• Title/Summary/Keyword: complex degradation

검색결과 441건 처리시간 0.026초

복합열화로 인한 옥외용 에폭시수지의 내트래킹성 변화 (The variations of tracking resistance of outdoor Epoxy composites due to complex degradation)

  • 김탁용;김경민;이덕진;손인환;가출현;김재환
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 D
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    • pp.1614-1616
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    • 1999
  • Epoxy resin has been used as matrix resin of advanced composites owing to ideally suitable properties and inherent physical and chemical properties for electrical and electronic insulation. In this paper, in order to evaluate the performance of epoxy composites for out door insulation, variations of tracking resistance were investigated on the complex ageing parameter. Also, IPN methods were introduced in order to improve performance for out door use. As a result, it was confirmed that tracking resistance were degraded with complex ageing parameters. But, it was confirmed that specimen of IPN structure have the better tracking resistance properties than SIN structure by moisture absorption aging.

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공동주택 토목공사의 책임기술자와 품질의 상관관계 분석 (Correlation analysis of the quality and civil construction engineer in apartment house)

  • 정상훈
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2015년도 추계 학술논문 발표대회
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    • pp.70-71
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    • 2015
  • Construction period is longer than the non-disclosure in civil construction of apartment house. And this process is intensive at the beginning and end of construction. Because this project management expertise is required. Nevertheless, subsidiary work(Working avoid a tendency of advanced technician, Frequent turnover and employment contracts, etc.) management attention of construction is at a lower level. Because of, there are the bad factors(trial and error, finish degradation, etc.). Therefore, this study analyzed Hindrance Factor of quality control on apartment complex construction work and presented importance of civil construction engineer's role. Also, forms of civil construction engineer, Performance experience and technical Strength of apartment complex construction was investigated for the construction. To this end, It analyzes the relationship between forms of civil construction engineer, Performance experience and technical Strength of apartment complex construction and Construction of evaluation as required by Construction Technology Management Act.

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Development of a Rapid Spectrophotometric Method for Detecting Bacterial Mucinase Complex

  • Kim, Yoon-Hee;Cha, Jae-Ho
    • Journal of Microbiology and Biotechnology
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    • 제12권2호
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    • pp.345-348
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    • 2002
  • A rapid spectrophotometric method for detecting the mucinase complex was developed. Bovine submaxillary mucin is cleaved by commercial mucinase between the oligosaccharide chain and the side chain of peptide linkage, thereby liberating the N-acetyl neuraminic acid (NANA). The release of NANA resulted in an increase of absorbance at 280 nm. The susceptibility to NANA by the new method was found to be at least 10-fold more sensitive than the thiobarbituric acid method. Moreover, the quantification of NANA released from mucin by commercial neuraminidase and partially purified Vibrio parahaemolyticus mucinase showed a good linear correlation in proportion to the concentration of the enzyme used. These results demonstrate that the rapid identification of mucin degradation can be determined by a spectrophotometric assay, thereby providing a new, fast, and sensitive method for assaying the bacterial mucinase complex.

지하 콘크리트 구조물 조인트에 대한 멤브레인 방수시스템의 복합 환경 대응 성능 평가 방법 (Complex Environmental Degradation Resistance Performance Evaluation Method of Membrane Waterproofing Systems for Underground Concrete Structure Joint)

  • 오규환;김병일;오상근
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 춘계 학술논문 발표대회
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    • pp.44-45
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    • 2017
  • There are various national standards designed to test the physical properties of waterproofing materials for the respective countries based on each of their environmental parameters, variables and requirements. The problems of these standard systems can be outlined in the following: (1) there are too many test methods and criteria to satisfy in order assess one waterproofing membrane system, and (2) there is currently no known method to compile the separate testing results to provide a comprehensive report on waterproofing system durability. This paper outlines and compares the performance testing results of various types of asphalt waterproofing membrane systems and discusses the potentials of a complex environmental deterioration analysis method.

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오메프라졸의 안정화를 위한 에칠렌디아민 복합체 개발 (Ethylenediamine Complex for Stabilization of Omeprazole)

  • 오세종;김은영;김길수;김윤정;이계주
    • Journal of Pharmaceutical Investigation
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    • 제25권1호
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    • pp.9-17
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    • 1995
  • To stabilize omeprazole(OMP), ethylenediamine(ED) complex of omeprazole(OMPED) was prepared by reaction between OMP and ED in methanol, and the complex formation was confirmed by the instrumental analysis, i.e., IR, DSC, EA, NMR, MS and XRD. The rates of decomposition of OMP and OMPED in aqueous solution and the shelf lives at standard temperature were measured by accelerated stability analysis. The results are summarized as follows; The mole ratio of OMP and ED in OMPED complex is 1:1, the energy of formation within OMPED might be combined between polar imidazole group of OMP with induced a dipole amine group in the readily polarizable ED molecule. At standard temperature the degradation rate constant of OMP in aqueous solution is $2.540{\times}10^{-2}\;hr^{-1}$ and the shelf life is 4.15 hrs, and in the case of OMPED the degradation rate constant is $7.986{\times}10^{-4}\;hr^{-1}$ and the shelf life is 131.96 hrs. So, the OMPED has about 31 times longer shelf life than OMP. The activation energy of OMP and OMPED are 5.23 and 18.55 kcal $mole^{-1}$ respectively. The stability of OMP is dependent chiefly on pH in the solutions and it decomposes readily in acidic medium by hydrogen ion catalized reaction but becomes stable beyond pH 9.0. In case of the ED-complex, OMPED is stable in neutral as well as in dilute acidic solutions even in pH 6, OMPED is very stable to light(UV), that is, the rate constant and shelf life of OMP are $k=1.0188{\times}10^{-2}\;day^{-1}$, $T_{90%}=4.5 \;days$, on the other hand, the those of OMPED are $k=7.138{\times}10^{-4}\;day^{-1}$, $T_{90%}=64.1\;days$, respectively. From the above results, it is thought that new dosage forms could be developed by using the OMPED as a potential OMP complex.

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몇 개의 전이금속 이온과 고분자와 고분자 Complex의 합성과 특성연구 (Synthesis and Characterization of Polymer and Polymer Complex with Some Transition Metal Ions)

  • Badr, S.K.;Mohamed, T.Y.
    • 대한화학회지
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    • 제54권1호
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    • pp.43-48
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    • 2010
  • p-페닐렌 디아민과 maleic anhydride, 아세틸 아세톤과 커플된 O-아미노 페놀의 아조화합물으로 부터 폴리이미드가 만들어졌다. 합성된 폴리이미드(PA)는 DMF용매 속에 다른 몰비율로 녹아있는 $Co^{+2},\;Cr^{+2},\;Ni^{+2},\;Cu^{+2},\;Zn^{+2},\;Cd^{+2}$ and $Fe^{+3}$ 를 포함하는 전이금속이온들의 금속염들과 함께 환류되었다. 이 complex들은 원소분석과 열분석, IR, $^1H$ NMR으로 구조분석, 특성 연구되었다.

Selection of Multienzyme Complex-Producing Bacteria Under Aerobic Cultivation

  • Pason Patthra;Chon Gil-Hyong;Ratanakhanokchai Khanok;Kyu Khin Lay;Jhee Ok-Hwa;Kang Ju-Seop;Kim Won-Ho;Choi Kyung-Min;Park Gil-Soon;Lee Jin-Sang;Park Hyun;Rho Min-Suk;Lee Yun-Sik
    • Journal of Microbiology and Biotechnology
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    • 제16권8호
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    • pp.1269-1275
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    • 2006
  • The selection of multienzyme complex-producing bacteria under aerobic condition was conducted for improving the degradation of lignocellulosic substances. The criteria for selection were cellulase and xylanase enzyme production, the presence of cellulose-binding domains and/or xylan-binding domains in enzymes to bind to insoluble substances, the adhesion of bacterial cells to insoluble substances, and the production of multiple cellulases and xylanases in a form of a high molecular weight complex. Among the six Bacillus strains, isolated from various sources and deposited in our laboratory, Paenibacillus curdlanolyticus B-6 strain was the best producer of cellulase and xylanase enzymes, which have both cellulose-binding factors (CBFs) and xylan-binding factors (XBFs). Moreover, multiple carboxymethyl cellulases (CMCases) and xylanases were produced by the strain B-6. The zymograms analysis showed at least 9 types of xylanases and 6 types of CMCases associated in a protein band of xylanase and cellulase with high molecular weight. These cells also enabled to adhere to both avicel and insoluble xylan, which were analyzed by scanning electron microscopy. The results indicated that the strain B-6 produced the multienzyme complex, which may be cellulosome or xylanosome. Thus, P. curdlanolyticus B-6 was selected to study the role and interaction between the enzymes and their substrates and the cooperation of multiple enzymes to enhance the hydrolysis due to the complex structure for efficient cellulases and xylanases degradation of insoluble polysaccharides.

Degradation of Lignocelluloses in Rice Straw by BMC-9, a Composite Microbial System

  • Zhao, Hongyan;Yu, Hairu;Yuan, Xufeng;Piao, Renzhe;Li, Hulin;Wang, Xiaofen;Cui, Zongjun
    • Journal of Microbiology and Biotechnology
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    • 제24권5호
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    • pp.585-591
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    • 2014
  • To evaluate the potential utility of pretreatment of raw biomass with a complex microbial system, we investigated the degradation of rice straw by BMC-9, a lignocellulose decomposition strain obtained from a biogas slurry compost environment. The degradation characteristics and corresponding changes in the bacterial community were assessed. The results showed that rapid degradation occurred from day 0 to day 9, with a peak total biomass bacterium concentration of $3.3{\times}10^8$ copies/ml on day 1. The pH of the fermentation broth declined initially and then increased, and the mass of rice straw decreased steadily. The highest concentrations of volatile fatty acid contents (0.291 mg/l lactic acid, 0.31 mg/l formic acid, 1.93 mg/l acetic acid, and 0.73 mg/l propionic acid) as well as the highest xylanse activity (1.79 U/ml) and carboxymethyl cellulase activity (0.37 U/ml) occurred on day 9. The greatest diversity among the microbial community also occurred on day 9, with the presence of bacteria belonging to Clostridium sp., Bacillus sp., and Geobacillus sp. Together, our results indicate that BMC-9 has a strong ability to rapidly degrade the lignocelluloses of rice straw under relatively inexpensive conditions, and the optimum fermentation time is 9 days.

고정화 활성슬러지를 이용한 시안 분해 (Degradation of Cyanide by Activated Sludge Immobilized with Polyethylene Glycol)

  • 정경훈;최형일;김정애;문옥란;김명희
    • 한국환경과학회지
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    • 제17권12호
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    • pp.1343-1351
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    • 2008
  • The activated sludge obtained from wastewater coke oven plant was immobilized by entrapment with polyethylene glycol (PEG). The effects of several factors on the biodegradation of $CN^-$ from. synthetic wastewater were investigated using batch and continuous reactors. The degradation rate of $CN^-$ increased with increasing of the immobilized bead volume in the reactor. Approximately 7.65mg/L of $NH_4-N$ was produced upon the degradation of 35mg/L of $CN^-$. When high concentrations of the toxic cyanide complex were used in the testing of cyanide degradation, the free activated sludge could be inhibited more than that of the immobilized activated sludge. When the phenol concentration was higher than 400mg/L in the synthetic wastewater, approximately 98.4% of $CN^-$ was removed within 42 hours by the immobilized activated sludge. However, the cyanide was not completely degraded by the tree activated sludge. This indicates that high phenol concentrations can act as a toxic factor for the free activated sludge. A $CN^-$ concentration of less than 1mg/L was achieved by the immobilized sludge at the loading rate of 0.025kg $CN^-/m^3-d$. Moreover, it was found that the HRT should be kept for 48 hours in order to obtain stable treatment conditions.

Recent Advances in Titania-based Composites for Photocatalytic Degradation of Indoor Volatile Organic Compounds

  • Raza, Nadeem;Kim, Ki-Hyun;Agbe, Henry;Kailasa, Suresh Kumar;Szulejko, Jan E.;Brown, Richard J.C.
    • Asian Journal of Atmospheric Environment
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    • 제11권4호
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    • pp.217-234
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    • 2017
  • Indoor air pollutants can cause severe health problems, specifically in terms of toxicological impacts on human. Every day, a complex mixture of many air pollutants is emitted from various sources and subject to atmospheric processes that can create varied classes of pollutants such as carboxylic acids, aldehydes, ketones, peroxyacetyl nitrate, and hydrocarbons. To adhere to indoor air quality standards, a number of techniques such as photocatalytic oxidation of various volatile organic compounds (VOCs) have been employed. Among these techniques, titania ($TiO_2$) based photocatalytic reactions have proven to be the best benchmark standard approach in the field of environmental applications. Over the last 45 years, $TiO_2$-based photocatalytic reactions have been explored for the degradation of various pollutants. This review discusses the indoor air quality profile, types of indoor pollutants, available indoor air cleaning approaches, and performance of $TiO_2$-based catalysts. Finally, we have presented the perspectives on the progress of $TiO_2$ induced photocatalysis for the purification of indoor air.