• Tribology and Lubricants
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• v.36 no.6
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• pp.385-390
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• 2020

It rains heavily, such as long rain and typhoons, during a typical rainy season in Korea. In this season, several fuel contamination accidents by water and vehicular problems caused by water contaminated fuel occur. Many research groups have studied the effects of water contaminated fuel on vehicles and environment. However the characteristics of water contaminated fuel have not been studied. In this study, we prepared diesel samples with a constant ratio of water (0~30 volume %) using an emulsifier. Then, we analyzed these diesel samples for their representative fuel properties. In the analytical results, diesel with 30% water showed an increase in fuel properties such as density (823→883 kg/㎥), kinematic viscosity (2.601→6.345 ㎟/s), flash point (47→56℃), pour point (-22→2℃), CFPP (cold filter plugging point) (-17→20℃) and copper corrosion number (1a→2a). The low temperature characteristics, such as low pour point and CFPP, blocks the fuel filter in the cold season. In addition, water contaminated diesel decreases lubricity (190→410 ㎛) under high frequency reciprocating rig (HFRR) and derived cetane number (54.81→34.25). The low lubricity of fuel causes vehicle problem such as pump and injector damage owing to severe friction. In addition, the low cetane diesel fuel increases exhaust gases such as NOx and particulate matters (PM) owing to incomplete combustion. This study can be used to identify the problems caused by water contamination to vehicle and fuel facilities.

• Nuclear Engineering and Technology
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• v.54 no.6
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• pp.2077-2083
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• 2022

In the unlikely event of core disruptive accident in sodium cooled fast reactors, the reactor containment building would be bottled up with sodium and fission product aerosols. The behavior of these aerosols is crucial to estimate the in-containment source term as a part of nuclear reactor safety analysis. In this work, the evolution of sodium aerosol characteristics (mass concentration and size) is simulated using HAARM-S code. The code is based on the method of moments to solve the integro-differential equation. The code is updated to FORTRAN-77 and run in Microsoft FORTRAN PowerStation 4.0 (on Desktop). The sodium aerosol characteristics simulated by HAARM-S code are compared with the measured values at Aerosol Test Facility. The maximum deviation between measured and simulated mass concentrations is 30% at initial period (up to 60 min) and around 50% in the later period. In addition, the influence of humidity on aerosol size growth for two different aerosol mass concentrations is studied. The measured and simulated growth factors of aerosol size (ratio of saturated size to initial size) are found to be matched at reasonable extent. Since sodium is highly reactive with atmospheric constituents, the aerosol growth factor depends on the hygroscopic growth, chemical transformation and density variations besides coagulation. Further, there is a scope for the improvement of the code to estimate the aerosol dynamics in confined environment.

• Journal of The Korean Society of Agricultural Engineers
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• v.64 no.5
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• pp.9-16
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• 2022

Syngas, also known as synthesis gas, synthetic gas, or producer gas, is a combustible gas mixture generated when organic material (biomass) is heated in a gasifier with a limited airflow at a high temperature and elevated pressure. The present research was aimed at modifying the existing LPG engine generator for fully operated syngas. During this study, the designed gasifier-powered woodchip biomass was used for syngas production to generate power. A 6.0 kW LPG engine generator was modified and tested for operation on syngas. In the experiments, syngas and LPG fuels were tested as test fuels. For syngas production, 3 kg of dry woodchips were fed and burnt into the designed downdraft gasifier. The gasifier was connected to a blower coupled with a slider to help the air supply and control the ignition. The convection cooling system was connected to the syngas flow pipe for cooling the hot produce gas and filtering the impurities. For engine modification, a customized T-shaped flexible air/fuel mixture control device was designed for adjusting the correct stoichiometric air-fuel ratio ranging between 1:1.1 and 1.3 to match the combustion needs of the engine. The composition of produced syngas was analyzed using a gas analyzer and its composition was; 13~15 %, 10.2~13 %, 4.1~4.5 %, and 11.9~14.6 % for CO, H₂, CH₄, and CO₂ respectively with a heating value range of 4.12~5.01 MJ/Nm³. The maximum peak power output generated from syngas and LPG was recorded using a clamp-on power meter and found to be 3,689 watts and 5,001 watts, respectively. The results found from the experiment show that the LPG engine generator operated on syngas can be adopted with a de-ration rate of 73.78 % compared to its regular operating fuel.

• Safety and Health at Work
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• v.14 no.2
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• pp.215-221
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• 2023

Background: There is little information about the airborne hazardous agents released during the heat treatment when manufacturing a welding material. This study aimed to evaluate the airborne hazardous agents generated at welding material manufacturing sites through area sampling. Methods: concentration of airborne particles was measured using a scanning mobility particle sizer and optical particle sizer. Total suspended particles (TSP) and respirable dust samples were collected on polyvinyl chloride filters and weighed to measure the mass concentrations. Volatile organic compounds and heavy metals were analyzed using a gas chromatography mass spectrometer and inductively coupled plasma mass spectrometer, respectively. Results: The average mass concentration of TSP was 683.1±677.4 ㎍/m³, with respirable dust accounting for 38.6% of the TSP. The average concentration of the airborne particles less than 10 ㎛ in diameter was 11.2-22.8×10⁴ particles/cm³, and the average number of the particles with a diameter of 10-100 nm was approximately 78-86% of the total measured particles (<10 ㎛). In the case of volatile organic compounds, the heat treatment process concentration was significantly higher (p < 0.05) during combustion than during cooling. The airborne heavy metal concentrations differed depending on the materials used for heat treatment. The content of heavy metals in the airborne particles was approximately 32.6%. Conclusions: Nanoparticle exposure increased as the number of particles in the air around the heat treatment process increases, and the ratio of heavy metals in dust generated after the heat treatment process is high, which may adversely affect workers' health.

• Journal of the Korean Society of Safety
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• v.10 no.3
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• pp.120-129
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• 1995

Since the rate and completeness of combustion in direct injection engines were controlled by the characteristics of gas flow fields and sprays, an understanding of those was essential to the design of the direct injection engines. In this study the numerical simulations of swirl effects on the characteristics of gas flow fields and sprays were performed using the spray model that could predict the interactions between gas fields and spray droplets. The governing equations were discretized by the finite volume method and the modified k- e model which included the compressibility effects due to the compression/expansion of piston was used. The results of numerical calculation of the spray characteristics in the quiescent environment were compared with the experimental data. There were good agreements between the results of calculation and the experimental data, except in the early stages of spray. In the motoring condition, the results showed that a substantial air entrainment into the spray volume was emerged and hence the squish motion was relatively unimportant during fuel injection periods. As the swirl ratio increased, the evaporation rate was increased due to the wide dispersion of the spray droplets and the strong interaction between spray droplets and gas fields.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.39 no.9
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• pp.909-916
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• 2015

In this study, to investigate the effect of spray behavior characteristics, we induce the mixing ratio of emulsified fuel using impinging spray. We formulate the emulsified fuel by mixing diesel and hydrogen peroxide($H_2O_2$). We set the temperature of the heating plate to $150^{\circ}C$, $200^{\circ}C$, and $250^{\circ}C$, and set the injection pressures to 400, 600, 800, and 1000bar. The surfactants for the emulsified fuel mixture, which were mixed span80 and tween80 was mixed as 9:1, were fixed to 3% of the total volume of the emulsified fuel. We set the mixing ratio of $H_2O_2$ in the emulsified fuel as emulsified fuel(EF)0, EF2, EF12, and EF22. Further, we visualize the evaporation impinging spray using the Schlieren method. Based on the results of this study, we found that a higher temperature and injection pressure of the heating plate impingement led to the active diffusion of the fuel vapor, which promoted emulsified fuel evaporation. When the emulsified fuel is utilized in an actual engine, because of the temperature-drop effect of the combustion chamber, which is due to the evaporation of $H_2O_2$ in fuel and faster mixture formation is expected to decrease the engine emissions.

• Journal of Environmental Health Sciences
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• v.36 no.2
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• pp.108-117
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• 2010

In this study, ambient particulate matter ($PM_{2.5}$ and $PM_{10}$) levels were measured and their chemical and physical properties were characterized. Two sites in Gwangju were sampled once a month from December 2008 to November 2009. The annual mean concentrations of $PM_{2.5}$ and $PM_{10}$ were $26.9\;{\mu}g/m^3$ and $46.3\;{\mu}g/m^3$, respectively, in Nongseongdong and $26.1\;{\mu}g/m^3$ and $44.8\;{\mu}g/m^3$, respectively, in Duam-dong. $PM_{2.5}$ levels were 1.8 times higher than the USA Environmental Protection Agency (EPA) national ambient air quality standard for $PM_{2.5}$ ($15\;{\mu}g/m^3$). The average $PM_{2.5}/PM_{10}$ ratio of 0.58 suggested that $PM_{2.5}$ is a significant component of the ambient particle pollution. The order of concentration of metallic elements in $PM_{2.5}$ and $PM_{10}$ was Si > Al > Fe > Zn > Pb > Cu > Mn. Cd was not detected. The earth crustal enrichment factors for Cr, Cu, Pb and Zn in $PM_{2.5}$ were higher than those in $PM_{10}$. When the earth crustal enrichment factors for Cr, Cu, Pb and Zn were higher than 10, this suggested influence from anthropogenic sources. The soil contribution ratios for $PM_{2.5}$ and $PM_{10}$ were 11.3% and 16.4%, respectively, and were higher in the fall and winter. Anions (${SO_4}^{-2}$, ${NO_3}^-$, and $Cl^-$) comprise 28.7% of $PM_{2.5}$ and 21.4% of $PM_{10}$. The correlation coefficient of Zn-Fe, Mn-Cu, Fe-Cu and Fe-Mn in $PM_{2.5}$ was high in the sampling sites, and metallic elements were primarily from anthropogenic sources such as fuel combustion and vehicle emissions.

• Journal of Soil and Groundwater Environment
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• v.17 no.2
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• pp.15-21
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• 2012

MTBE (Methyl tertiary-butyl ether) has been commonly used as an octane enhancer to replace tetraethyl lead in gasoline, because MTBE increases the efficiency of combustion and decreases the emission of carbon monoxide. However, MTBE has been found in groundwater from the fuel spills and leaks in the UST (Underground Storage Tank). Fenton's oxidation, an advanced oxidation catalyzed with ferrous iron, is successful in removing MTBE in groundwater. However, Fenton's oxidation requires the continuous addition of dissolved $Fe^{2+}$. Zero-valent iron is available as a source of catalytic ferrous iron of MFO (Modified Fenton's Oxidation) and has been studied for use in PRBs (Permeable Reactive Barriers) as a reactive material. Therefore, this study investigated the condition of optimization in MFO-PRBs using waste zero-valent iron (ZVI) with the waste steel scrap to treat MTBE contaminated groundwater. Batch tests were examined to find optimal molar ratio of MTBE : $H_2O_2$ on extent to degradation of MTBE in groundwater at pH 7 with 10% waste ZVI. As the results, the ratio of optimization of MTBE to hydrogen peroxide for MFO was determined to be 1:300[mM]. The column experiment was conducted to know applicability of MFO-PRBs for MTBE remediation in groundwater. As the results of column test, MTBE was removed 87% of the initial concentration during 120days of operational period. Interestingly, MTBE was degraded not only within waste ZVI column but also within sand column. It means the aquifer may affect continuously the MTBE contaminated groundwater after throughout the waste ZVI barrier. The residual products showed acetone, TBF (Tert-butyl formate) and TBA (Tert-butyl acetate) during this test. The results of the present study showed that the recycled materials can be effectively used for not only a source of catalytic ferrous iron but also a reactive material of the MFO-PRBs to remove MTBE in groundwater.

• Journal of the Korean Institute of Gas
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• v.14 no.3
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• pp.41-45
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• 2010

The physical properties of DME(Dimethyl Ether) are very similar to LPG and well-mixed. As cetane number of DME is similar to diesel fuel that can replace diesel fuel and alternative energy. DME is a clean energy source that can be manufactured from various raw materials such as natural gas, CBM(Coal Bed Methane) and biomass. DME has no carbon-carbon bond in its molecular structure and its combustion essentially generates no soot as well as no SOx. The development of DME process in KOGAS have 4 section. First, syngas section can be manufactured various syngas ratio. This completes the tri-reforming process for the synthesis gas ratio of approximately 4.0 to 1.0 range can be adjusted. Second, $CO_2$ is removed from the $CO_2$ removal section of about 92~99%, so the maximum concentration of $CO_2$ entering the DME synthesis reactor should not exceed 8%. Third, in the DME synthesis section, if the temperature of DME reactor increases, the activity of DME catalyst increased. but for the long-term activity is desirable to maintain the proper temperature. Finally, the purity of DME in the DME purification section is over 99.6%.

• Korean Journal of Environmental Agriculture
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• v.19 no.5
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• pp.401-418
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• 2000

1. Production of the artificial zeolite from coal ash Coal fly ash is mainly composed of several oxides including $SiO_2$ and $Al_2O_3$ derived from inorganic compounds remained after burning. As minor components, $Fe_2O_3$ and oxides of Mg, Ca, P, Ti (trace) are also contained in the ash. These components are presented as glass form resulting from fusion in the process of the combustion of coal. In other word, coal ash may refer to a kind of aluminosilicate glass that is known to easily change to zeolite-like materials by hydrothermal reaction. Lots of hot seawater is disposing near thermal power plants after cooling turbine generator periodically. Using seawater in the hydrothermal reaction caused to produce low price artificial zeolite by reduction of sodium hydroxide consumption, heating energy and water cost. As coal ash were reacted hydrothermally, peaks of quartz and mullite in the ash were weakened and disappeared, and new Na-Pl peaks were appeared strengthily. Si-O-Si bonding of the bituminous coal ash was changed to Si-O-Al (and $Fe^{3+}$) bonding by the reaction. Therefore the produced Na-Pl type zeolite had high CEC of 276.7 $cmol^+{\cdot}kg^{-1}$ and well developed molecular sieve structure with low concentration of heavy metals. 2. Utilization of the artificial zeolite in agro-environment The artificial zeolite(1g) could remove 123.5 mg of zinc, 164.7 mg copper, 184.4 mg cadmium and 350.6 mg lead in the synthetic wastewater. The removability is higher 2.8 times in zinc, 3.3 times in copper, 4.7 times in cadmium and 4.8 times in lead than natural zeolite and charcoal powder. When the heavy metals were treated at the ratio of 150 $kg{\cdot}ha^{-1}$ to the rice plant, various growth inhibition were observed; brownish discoloration and death of leaf sheath, growth inhibition in culm length, number of panicles and grains, grain ripening and rice yield. But these growth inhibition was greatly alleviated by the application of artificial zeolite, therefore, rice yield increased $1.1{\sim}3.2$ times according to the metal kind. In addition, the concentration of heavy metals in the brown rice also lowered by $27{\sim}75%$. Artificial Granular Zeolites (AGZ) was developed for the purification of wastewater. Canon exchange capacity was 126.8 $cmol^+{\cdot}kg^{-1}$. AGZ had Na-Pl peaks mainly with some minor $C_3S$ peaks in X-ray diffractogram. In addition, AGZs had various pore structure that may be adhere the suspended solid and offer microbiological niche to decompose organic pollutants. AGZ could remove ammonium, orthophosphate and heavy metals simultaneously. Mixing ratio of artificial zeolite in AGZs was related positively with removal efficiency of $NH_4\;^+$ and negatively with that of $PO_4\;^{3-}$. Root growth of rice seedling was inhibited severely in the mine wastewater because of strong acidity and high concentration of heavy metals. As AGZ(1 kg) stayed in the wastewater(100L) for 4days, water quality turned into safely for agricultural usage and rice seedlings grew normally.