• Title/Summary/Keyword: compositional characteristics

Search Result 212, Processing Time 0.026 seconds

Fabrication of the Functional Coatings of a Tubular Solid Oxide Fuel by Plasma Spray Processes. (플라즈마 용사법을 이용한 원통형 고체산화물 연료전지의 요소피막 제조)

  • 주원태;홍상희
    • Journal of the Korean institute of surface engineering
    • /
    • v.30 no.5
    • /
    • pp.333-346
    • /
    • 1997
  • Plasma spray processes for functional coatings of tubular SOFC ( Soild oxide Fuel Cell).consisting of air electrode, oxide electrolyte, an fuel electrode, are optimized by fully saturated fractional factorial testing. Material and electric characteristics of each coating are analtsed by the implementation of SEM and optical microscope for evaluating microstructure and porosity, X-ray diffraction method for investigating compositional change between raw powder and sprayed coating, and Van der Pauw method for measuring electrical conductivity. LSM ($La_{0.65}Sr_{0.35}MnO_3$air electrode and Ni-YSL fuel electrode coatings have porosities of around 23~30% sufficient for effective fuel and oxidant gas supply to electrochemical reaction interfaces and electrical conductivities of around 90 S/cm and 1000 S/cm, respectively, enough for acting as current collecting electrodes. YSZ($ZrO_2-8mol%Y_2O_3$) electrolyte film has a high ionic conductivities of 0.05~0.07 S/cm at $1000^{\circ}C$ in air atmosphere, but appears to be somewhat too porous to reduce the thickness. for enhancing the cell efficiency. A unit tubular SOFC has beem fabricated by the optimized plasma spray processes for each functional coating and the cell. Its electrochemical chracteristics are investigated by measuring voltage-current and power density with variation of operationg temperature, radio of fuel to air gas flowrates, and total gas flowrate of reactants.

  • PDF

Development of AlN/Al-Ti Functionally Gradient Materials (AlN/Al-Ti계 경사기능재료의 개발)

  • 이현규;박진성;공창덕
    • Journal of the Korean Society of Propulsion Engineers
    • /
    • v.5 no.1
    • /
    • pp.49-59
    • /
    • 2001
  • Functionally gradient materials(FGMs) generally consist of different material components, such as ceramics and metals. Continuous changes in their composition, microstructure, porositys, and so on result in gradients in the properties of FGMs. In this study AlN/Al-$Al_3$Ti FGM cubes were fabricated by the powder metallurgical process, and the characteristics of the FGMs were investigated. Powders of Mg and Ti mixed with Al in different ratios or the stack of the mixed powders having a stepwisely controlled compositional gradient from one plane to another were formed in a steel mold. The more the composition of Mg and sintering temperature are increased, the more the amount of AlN is formed. AlN and $Al_3$Ti distributed with continuously gradient composition were detected by XRD analysis and also revealed in optical microstructures, and microhardness tests.

  • PDF

Organic Solvent Absorption Characteristics of Split-type Microfiber Fabrics

  • Lee Kwang Ju;Kim Seong Hun;Oh Kyung Wha
    • Fibers and Polymers
    • /
    • v.5 no.4
    • /
    • pp.280-288
    • /
    • 2004
  • Split-type nylon/polyester microfiber and polyester microfiber fabrics possess drapeability, softness, bulkiness, and smoothness, so that they can be applied in various industrial fields. In particular, these fabrics are able to absorb various organic solvents, and can be used as clean room materials. To investigate the chemical affinity between solvents and the compositional materials of these fabrics, the contact angle of thermally pressed film fabrics was measured with different solvents. The thermally pressed nylon/polyester fabric films showed a chemical attraction to formamide. The sorption properties of the microfiber fabrics were investigated using a real time testing device, and these tests showed that the sorption behavior was more influenced by the structure of the fibrous assembly than by any chemical attraction. The effect of the fabric density, specific weight, and sample structure on the sorption capacity and rate was examined for various organic solvents. The sorption capacity was influenced by the density and the specific weight of the fibrous assembly, and knitted fabric showed a higher sorption capacity than woven fabric. However, the sorption rate was less affected in lower viscosity solvents. On applying Poiseuille's Law, the lower viscosity solvents showed higher initial sorption rates, and more easily penetrated into the fibrous assembly.

A Study on the Characteristic of Viewing Satisfaction and Viewing Behavior on the Exhibition Environment of Art Museum - Focusing on the exhibition spaces exhibit by flat works - (미술관의 물리적 전시환경에 대한 관람 만족도와 관람행태의 특성에 관한 연구 - 평면작품 위주의 전시공간을 중심으로 -)

  • Lee, Kyoo-Hwang
    • Korean Institute of Interior Design Journal
    • /
    • v.21 no.3
    • /
    • pp.11-21
    • /
    • 2012
  • In order to increase visitors' viewing satisfaction and viewing behavior in the art museum exhibit by flat works, it is necessary to analyze the characteristics of major evaluation factors, such as 'the number of artworks and their intervals', 'the space of exhibition and the size of walls', and 'compositional change of exhibition spaces', which have a close relationship with each evaluation factors, by focusing on artworks and exhibition space. Thus, to investigate how the characteristic differences of the major evaluation factors in art museums affect visitors' viewing satisfaction and viewing behavior, this study compared the related analytical indicators, and conducted a correlation analysis. The results of this study are summarized as follows: First, the degree of concentration on artworks (which has been selected as a collective assessment indicator of visitors' satisfaction) increased when the exhibition space of art museum is display by less artworks and they have big interval in the large wall. Second, visitors' viewing satisfaction and qualitative viewing behavior increased when the exhibition space of art museum are simple and they change to simpler step by step. These findings imply that there is a high correlation between visitors' visio-perceptual experiences and viewing behavior, and that visitors' viewing satisfaction and viewing behavior can be predicted partially in the certain exhibition environment from this correlation.

  • PDF

A Study on the Characteristics change of WSix Thin Films by S/H Life Time (S/H Life Time에 따른 WSix의 특성 변화에 관한 연구)

  • 정양희;강성준
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.6 no.5
    • /
    • pp.689-695
    • /
    • 2002
  • Film compositions are needed in semiconductor manufacturing for such diverse application as production tool qualifications and process development. Surface and interface information is generally provided with Auger electron spectroscopy(AES). In this paper, WSix films were analyzed for structural, electrical, and compositional properties of tungsten silicide thin films produced by low pressure chemical vapor deposition as a function of temperature, DCS post flow, shower head life time, and the silicon to tungsten ratios have been investigated. We find that Si/W composition ratio is increased in the surface and interface of WSix thin films by the DCS post flow process and increasing deposition temperature, respectively. The results obtained in this study are also applicable to process control of WSix deposition for memory device fabrication.

Compositional Differences of Bojungikgi-tang and Yukmijihwang-tang Decoctions Produced by the Extractors Made of Various Materials (전탕 용기에 따른 보중익기탕과 육미지황탕 전탕액 비교 연구)

  • Kim, Jung-Hoon;Lee, Nari;Shin, Hyeun-Kyoo;Seo, Chang-Seob
    • Korean Journal of Pharmacognosy
    • /
    • v.45 no.3
    • /
    • pp.249-255
    • /
    • 2014
  • This study compared Bojungikgi-tang (BIT) and Yukmijihwang-tang (YJT) decoctions produced using the extractors made of various materials, such as glass, earthenware, and stainless steel, for 60, 90, and 120 min. The extraction yield was measured and the amounts of marker compounds in decoctions were determined by quantitative analysis using high performance liquid chromatography. The extraction yields of BIT decoctions produced by three extractors were not significantly different, whereas the extraction yield of YJT produced using glass extractor was significantly higher than that of YJT produced using earthenware extractor after 90 min. The amounts of most marker compounds were highest in BIT decoctions produced using glass extractor. However, variations of the amounts of marker compounds were observed in YJT decoctions and the volatile compound was not easily vaporized in YJT decoction produced using earthenware extractor. This study suggests that the extractor made of various materials may affect the extraction efficiency and the contents of marker compounds, especially in the decoction produced using earthenware extractor, although the results were dependent on the characteristics of herbal formula.

The Characteristics and Optimization of Brown Rice Cookies Prepared using Chungkukjang (청국장분말 첨가 발아현미 쿠키의 품질특성 및 최적화)

  • Song, Yun-Hee;Joo, Na-Mi
    • Journal of the Korean Society of Food Culture
    • /
    • v.24 no.3
    • /
    • pp.321-330
    • /
    • 2009
  • This study was conducted to develop a recipe for a nutritional cookie containing chungkukjang powder that had a composition of ingredients and a texture that resulted in a high preference by all age groups. Wheat flour was partially substituted with chungkukjang powder to reduce its content. Response surface methodology was then used to analyze the measured results, which showed 16 experimental points including 2 replicates for chungkukjang powder, butter and sugar. The compositional and functional properties were then measured, after which these values were applied to a mathematical model. A canonical form and perturbation plot revealed the influence of each ingredient on the final mixture. The results of the sensory evaluation showed significant values with respect to color (p<0.01), texture (p<0.05) and overall quality (p<0.05). Taken together, the results of this study indicated that the optimal ratio was 26.57 g of chungkukjang powder, and 82.08 g of butter for every 52.36 g of sugar. The physical and chemical sensory measurements were then evaluated by a t-test, and the results revealed significant differences in the flavor of the optimized cookie when compared to the control cookie.

Characterization of Selenium (Se) Distribution in Soils and Crops at Moi-san, Haenam (해남 모이산 인근 토양 및 농작물의 셀레늄(Se) 분포 특성)

  • Kim, Seon-Ok;Cheon, Se Weon;Park, Gyu-Ryeong;Wang, Sookyun
    • Economic and Environmental Geology
    • /
    • v.48 no.3
    • /
    • pp.213-219
    • /
    • 2015
  • Samples from soils and crops were collected and analyzed in order to investigate the interactions of selenium among rocks, soils, and crops by hydrothermal alteration near epithermal mines in the region of Mio-san, Haenam. Soil samples included 6 samples each from mountain and farm area and compositional minerals and their contents were analyzed by water content, pH, ICP, XRD, XRF. Crop samples from onion and scallion were analyzed for chemical composition to elucidate the relationship with soils. Results from XRD analysis for soil samples showed that major compositional minerals are qualtz and feldspar, and illite, chlorite, hematite formed by hydrothermal alteration were included on a small scale. The pH ranges of soil samples from mountain and farm were measured at 4.6~4.9 and 5.2~6.7, respectively. The higher pH in farm soils may result from fertilization during agricultural activities. Results from ICP analysis showed that, compared to soil samples from mountain area with no potassium and calcium, significant amount of K and Ca were detected in soil samples from farms which is affected by fertilization. In a similar manner, potassium and calcium were absorbed and detected in crop samples at relatively high concentrations (116.89~169.79 ppm for K and 20.18~32.29 ppm for Ca). While the selenium contents in soil samples ranged from 18.35 ppb to 70.31 ppb which showed no significant difference, high concentrations of selenium were detected in onion (119.48~179.50 ppb) and scallion (146.65 ppb). These difference in enrichment for each element may result from the distinctive adsorption characteristics depending on crops.

Compositional Changes of Kochujang During Fermentation in Onggis with Different Physical Properties (물리적 특성이 다른 옹기에서의 고추장 발효 중 성분 변화)

  • Chung, Sun-Kyung;Lee, Kwang-Soo;Lee, Dong-Sun;Lee, Se-Hoon
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
    • /
    • v.13 no.2
    • /
    • pp.51-58
    • /
    • 2007
  • This research investigated the effect of different onggi containers (Korean earthenware) on the ripening of kochujang (Korean hot pepper paste). The physical characteristics of 'onggi', were evaluated as function of manufacturing variables such as raw material soils (onggi-specific soil, red brown soil, and fine powdered soil) and galzing treatments. The physical properties were then related to the compositional quality changes of the kochujang fermented at $30^{\circ}C$ for 4 months. The porosity of the onggi containers seems to be increased by the content of finer raw soil rather than the chemical component of soil (amount of CaO, MgO, $K_2O$ and $Na_2O$, acting as melting aid in the firing). Natural glaze was measured to contain higher contents of CaO, MgO, $K_2O$ and $Na_2O$ than the other soils, which is desirable property for the fired onggi. The glazed surface showed higher far-infrared radiation emissivity than the non-glazed part. The kochujang fermented in P0-BG (the glazed onggi from 100 % onggi soil) attained higher concentration of reducing sugar, amino nitrogen and nucleotides compared to those in the other onggis. All of these changes of kochujang in P0-BG resulted in significantly better sensory quality than the other treatments.

  • PDF

Effects of genotype and environmental factors on content variations of the bioactive constituents in rice seeds (벼의 유전형질과 재배환경 요인이 기능성물질 함량 변이에 미치는 영향 비교)

  • Soo-Yun Park;Hyoun-Min Park;Jung-Won Jung;So Ra Jin;Sang-Gu Lee;Eun-Ha Kim;Seonwoo Oh
    • Journal of Applied Biological Chemistry
    • /
    • v.65 no.4
    • /
    • pp.429-438
    • /
    • 2022
  • The composition of crops reveal natural variation according to genetic characteristics and environmental factors such as the cultivated regions. For comparative investigation of the impact of genetic difference and environmental influence on the levels of bioactive components in rice seeds, 23 cultivars including indica, japonica, and tongil rice were grown in two location in Korea (Jeonju and Cheonan) for two years (2015 and 2016). Sixteen compounds consisting of tocopherols, tocotrienols, phytosterols, and policosanols were identified from 368 rice samples and the compositional data were subjected to data mining processes including principal component analysis and Pearson's correlation analysis. Under 4 different environmental conditions (Jeonju in 2015, Cheonan in 2015, Jeonju in 2016, Cheonan in 2016), the natural variability of rice seeds showed that the genetic background (indica vs japonica vs tongil) had more impact on the compositional changes of bioactive components compared to the environments. Especially, the results of correlation analysis revealed negative correlation between α-, β-tocopherols and γ-, δ-tocopherols as a representative genetic effect that did not changed by the environmental influence.