivity and wetting property. Spray coating method was used to form the CNT/PVDF composite films by injecting the dispersed CNTs in the PVDF solution with different weight ratios from 0.7 wt% to 7 wt%. We investigated the electrical properties and contact angles of the CNT/PVDF composite films with the CNT concentration. Finally we discussed the conducting mechanism and feasibility of the CNT/PVDF composite film for the conducting polymer films.

A Study on Physical Properties of $PAN-CuSO_4$ Electroconductive Fiber and Wool Blended Fabrics (아크릴-황산동 복합체로 제조한 도전성 섬유 및 혼방한 모직물의 물성에 관한 연구)

  • 정영진;이명환;최해욱;이기환
    • Textile Coloration and Finishing
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    • v.11 no.4
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    • pp.8-15
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    • 1999
  • Electroconductive fiber was obtained by acryl fiber treated with $CuSO_4$. The Properties and structure of fiber and fabric such as mechanical property, electrical conductivity, fine structure, electrification were investigated. The experimental results are as follows 1) The electrical conductivity of the conducting fiber was greatly increased but fine structure and physical properties were similar to acryl fiber 2) Fabric made by mix spinning with conducting fiber was shown great electrification effect. 3) In the mix spinning with conducting fiber, it was necessary to use different. finishing such as milled finish because stiffness of fabric made by mix spinning with conducting fiber was increased and elastic recovery was decreased. 4) The antimicrobial activity of electroconductive fiber blended wool was effective by Cu component for shake flask test.

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Synthesis of Mesostructured Conducting Polymer-Carbon Nanocomposites and Their Electrochemical Performance

  • Choi, Moon-Jung;Lim, Byung-Kwon;Jang, Jyong-Sik
    • Macromolecular Research
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    • v.16 no.3
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    • pp.200-203
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    • 2008
  • A conducting polymer layer was introduced into the pore surface of mesoporous carbon via vapor infiltration of a monomer and subsequent chemical oxidative polymerization. The polypyrrole, conducting polymer has attracted considerable attention due to the high electrical conductivity and stability under ambient conditions. The mesoporous carbon-polypyrrole nanocomposite exhibited the retained porous structure, such as mesoporous carbon with a three-dimensionally connected pore system after intercalation of the polypyrrole layer. In addition, the controllable addition of pyrrole monomer can provide the mesoporous carbon-polypyrrole nanocomposites with a tunable amount of polypyrrole and texture property. The polypyrrole layer improved the electrode performance in the electrochemical double layer capacitor. This improved electrochemical performance was attributed to the high surface area, open pore system with three-dimensionally interconnected mesopores, and reversible redox behavior of the conducting polypyrrole. Furthermore, the correlation between the amount of polypyrrole and capacitance was investigated to check the effect of the polypyrrole layer on the electrochemical performance.

Studies on the Sensing Mechanism of Conducting Polymer for Volatile Organic Compound Sensing (휘발성 유기화합물 측정을 위한 전도성고분자 센서의 감응기구에 관한 연구)

  • Hwang, Ha-Ryong;Baek, Ji-Heum;Heo, Jeung-Su;Lee, Deok-Dong;Im, Jeong-Ok;Lee, Jun-Yeong
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.599-602
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    • 2001
  • In this study, we fabricated chemically polymerized PPy and PANi films with different selectivity by controlling dedoping time. And the sensing properties and mechanism of VOCs adsorption to conducting polymers were investigated. Thin sensor had higher sensitivity compared to thick one, and dedoped sensor for 1-minute highest sensitivity. Upon gas absorption, polypyrrole exhibited positive sensitivity while polyaniline had negative sensitivity. PPy film show hydrophilic property and PANi film show hydrophobic property. After the gas absorption, the sensitivity increased as a function of polarity of absorbed molecules. These behaviors are due to the polar molecules absorbed with the movable polaron or free carrier, and then it interrupt or generate the movement of polaron and carrier, and then it changes the conductivity of polymer. We found that conducting polymer sensors are very sensitive to the difference in polarity of gas molecules.

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The Conductivity Percolation of Conducting Plastic Materials (도전성 플라스틱의 전도 퍼콜레이션)

  • Kim, In Chan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.6
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    • pp.713-721
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    • 1999
  • A composite plastic, where long metallic fibers are used as filling materials, is transformed from nonconducting to conducting medium as the volume fraction of filling metallic fibers is increased from zero : such drastic change in property is called the percolation. It is desired both for practical and theoretical purposes to understand the physics underlying the percolation and to estimate the percolation threshold that is defined by the minimum volume fraction of the metallic fibers for which the percolation occurs. In this study, percolation thresholds are calculated by Monte Carlo Computer simulation. Both lattice and continuum spaces are considered and detailed microstructures of metallic fibers are modelled as rigid and flexible bodies for both model spaces. Simulations are carried out for wide range of aspect ratios and discussions are given.

Effect of Niobium on Corrosion Fatigue Properties of High Strength Steel

  • Cho, Young-Joo;Cho, Sang-Won;Kim, Jung-Gu
    • Corrosion Science and Technology
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    • v.17 no.2
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    • pp.81-89
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    • 2018
  • In this study, the effect of Nb alloying element on the corrosion fatigue properties of high strength steel is investigated by conducting fatigue experiments under corrosive condition and hydrogen induced condition, potentiodynamic polarization test, tensile test and surface analyses. Nb element is added to enhance the mechanical property of medium carbon steel. This element forms MX-type phases such as carbides and nitrides which are playing an important role in the grain refinement. The grain refinement is one of the effective way to improve mechanical property because both tensile strength and toughness can be improved at the same time. However, MX-type phase precipitates can be a susceptible site to localized corrosion in corrosive environment due to the potential difference between matrix and precipitate. The obtained results showed that Nb-added steel improved corrosion fatigue property by grain refinement. However, it is degraded for hydrogen-induced fatigue property due to Nb, Ti-inclusions acting as a stronger trap.

A Study on the China's revised foreign Trade Law (중국(中國) 대외무역법(對外貿易法)의 개정(改定)에 관한 소고(小考))

  • Jo, Jong-Ju
    • THE INTERNATIONAL COMMERCE & LAW REVIEW
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    • v.27
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    • pp.215-232
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    • 2005
  • China had revised Foreign Trade Law in order to fulfill its WTO commitments and duties, and fully exercise its rights and benefits as a WTO member. The main contents of the revised Foreign Trade Law as followed. For the first time, individuals are allowed to conduct foreign trade. Intellectual property is an important component of foreign trade, and protecting intellectual property rights is a key issue. A chapter on Intellectual property protection is one of the major additions to the Foreign Trade Law. New sections have also been added to allow and provide guidance for conducting investigations and seeking relief. Finally, the new law beefs up and clarifies enforcement procedures. It regulates the setting up of early warning and emergency systems and a foreign trade statistics system.

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Properties of Hydration Heat with Compressive Strength Level of High Flowing Self-Compacting Concrete (고유동 자기충전 콘크리트의 압축강도 수준에 따른 수화발열 특성)

  • Choi, Yun Wang;Jung, Jea Gwone;Lee, Jae Nam;Kim, Byoung Kwon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.5A
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    • pp.531-541
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    • 2009
  • The research analyzes and investigates conventional concrete, hydration heat, set, and mechanical properties by making high flowing self-compacting concretes of binary blend and ternary blend as one of evaluations about the properties of the hydration heat of high flowing self-compacting concrete with a strength of 30, 50, and 70 MPa. In addition, it estimates concrete adiabatic temperatures by calculating a thermal property value of powder obtained by measuring a heat evolution amount for powder used in concrete, a thermal property value of concrete obtained by conducting a simple adiabatic temperature test, and a normal thermal property value of material used in concrete, using a simple equation. Moreover, it analyzes and investigates the hydration heat property of high flowing self-compacting concrete and the thermal stress caused by hydration heat by conducting a 3D temperature stress analysis for the hydration heat and the adiabatic temperature obtained by temperature analysis, using MIDAS CIVIL 06 program.

A study on the electromagnetic characteristics of the octadecylviologen-$(TCNQ^-)_2$ thin films with The Langmuir-Blodgett technique (LB법으로 제작된 octadecylviologen-$(TCNQ^-)_2$ 박막의 전자기적 특성 연구)

  • Shin, Dong-Myung;Park, Je-Sang;Lee, Chang-Keun;Kang, Dou-Yol
    • Proceedings of the KIEE Conference
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    • 1995.11a
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    • pp.423-426
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    • 1995
  • Langmuir-Blodgett technique offers a convenient and elegant way to organic conducting systems for ultra thin films. In conducting systems based on LB films, TCNQ derivatives have been extensively studied as electron acceptor molecules in a large number of organic conducting systems.[1] A very interesting UV-visible spectra of octadecylviologen-$(TCNQ^-)_2$ was obtained from a methylenechloride and acetonitrile mixture, and from Langmuir-Blodgett films. The ESR characteristics of octadecylviologen-$(TCNQ^-)_2$ were studied to understand conducting mechanism and structure of LB films. The ESR spectra infer that the N-dococylquinolinium-TCNQ LB films has anisotropic property. But octadecylviologen-$(TCNQ^-)_2$ does not show angular dependence. As the temperature increases from 350K to 450K, the ESR signal of LB films becomes sharp. Scanning calorimetry(DSC) of octadecylviologen-$(TCNQ^-)_2$ provides the endothermic reaction temperature of the films, 340K, which corresponds to the temperature, 365K, of the new ESR signal.

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