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Effect of Casting Temperature and Speed on Formation of Surface Defect in Al-8Zn-2Mg-2Cu Billets Fabricated by Direct-Chill Casting Process (수직 연속주조 공정으로 제조된 Al-8Zn-2Mg-2Cu 빌렛의 표면 결함 형성에 미치는 주조 온도와 주조 속도의 영향)

  • Lee, Yoon-Ho;Kim, Yong-You;Lee, Sang-Hwa;Kim, Min-Seok;Euh, Kwangjun;Lee, Dong-Geun
    • Journal of Korea Foundry Society
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    • v.41 no.3
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    • pp.241-251
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    • 2021
  • 7000-series aluminum alloys are noted for their superior strength compared with other Al alloys, and their billets are generally fabricated by direct-chill (DC) casting. Surface defects in a DC-cast aluminum billet are mainly related to exudation and the meniscus freezing phenomenon, which are influenced by alloy compositions, casting speed, and casting temperature. 7000-series aluminum alloys have a wide freezing range during solidification, which makes it easy for casting defects to occur. In this study, we investigated surface defect evolution in casting billets of Al-8Zn-2Mg-2Cu alloy fabricated by a DC casting process. The billets showed "wavy" or "dotted" surfaces. The wavy surface was formed by meniscus freezing at a lower casting speed (200 mm/min) and temperature (655 ℃). In the wavy surface, refined dendritic cells were observed in a concave region due to the constitutional supercooling caused by meniscus freezing. Meanwhile, at a higher casting temperature (675 ℃), the dotted surface was formed by pore formation. In the dotted surfaces in the billet formed at a high casting speed (230 mm/min), an exudation layer was formed by the high metallostatic head pressure. The dotted region and the smooth region had a refined dendritic morphology and a columnar morphology at the exudation layer, respectively. This is attributed to the formation of gas pores in the dotted region.

Environmental Effect of the Reduced Slag in the Electric Furnace (전기로 제강 환원슬래그 혼합토의 환경적 영향)

  • Na, Hyunsu;Yoon, Yeowon;Yoon, Gillim
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.7
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    • pp.23-29
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    • 2011
  • The oxidation slag has been widely used in civil engineering project, whereas the reduced slag from electric furnace has yet to be applied. Consequently in order to find out the recycling method in civil engineering field, the mineral compositions of the reduced slag were analyzed and some tests on water quality were performed to estimate the potential release of toxic compounds. Slag-soil mixtures of 0, 10, 20 and 30%(dry weight) soil were prepared in lysimeter columns and the effluents were collected with the period of one, two and four week options in closed system, respectively. The result from qualitative and quantitative analysis using X-ray Diffraction(XRD) and X-ray Fluorescence(XRF) indicates that the main mineral of the reduced slag is $Ca_2(SiO_4)$, a kind of calcium silicate. Also, the leaching medium analyzed by Inductively Coupled Plasma Optical Emission Spectroscopy(ICP-OES) showed that main heavy metals such as Al, Fe and Mn are included in the reduced slag due to the effect of steel production process. It can be seen that the leachate does not violate the regulation guide line of waste material of heavy metal. Also the pH levels were increased from pH 6.9 for 0% soil to pH 10 for 30% soil. However the influence on leachate circulation period of one through four weeks was negligible.

Synthesis and Characterization of 4-Component Polyimide Films with Various Diamine and Dianhydride Compositions (다양한 조성 변화에 따른 4성분계 폴리이미드 필름 제조와 물성분석)

  • Park, Yun Jun;Yu, Duk Man;Choi, Jong Ho;Ahn, Jeong-Ho;Hong, Young Taik
    • Applied Chemistry for Engineering
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    • v.22 no.6
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    • pp.623-626
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    • 2011
  • Various poly(amic acid)s were synthesized from PMDA/BPDA/p-PDA/ODA with different mole ratios and effectively converted into 4-component polyimide films by thermal imidization. The chemical structures and thermo-mechanical properties of polyimide films were examined using Fourier transform infrared spectroscopy (FT-IR), thermo-gravimetric analyzer (TGA), thermo-mechanical analyzer (TMA), dynamic mechanical analyzer (DMA) and universal tensile machine (UTM). The tensile strength, modulus, and thermal properties of polyimides films increased with the amount of rigid PMDA and p-PDA, while the elongation and moisture absorption of polyimide films increased with the amount of flexible BPDA and ODA. One of 4-component polyimide films exhibited a similar coefficient of thermal expansion (CTE) value to that of copper when it was composed of PMDA : BPDA : p-PDA : ODA with the ratio of 5 : 5 : 4 : 6. Thus, this polyimide film could be useful for a base film for flexible copper clad laminates (FCCL) of flexible printed circuit boards.

Suggestion of Physicochemical Characteristics and Safety Management in the Waste Containing Nanomaterials from Engineered Nano-materials Manufacturing Plants and Waste Treatment Facilities (산업용제조시설과 폐기물처리시설에서 발생된 나노폐기물의 물리화학적 특성 및 안전관리방안 제시)

  • Kim, Woo-Il;Yeon, Jin-Mo;Cho, Na-Hyeon;Kim, Yong-Jun;Um, Nam-Il;Kim, Ki-Heon;Lee, Young-Kee
    • Journal of Korea Society of Waste Management
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    • v.35 no.7
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    • pp.670-682
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    • 2018
  • Engineered nanomaterials (ENMs) can be released to humans and the environment through the generation of waste containing engineered nanomaterials (WCNMs) and the use and disposal of nano-products. Nanoparticles can also be introduced intentionally or unintentionally into waste streams. This study examined WCNMs in domestic industries, and target nanomaterials, such as silicon dioxide, titanium oxide, zinc oxide, nano silver, and carbon nanotubes (CNTs), were selected. We tested 48 samples, such as dust, sludge, ash, and by-products from manufacturing facilities and waste treatment facilities. We analyzed leaching and content concentrations for heavy metals and hazardous constituents of the waste. Chemical compositions were also measured by XRD and XRF, and the unique properties of nano-waste were identified by using a particle size distribution analyzer and TEM. The dust and sludge generated from manufacturing facilities and the use of nanomaterials showed higher concentrations of metals such as lead, arsenic, chromium, barium, and zinc. Oiled cloths from facilities using nano silver revealed high concentrations of copper, and the leaching concentrations of copper and lead in fly ash were higher than those in bottom ash. In XRF measurements at the facilities, we detected compounds such as silicon dioxide, sulfur trioxide, calcium oxide, titanium dioxide, and zinc oxide. We found several chemicals such as calcium oxide and silicon dioxide in the bottom ash of waste incinerators.

A Study on the Actual Condition of Middle School Space Usage For Future School - Focused on the Reorganization of Student-Oriented School Space - (미래학교 조성을 위한 중학교 공간사용 실태 분석 연구 - 학생중심 공간 재구조화를 중심으로 -)

  • Kim, Kyoung-Suk
    • The Journal of Sustainable Design and Educational Environment Research
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    • v.19 no.4
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    • pp.26-39
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    • 2020
  • This study analyzed the usage characteristics and requirements of students who are users of the middle school education space, and the following results were obtained: First, we could see that various types of classes were needed, such as lecture-style classes, team projects, and four-person consultation and discussion classes, in a way that helped to improve the desirable teaching patterns and learning ability. Second, the place where space was used during the break and the relationship between peers, revealed that most of them were in the classroom and the hallway, and the peer group was composed of three to eight people or more, that were active with various compositions. Third, a gym, library, toilet, stairway, cafeteria, nurse's office, and teachers' room appeared in the center of the building, indicating the need for a balanced layout. Fourth, physical education (dance) rooms, audiovisual rooms (performance rooms), workshops (personal creation), snack bar, rest area, spacious indoor square, and study rooms were needed as facilities that can help learning activities other than current facilities. These outcomes show that the existing classroom layout and space composition formats require some spatial restructuring.

Flora of crop lands in Ulleungdo Island (울릉도 농경지의 식물상)

  • Kim, Myung-Hyun;Hong, Sun-Hee;Lee, Yong-Ho;Kim, Min-Kyeong;Choi, Soon-Kun;Eo, Jinu;Yeob, So-Jin;Bang, Jeong Hwan;Oh, Young-Ju
    • Korean Journal of Environmental Biology
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    • v.39 no.2
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    • pp.245-257
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    • 2021
  • Ulleungdo, a volcanic island, has different climate, soil, and topography characteristics from inland of the Korean Peninsula. Its agriculture also exhibits distinctive features. This study focused on floristic compositions and characteristics of crop lands in Ulleungdo. Flora surveys were conducted for 37 areas three times, one in May of 2016, one in July of 2020, and one in August of 2020. Results showed that vascular plants of crop lands in Ulleungdo included 186 taxa of 53 families, 132 genera, 160 species, 14 varieties, five subspecies, and five hybrids. Asteraceae had the most diverse species (33 taxa), followed by Poaceae (25 taxa), Fabaceae (12 taxa), Polygonaceae (11 taxa), and Liliaceae (nine taxa). The biological type of crop lands in Ulleungdo island was determined to be Th-R5-D4-e type. Rare plants were found for nine taxa: Athyrium acutipinnulum Kodama ex Nakai, Sedum takasimense Nakai, Rubus takesimensis Nakai, Dystaenia takesimana (Nakai) Kitag., Ligustrum foliosum Nakai, Aster pseudoglehni Y.Lim, Cirsium nipponicum (Maxim.) Makino, Lilium hansonii Leichtlin ex D.D.T.Moore, and Polygonatum robustum (Korsh.) Nakai. In addition, 45 taxa contained naturalized plants of 13 families, 33 genera, 44 species, and one variety. Urbanization and naturalization indices were 13.9%, and 24.2%, respectively.

Compositions and Provenience Studies on Horse Armour Excavated from Changnyeong Gyo-dong and Songhyeon-dong Tumuli (창녕 교동과 송현동 고분군 출토 마구류(馬具類)의 조성 및 원료 산지 추정)

  • Han, Woorim;Park, Jiyeon;Kim, Sojin
    • Korean Journal of Heritage: History & Science
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    • v.54 no.1
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    • pp.4-17
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    • 2021
  • This study analyzed 19 samples of harness fittings and pendants, which were excavated in Tomb No. 15 in Songhyeon-dong, Changnyeong. Harness fittings and pendants are used for ostentation, rather than practicality, and were excavated from ancient tombs in Gaya culture. So, they are considered artifacts that compare the production techniques and raw materials. This study aimed to examine the production techniques and provenience studies of Bihwa Gaya, which is estimated to be from the 5th to 6th centuries. According to the research, harness fittings were made of pure copper and were gilded with Au·Ag alloys on their surfaces. Hg was detected together and plated with a mercury amalgam method. As a result of the pendant (fish scales-pattern, oval and fish-tail shape), analysis showed that Fe in the background metal, Cu in the middle layer, and Au and Ag on the surface were the main components. The method of adhesion between Cu and Au·Ag gilded layers are plated by a mercury amalgamation method. So, it was identified by the gilt-iron·gold·bronze technique. Since the pendant (heart shaped) is found to be the main component of Fe in the background metal and Ag in the surface layer, the metal was made gilt-iron·silver technique. The background metal and gilding were additionally fixed using a rivet. The raw materials of 3 harnesses excavated from Changnyeong are plotted in zone 2 in the southern Korean Peninsula. And 16 harnesses were plotted in Chinese copper ore by Mabuchi Hishao in the Chinese Peninsula.

Effects of dietary glycerol inclusion on growth performance, carcass and meat quality characteristics, glycogen content, and meat volatile compounds in Korean cattle steers

  • Piao, Minyu;Jung, Da Jin Sol;Kang, Hyeok Joong;Park, Seung Ju;Lee, Jin Oh;Kim, Minsu;Kim, Hyun Jin;Kim, Do Hyun;Seo, Ja Kyeom;Jo, Cheorun;Haque, Md Najmul;Baik, Myunggi
    • Animal Bioscience
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    • v.34 no.4
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    • pp.603-612
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    • 2021
  • Objective: We have tested our hypothesis that inclusion of purified glycerol as a replacer of portions of dried distillers grain with solubles (DDGS) would affect growth performance, rumen fermentation and blood parameters, carcass and sensory traits, reducing sugar and glycogen contents, and volatile compound profiles in longissimus thoracis (LT) in Korean cattle steers. Methods: A total of 20 Korean cattle steers (27.0±0.2 months old; 647±10.5 kg body weight [BW]) were assigned to a conventional control group or a glycerol group (3.17% purified glycerol addition as a replacement for DDGS and molasses). The steers were individually allowed to receive the experimental concentrate at the daily amount of 1.5% of their individual BW and a total 1.0 of kg/d of rice straw twice daily. The feeding trial was conducted for a period of 20 weeks. Results: Glycerol supplementation (GS) increased (p = 0.001) concentrate intake. However, GS did not affect (p>0.05) average daily gain, feed efficiency, and ruminal volatile fatty acid concentrations. GS tended to increase (p≤0.10) serum glucose concentrations at the 16th and 20th weeks. GS decreased (p = 0.001) LT pH. GS did not affect (p>0.05) carcass traits and the chemical or physicochemical compositions, reducing sugar or glycogen contents, sensory traits, and most of volatile compounds in the LT. Conclusion: The inclusion of purified glycerol as a replacement for DDGS in the finishing diet did not affect growth performance, rumen fermentation parameters, and carcass quality in Korean cattle. The purified glycerol could be used as a substitute for other energy sources such as DDGS in beef cattle, depending on the price.

SHRIMP Zircon U-Pb Ages of Basement Rocks in the Danyang National Geopark (단양 국가지질공원 기반암류의 SHRIMP 저어콘 U-Pb 연령)

  • Cheong, Wonseok;Han, Giun;Kim, Taehwan;Aum, Hyun Woo;Kim, Yoonsup
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.4
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    • pp.339-347
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    • 2020
  • We carried out the U-Pb age dating of zircon from basement rocks in the southern part of the Danyang National Geopark. Two migmatitic gneisses composed of biotite±sillimanite±garnet+feldspar+quartz were dated. Leucosomes in the samples were clearly distinguished from their melanosomes. The U-Pb isotopic compositions of zircon from sillimanite- and garnet-bearing migmatitic samples were measured using a secondary ion microprobe, yielding metamorphic ages, 1870±10 Ma (2σ)와 1863±6 Ma (2σ), respectively. 1.87~1.86 Ga metamorphic ages are consistent with those of the Paleoproterozoic low-P and high-T regional metamorphism (1.87~1.85 Ga) in the Yeongnam Massif. The maximum depositional age based upon the apparent 207Pb/206Pb ages of detrital zircon in the samples was estimated as 2.06 Ga, and thus sedimentation age of the protolith of the migmatitic gneisses ranges between 2.06 and 1.87 Ga.

Changes in Growth and Productivity Characteristics by Sowing Date on Spring Sowing Rapeseed (Brassica napus L.) in Paddy Field of Southern Region of South Korea (남부지역 유채(Brassica napus L.) 논재배 봄파종 시 파종시기에 따른 생육 및 수량 특성 변화)

  • Kwon, Da-Eun;Kim, Kwang-Soo;Hwang, Eom-Ji;Park, Jin-Cheon;Lee, Ji-Eun;Lee, Yeong-Hoon
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.66 no.1
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    • pp.80-86
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    • 2021
  • The purpose of this study was to determine the optimal sowing date for the spring sowing cultivation of rapeseed (Brassica napus L.). To determine suitable rapeseed sowing dates for spring sowing cultivation, changes in growth, flowering characteristics, and seed production were investigated in Muan, South Korea between 2019 and 2020. 'Jungmo7001' is the suitable variety for spring sowing because of its early flowering characteristics, high seed yield, and the fact that it occupies the highest cultivation area in South Korea. When the yield of 'Jungmo7001' was investigated in 2019 and 2020, the highest yields recorded were 243 kg/10a in February 28, 2019, and 294 kg/10a in February 18, 2020. As a result, the optimal rapeseed seeding period is considered to be mid-to-late February in the southern region. There was no statistically significant difference in seed crude oil content. The content of oleic acid (C18:1) decreased, but that of linoleic acid (C18:2) and of linolenic acid (C18:3) increased significantly depending on the sowing date.