• Bulletin of the Korean Chemical Society
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• v.29 no.3
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• pp.541-545
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• 2008

Stable molecular isomers were calculated for the azobenzene crown ether p-tert-butylcalix[4]arene (1) in the host and their alkali-metal-ion complexes. The structures of two distinct isomers (cis and trans) have been optimized using DFT B3LYP/6-31G(d,p) method. Trans isomer of 1 is found to be 11.69 kcal/mol more stable than cis analogue. For two different kinds of complexation mode, the alkali-metal-cation in the crown-ether moiety (exo) has much better complexation efficiency than in the benzene-rings (endo) pocket for both isomers of 1. Sodium ion has much better complexation efficiency than potassium ion in all kinds of complexation mode with host 1. The Na+ complexation efficiency of the trans-complex (1) in the exo-binding mode is 8.24 kcal/mol better than cis-exo analogue.

• Journal of the Optical Society of Korea
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• v.15 no.2
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• pp.202-206
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• 2011

We propose a tunable flat-top bandpass filter to pass light in a customized wavelength band by using long-period fiber gratings (LPFG) structure. The LPFG structure is composed of a core mode blocker in between two LPFGs. The bandpass spectrum of the proposed structure is obtained in overlapped wavelength band of two LPFGs operating on the same modes. To analyze the properties, we introduce a mathematical matrix model for the structure. We theoretically demonstrate flexibility of the flat-top bandpass filter with various bandwidths.

• The Transactions of the Korean Institute of Electrical Engineers D
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• v.49 no.5
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• pp.269-277
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• 2000

We propose two new types multi-stage blind clustering equalizers for QAM demoulation, which are called a complex classification algorithm(CCA) and a radial basis function algorithm(RBFA). The CCA uses a clustering technique based on the joint gaussian probability function and computes separately the real part and imaginary part for simple implementation as well as less computation. In order to improve the performance of CCA, the Dual-Mode CCA(DMCCA) incorporates the CCA tap-updating mode with the decision-directed(DD) mode. The RBFA reduces the number of cluster centers through three steps using the classification technique of RBF and then updates the equalizer taps for QAM demodulation. Test results on 16-QAM confirm that the proposed algorithms perform better the conventional multi-state equalizers in the senses of SER and MSE under multi-path fading channel.

• Bulletin of the Korean Chemical Society
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• v.31 no.4
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• pp.829-834
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• 2010

Ligand variation was carried out on a cobalt(III) complex of Salen-type ligand comprised of 1,2-cyclohexenediamine and salicylaldehyde bearing a methyl substituent on 3-position and -[$CMe(CH_2CH_2CH_2N^+Bu_3)_2$] on 5-position, which is a highly active catalyst for $CO_2$/propylene oxide copolymerization. Replacement of the methyl substituent with bulky isopropyl group resulted in alteration of the binding mode, consequently lowering turnover frequency significantly. Replacement with an ethyl group preserved binding mode and activity. Replacement of the tributylammonium unit with trihexylammonium or trioctylammonium, or replacement of 1,2-cyclohexenediamino unit with -$NC(Me)_2CH_2N$- decreased activity, even though the binding mode was unaltered.

• Proceedings of the IEEK Conference
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• 2007.07a
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• pp.433-434
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• 2007

This paper describes a low-voltage dynamic random-access memory (DRAM) focusing on subthreshold leakage reduction during self-refresh (sleep) mode. By sharing a power switch, multiple iterative circuits such as row and column decoders have a significantly reduced subthreshold leakage current. To reduce the leakage current of complex logic gates, dual channel length scheme and input vector control method are used. Because all node voltages during the standby mode are deterministic, zigzag super-cutoff CMOS is used, allowing to Preserve internal data. MTCMOS technique Is also used in the circuits having no need to preserve internal data. Sub-1.2-V 1-Gb mobile DDR DRAM employing all these low-power techniques was designed in a 60 nm CMOS technology and achieved over 77% reduction of overall leakage current during the self-refresh mode.

• Journal of Electrical Engineering and Technology
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• v.3 no.2
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• pp.243-253
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• 2008

This paper deals with the analysis, design, and implementation of a single phase AC-DC Zeta converter with high frequency transformer isolation and power factor correction(PFC) in two modes of operation, discontinuous current mode of operation(DCM), and continuous current mode of operation(CCM). A Digital Signal Processor(DSP) based implementation is carried out for validation of the Zeta converter developed design in discontinuous mode of operation. A comparison of both modes of operation is presented for a 1kW power rating from the point of view of steady state and dynamic behavior, power quality, simplicity, control technique, device rating, and converter size. The experimental results of a developed prototype of Zeta converter are presented for validation of the developed design. It is observed that CCM is most suitable for higher power applications where it requires some complex control and sensing of the additional variables.

• Journal of the Korean Society for Precision Engineering
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• v.22 no.6 s.171
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• pp.98-108
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• 2005

Conventional robot manipulators actuated by motors with the speed reducer such as the harmonic drive have weakness in the load capacity, since the speed reducer does not have enough strength. To improve this, a new type of robot actuator based on the four-bar-link mechanism driven by the ball screw was constructed. Also, a new type of revolute robot manipulator composed of the developed actuators was developed. But, modelling errors occur due to the off-set from the nominal model since the exact modeling of the complex inertia variation of the four-bar-link actuator is very difficult. To control the proposed robot along the prescribed trajectory, a sliding mode control algorithm was applied with compensation function for the modeling errors. To show performance of the proposed controller, a computer simulation was performed, and its results was presented.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.19 no.2
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• pp.169-175
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• 2009

This paper presents motion control of the Inchworm composed of the piezoelectric actuators and mechanical elements. Piezoelectric actuator shows nonlinear response characteristics including hysteresis due to the ferroelectric characteristics. This paper proposes feedback control scheme to improve the ability of tracking response to complex input signal and suppress the phenomenon of hysteresis using the sliding mode control technique with the integrator. The sliding mode control system has the limit to minimize both the settle time and overshoot. For making up this limit, this paper also suggests input shaping technique suitable to the inchworm control system.

• Advances in nano research
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• v.15 no.1
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• pp.25-34
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• 2023

This paper investigates the dynamics and stability of steady states in a continuous and discrete-time single-mode laser system. By using an explicit criteria we explored the Neimark-Sacker bifurcation of the single mode continuous and discrete-time laser model at its positive equilibrium points. Moreover, we discussed the parametric conditions for the existence of period-doubling bifurcations at their positive steady states for the discrete time system. Both types of bifurcations are verified by the Lyapunov exponents, while the maximum Lyapunov ensures chaotic and complex behaviour. Furthermore, in a three-dimensional discrete-time laser model, we used a hybrid control method to control period-doubling and Neimark-Sacker bifurcation. To validate our theoretical discussion, we provide some numerical simulations.

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3695-3702
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• 2013

A nickel(II) complex $[Ni(H_2biim)_2(H_2O)_2](ClO_4)_2{\cdot}H_2O$ (1) of biimidazole ligand has been synthesized and characterized (Where $H_2biim$ = 2,2'-biimidazole). The single crystal X-ray diffraction of the complex shows a dimeric structure with six coordinated psudo-octahedral geometry. The cyclic voltammograms of complex exhibited one quasireversible reduction wave ($E_{pc}=-0.61V$) and an irreversible oxidation wave ($E_{pa}=1.28V$) in DMF solution. The interaction of the complex with Calf-Thymus DNA (CT-DNA) has been investigated by absorption and fluorescence spectroscopy. The complex is an avid DNA binder with a binding constant value of $1.03{\times}10^5M^{-1}$. The results suggest that the nickel(II) complex bind to CT-DNA via intercalative mode and can quench the fluorescence intensity of EB bind to CT-DNA with $K_{app}$ value of $3.2{\times}10^5M^{-1}$. The complex also shown efficient oxidative cleavage of supercoiled pBR322 DNA in the presence of hydrogen peroxide as oxidizing agent. The DNA cleavage by complex in presence of quenchers; viz. DMSO, KI, $NaN_3$ and EDTA reveals that hydroxyl radical or singlet oxygen mechanism is involved. The complex showed invitro antimicrobial activity against four bacteria and two fungi. The antimicrobial activity was nearer to that of standard drugs and greater than that of the free ligand.