• Korean Chemical Engineering Research
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• v.49 no.5
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• pp.628-632
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• 2011

L-ribose has recently attracted interest as a starting material for antiviral drug. It could be obtained from L-arabinose by epimerization reaction. Epimerization reaction was carried out with molybdenium oxide or molybdic acid catalyst and methanol/water solution. Reaction temperature, methanol percentage, and catalyst kind were selected to find an optimum reaction condition. Ion exhange chromatography was used for separating epimerization reaction mixture, and then HPLC chromatogram of L-ribose fraction obtained to calculate the yield of the reaction. Shodex ion exchange HPLC column(Model SC1011) and Phenomenex Luna $NH_2$ HPLC column were compared to employ a convenient HPLC analysis. It was found that the usage of 20% methanol, $60^{\circ}C$, and 40 g/L molybdic acid gives the best reaction condition with a yield of 21%.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.20 no.1
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• pp.49-55
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• 2024

Stainless 630 (or 17-4PH) is a precipitation-hardening martensitic stainless steel that has excellent mechanical properties and corrosion resistance. These characteristics make the STS630 to be used as a consisting material for various components such as spider, pin, spring, and spring retainer, of the control rod drive mechanism (CRDM) in pressurized water reactors (PWRs). In general, it is well known that the oxide layer of stainless steel consists of a duplex layer, a compact inner layer of FeCr₂O₄ spinel, and a coarse-grained outer layer of Fe₃O₄ spinel in PWR primary coolant condition. However, the characteristics of the oxide layer can be sensitively influenced by various water chemistry conditions such as temperature, dissolved oxygen, dissolved hydrogen, pH, pH adjuster type, and exposure time. In this work, we investigate the corrosion properties of the STS630 as a function of coolant temperature in an NH3 alkaline solution for its boron-free application in a small modular reactor, to confirm the feasibility for usage as a boron-free SMR structural material. As a result, oxide layer of corroded STS630 is consist of double-layer oxides consisting of a Cr-rich dense inner oxide and a Fe-rich polyhedral outer particles like as that in commercial PWR primary coolant. The corrosion rate of STS630 increases with increase in test time and temperature and the corrosion rate-time model equation was developed based on experimental data. Overall, it is expected that the results in this study provides useful data for the corrosion behavior of STS630 in alkaline environments, contributing to the development of selecting suitable materials for SMRs.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.8
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• pp.3537-3543
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• 2012

Therefore, to establish optimal condition and composition with magnesium chloride emulsion as coagulant, this study compared its properties by the usage of 60%(w/w) magnesium chloride solution, lastly measured the characteristics of soybean curd coagulation, coagulation time, state of texture, and water separation ratio with using emulsion as coagulant. After all the experiments, when manufacturing magnesium chloride emulsion with using 70% of quantity of 60%(w/w) magnesium chloride solution, it had the best result as coagulant according to the state of texture and the water separation ratio of soybean curd.

• Journal of the Korean Solar Energy Society
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• v.27 no.1
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• pp.47-54
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• 2007

Interests on renewable energy are increased due to oil price and environmental problems aroused from the fossil energy usage. In this study, performances of a solar assisted hybrid heat pump system are analyzed by experimental method. The developed system could runs at two types of operating mode. When the storage temperature is higher than the set temperature, the stored hot water in storage tank is supplied to the load directly. On the other hand, when the storage temperature lower than the set temperature, the water inside of the storage tank is used as heat source of the heat pump. In this study, the system control temperature for the alternation of the operating mode is set to $40^{\circ}C$ of the storage tank outlet. As results, it is founded that the COP of the developed heat pump system shows between 3.0 and 3.5. It is resonable performance for the heating system with a renewable energy as secondary heat source. The solar collect used in this study could supplies heat to the storage tank at over 400 W/m2 solar intensity. If the irradiation is lower than the 400 W/m2, the circulation pump stored and it could not supply heat to the storage tank. It is found that the difference temperature between the outlet of the storage tank and collector is $3^{\circ}C$. Even though, the extended study should be conducted to get a optimum performance of the developed system with various operating condition and control strategies.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.40 no.2
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• pp.191-195
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• 2020

In this work, tensile tests, one of the most common test method to assess the condition of a corroded pipe, were conducted. According to ASTM E8 method, the use of flat or curved uni-axial tension test is allowed under the recommendation with the usage of grips corresponding to a curvature of the pipe. However, this method is not for corroded specimen. Furthermore, in the case of performing the multiple tensile tests with various curvatures, it is desirable not to produce zigs that fit each curvatures, if merely processing the specimen grip with curvature into the flat grip can show almost identical tensile behavior. Therefore, various tension simulations were conducted first to check if there exist any differences. Also, experiments on corroded tensile specimen were conducted and compared with the FEM simulation that reflects the actual geometry acquired from the 3D scanner.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.5 no.1
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• pp.104-118
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• 1995

This study was performed to evaluate factors affecting desorption of organic solvents collected on charcoal tube and to find out the optimum condition. Desorption efficiency for polar analytes was improved when several polar desorption solvents such as methanol, dimethylformamide(DMF), 2-(2-butoxyethoxy)ethanol were added to carbon disulfide($CS_2$). The best improvement was achieved when 10% dimethylformamide(DMF) in $CS_2$ was used as desorption solvent. During storage of polar analytes, recovery was greatly reduced. Especially, the recovery of cyclohexanone was decreased to 18.1 % after a month storage at $34^{\circ}C$. After two weeks storage, recovery of polar analytes was sharply decreased. Water adsorbed on charcoal interfered the recovery of polar analytes but didn't interfere that one of nonpolar solvent, toluene. When 10% DMF in $CS_2$ was used as desorption solvent, the effect of water on recovery was decreased, comparing with Desorption efficiency increased when analyte loading increased, and usage of 10% DMF in $CS_2$ decreased the loading effect. Increasing volume of desorption solvent was not effective to improve desorption efficiency of analytes when 10% DMF was used. Continuous shaking and sonication is not helpful to increase the desorption efficiency of analytes except cyclohexanone using 10% DMF. When silica gel used as adsorbent, methanol was better desorbent than dimethylsulfoxide. Analytes adsorbed on silica gel showed high recovery in low concentration and less affected by humidity. On the basis of this study, the following conclusions have been drawn. To improve the recovery of polar organic materials in air samples, it is necessary to analyze samples as soon as possible after they were collected. Otherwise, samples must be stored at low temperature. Using two components of desorption solvents, such as 10% DMF in $CS_2$, the effects of loading and humidity decreased for polar analytes such as methyl ethyl ketone and methyl isobutyl ketone. When work place has high humidity with low concentration of polar organic solvents, silica gel can be used as adsorbent, because it produces quantitative recovery for polar analytes at this condition. But it should be noted that high humidity makes breakthrough easy in silica gel samples.

• Journal of the Korean GEO-environmental Society
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• v.23 no.10
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• pp.5-12
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• 2022

In this study, we investigated the UV/H₂O₂ process to treat organic compound-spilled water. In consideration of usage and properties, benzene, toluene, phenol, and methyl ethyl ketone were selected as representative organic compounds. The selected material was first removed by natural volatilization and aeration that simulated the pretreatment of the prcoess. After that, UV/H₂O₂ oxidation experiments were conducted under various H₂O₂ concentration conditions. Benzene and toluene were mostly volatilized before reaching the oxidation process due to high volatility. Considering the volatility, oxidation experiments were performed at an initial concentration of 5 mg/L for benzene and toluene. The UV/H₂O₂ oxidation process achieved 100% of benzene and toluene removal after 20 minutes under all hydrogen peroxide concentration conditions. The phenol was rarely removed from the volatile experiments and oxidation tests were performed at an initial concentration of 50 mg/L. The process showed 100 % phenol removal after 30 minutes under 0.12 v/v% of hydrogen peroxide concentration condition. Methyl ethyl ketone was removed 58 % after 2 hours of volatile experiments. The process showed 99.7% Methyl ethyl ketone removal after 40 minutes under 0.08 v/v% of hydrogen peroxide concentration condition. It was confirmed that the UV/H₂O₂ process showed high decomposition efficiency for the four selected organic compounds, and identified the amount of hydrogen peroxide in classified organic contaminants.

• Journal of the Daesoon Academy of Sciences
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• v.25_2
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• pp.45-70
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• 2015

Master Jeungsan understood a general view of Pungsu but actually he used the theory of Pungsu in his own religious perspective, transcending it. The theory of Pungsu is different. But the fact that it is premised on the principle of 'in and yang', the five-element principle, the Book of Changes, energy thought, and To chugi piyung, etc. is generally recognized. The three important elements of Pungsu are mountain, water, and direction or man. Pungsu has formal principles such as Gallyongbeop, Jangpungbeop, Deuksubeop, Jeonghyeolbeop, Jwahyangbeop, and Hyeongukron. etc. In the late of Joseon, Jeungsan established a new traditional thought, understanding Bibopungsu, Gukdopungsu, Minganpungsu, etc. However, he reinterpreted them to be suitable to his religious ideal and let his followers understand them as well. In particular, Jeungsan overcame the previous view on earth and expressed a new perspective to enhance earth up to the level of heaven. In the perspective of the traditional world, earth is lower than heaven, but Jeungsan made it a status equal to heaven. He mentioned that in the past, the culture and history of man was influenced by earth's energy but today, at the age of man respect, he put passive man influenced by earth-condition on the more subjective and active status. Even though he mentioned different Pungsu, Hyeongguk, and Hyeolmyeong, he expressed the shape of Pungsu within the construction of three worlds, the one of heaven and earth transcending good or ill luck or a favorable change in fortune. He practised the expedient of Pungsu from the stand of the construction of heaven and earth instead of the usage of Bibopungsu, Gukdopungsu, and Minganpungsu. He diagnosed that the division of the world is caused by the one of earth and tried to solve it. Moreover, he said that Myeongdang(a propitious site) must be the man-orientation rather than the earth-orientation. It means that Pungsu, stressing the energy of earth and turning one's luck, is changing into the world of man-orientation. In other words, Jeungsan diagnosed the world of Pungsu but he ultimately used Pungsu theory in building up his own view of religious world transcending such a theory.

• Journal of the Korean Society of Marine Environment & Safety
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• v.15 no.2
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• pp.135-142
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• 2009

This study investigates the characteristic properties of strength, flowability, durability and drying shrinkage to control strength and to reduce heat of hydration of high performance concrete using crushed stone fines. According to the experimental results, when crushed stone fines are increased every 10%, $10{\sim}15%$ of compressive strength is decreased and flowability of high performance concrete is effectively improved due to the decrease of modulus of deformation and confined water ratio. When crushed stone fines are replaced every 10%, $4^{\circ}C$ of the highest adiabatic temperature rise is decreased by reducing the unit cement. However, 5% of drying shrinkage is increased in the same condition In the meantime, durability of high performance concrete is excellent, having over 100% of good relative dynamic modulus of elasticity due to fineness of formation mused by the increase of the unit powder content and the improvement of flowability, without regard to the replacement of crushed stone fines. Therefore, It can be said that the usage of crushed stone fines can control the strength of high performance concrete by replacement and reduce heat of hydration.

• Computers and Concrete
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• v.33 no.6
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• pp.707-724
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• 2024

This paper proposes a study of cement replacement with rice husk ash (RHA) and eggshell ash (ESA) for enhanced mechanical properties of geopolymer (GP) concrete with and without admixture. The main objective is to investigate the mechanical properties of GP with various replacement levels of Pozzolana Portland cement by RHA and ESA. The GP resistance to durability is examined and impact of ash materials on concrete's durability performance is determined. The environmental benefits of using agricultural waste materials in GP manufacturing minimize cement usage and CO2 emissions. The goal is to assess value of RHA-ESA of building material, paving stones for structures to lessen environmental impact. The novelty lies in use of ESA and RHA as partial replacements for cement and investigation of admixtures to enhance concrete properties, and reduce environmental impact. The research contributes by introducing a novel approach to reducing cement consumption by using ESA and RHA to address environmental concerns. It also explores the potential benefits of admixtures improving concrete performance and reducing environmental pollution. A study is carried with and without impacts of admixture to find compressive strength of GP cubes. The cement has been replaced by RHA and ESA in the range of (2.5%+7.5%, 5%+5%, 7.5%+2.5) by weight of cement for M20 mix. The compressive strength (CS) and split tensile strength (STS) at 7days, 14 days and 28 days is obtained as 21 N/mm2 at 7.5%RHA+2.5%ESA and 2.3 at 7.5%RHA+2.5%ESA, 24 N/mm2 at 7.5%RHA+2.5%ESA and 2.3 at 7.5%RHA+2.5%ESA, 28 N/mm2 at 7.5%RHA+2.5%ESA and 2.8 at 7.5%ESA respectively with normal curing condition.