• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.184-184
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• 2009

Lead-free Piezoelectric $[Li_{0.04}(Na_{0.44}K_{0.56})](Nb_{0.88}Ta_{0.1}Sb_{0.02})$ (abbreviated as NKNLTS) has been synthsized by conventional mixed oxide method traditional ceramics process without cold-isostatic pressing. Effect of $Bi_2O_3$ addition on NKNLTS ceramics was investigated. Piezoelectric properties of the ceramic were varied with the amount of $Bi_2O_3$ addition and showed the maximum Kp value at 0.4wt% $Bi_2O_3$ addition. The results show that the optimum poling condition for NKNLTS ceramics of 3.5kV/mm, poling temperature of $120^{\circ}C$ and poling time of 30min. At the sintering temperature of $1100^{\circ}C$ and the calcination temperature $800^{\circ}C$, the optimal values of density=$4.7g/cm^2$, Kp=0.44, $\varepsilon_r$=1309 were obtained. Consequently, lead free piezoelectric ceramics with the excellent piezoelectric could be fabricated using a conventional mixed oxide process and the optimal manuacturing condition of those was obtained.

• Journal of the Korean Ceramic Society
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• v.41 no.9
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• pp.715-721
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• 2004

Hydroxyapatite (HAp)/Gelatin (GEL) homogeneous composites of four different composition ratio were prepared by the co-precipitation process with synthetic HAp and GEL as a binder, HAP/GEL composites were molding by cold isostatic pressing and were sintering by various condition in air. Crystallinity and structure of sintered HAp/GEL composites were investigated by XRD and FTIR. Also, the compressive strength and the fracture surface of sintered specimens were measured by UTM and SEM. HAp/GEL composites showed a phase transformation to partially ${\alpha}$, ${\beta}$-tricalcium phosphate at the sintered condition of 1200$^{\circ}C$ for 3 h. The porosity of sintered body was in the range of 1.2-30.2％. The compressive strength of the sintered specimens was in the range of 16.2-60.1㎫, and its strength of sintered HAp/GEL comosites was higher than expected when the porosity was considered.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.25 no.3
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• pp.198-203
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• 2012

In this study, $[Li_{0.04}(Na_{0.5}K_{0.5})_{0.96}](Nb_{0.86}Ta_{0.10}Sb_{0.04})O_3+xSrO$ (x=0, 0.0025, 0.005, 0.0075) ceramics were synthesized by the conventional mixed oxide method. The X-ray diffraction patterns demonstrated that ceramics possessed single perovskite structure. The SEM images indicate that microstructure can be obviously affected by a small amount of added SrO. The phase transition temperature tetragonal-cubic($T_c$) and orthorhombic-tetragonal($T_{o-t}$) shifts downward and upward with the increase of Sr addition, respectively. The excellent piezoelectric properties of $d_{33}=170[pC/N]$, $k_p=0.37$, $Q_m=64.12$, $T_{o-t}=153^{\circ}C$ and $T_c=370^{\circ}C$ were obtained from the 0.25 mol% Sr added ceramics sintered at $1,120^{\circ}C$ for 1 h.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.13 no.2
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• pp.83-87
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• 2003

$(Nd/Y)_{1.8}Ba_{}2.4Cu_{3.4}O_{7-x}$high $T_c$ superconductor was directionally grown by floating Bone melt growth process with a large temperature gradient in air. Cylindrical green rods of (Nd/Y)1.8 oxides were fabricated by cold isostatic pressing (CIP) method using rubber mold. Microstructures were observed by SEM and TEM and superconducting properties were measured by a SQUID magnetometer. Nonsuperconducting $(Nd/Y)_2BaCuO_5$ inclusions were uniformly distributed within the superconducting $(Nd/Y)Ba_2Cu_3O_x$ matrix. The directionally melt-textured (Nd/Y) 1.8 superconductor showed an onset Tc $\geq$ 90 K and a sharp superconducting transition.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.14 no.2
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• pp.68-72
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• 2004

Sm-doped YBCO high $T_c$ superconductor was directionally grown by zone melt growth process in air atmosphere. Cylindrical green rods of $(Sm/Y)_{1.8}Ba_{2.4}Cu_{3.4}O_{7-x}$[(Sm/Y)1.8] oxides were fabricated by cold isostatic pressing (CIP) method using rubber mold. Based on the variation of melting temperature and growth rate, the microstructure and superconducting properties were systematically measured by using optical micrographs, TEM and SQUID magnetometer. In this study optimum melting temperature and growth rate were $1085^{\circ}C$ and 3.5 mm/hr respectively. Nonsuperconducting $(Sm/Y)_2BaCuO_5$ inclusions of (Sm/Y)1.8 superconductor were uniformly distributed within the superconducting (Sm/Y) $Ba_2Cu_3O^{7-x}$ matrix. The directionally melt-textured (Sm/Y)1.8 superconductor showed an onset $T_c$ $\geq$ 90K and sharp superconducting transition.

• Journal of the Korean Ceramic Society
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• v.40 no.6
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• pp.566-571
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• 2003

Hydroxyapatite (HAp)/Polyacrylic Acid(PAA) homogeneous composites of four different composition ratio were preparation by co-precipitation process with synthetic HAp and PAA as a binder. HAP/PAA composites were molding by cold isostatic pressing and were sintering by various condition in air. Crystallinity and structure of sintered HAp/PAA composites were investigated by XRD and FT-IR. Also, the compressive strength and the fracture surface of sintered specimens were measured by UTM and SEM. HAp/PAA composites were showed phase transformation of partially ${\alpha}$, ${\beta}$-tricalcium phosphate at sintering condition of 1200$^{\circ}C$ and 3 h. The pore size and porosity of sintered body were showed the range of 0.2∼3.0 $\mu\textrm{m}$ and 0.49∼13.43%, respectively. The compressive strength of sintered specimens were appeared the range of 36.6∼58.2 MPa. From these results, the sintered HAp/PAA comosites can be accounted for the microporous HAp having a good compressive strength due to homogeneous pore morphology.

• Journal of Powder Materials
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• v.20 no.3
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• pp.215-220
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• 2013

In the present work, 6061 Al-$B_4C$ sintered composites containing different $B_4C$ contents were fabricated and their characteristic were investigated as a function of sintering temperature. For this, composite powders and their compacts with $B_4C$ various contents from 0 to 40 wt.% were fabricated using a planetary ball milling equipment and cold isostatic pressing, respectively, and then they were sintered in the temperature ranges of 580 to $660^{\circ}C$. Above sintering temperature of $640^{\circ}C$, real density was decreased due to the occurrence of sweat phenomena. In addition, it was realized that sinterability of 6061Al-$B_4C$ composite material was lowered with increasing $B_4C$ content, resulting in the decrease in its real density and at the same time in the increment of porosity.

• Journal of the Korean Ceramic Society
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• v.56 no.1
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• pp.71-76
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• 2019

Monochromatic amber phosphor in glasses (PiGs) for automotive LED applications were fabricated with $YAG:Ce^{3+}$, $CaAlSiN_3:Eu^{2+}$ phosphors and Pb-free silicate glass. After synthesis and thickness-thinning process, PiGs were mounted on high-power blue LED to make monochromatic amber LEDs. PiGs were simple mixtures of 566 nm yellow YAG, 615 nm red $CaAlSiN_3:Eu^{2+}$ phosphor and transparent glass frit. The powders were uniaxially pressed and treated again through CIP (cold isostatic pressing) at 200 MPa for 20 min to increase packing density. After conventional thermal treatment at $550^{\circ}C$ for 30 min, PiGs were applied by using GPS (gas pressure sintering) to obtain a fully dense PiG plate. As the phosphor content increased, the density of the sintered body decreased and PiGs containing 30 wt% phosphor had full sintered density. Changes in photoluminescence spectra and color coordination were investigated by varying the ratio of $YAG/CaAlSiN_3$ and the thickness of the plates. Considering the optical spectrum and color coordinates, PiG plates with $240{\mu}m$ thickness showed a color purity of 98% and a wavelength of about 605 nm. Plates exhibit suitable optical characteristics as amber light-converting material for automotive LED applications.

• Nuclear Engineering and Technology
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• v.56 no.5
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• pp.1854-1862
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• 2024

This study aims to investigate the strain-dependent-deformation property of Gyeongju bentonite buffer material. A series of unconfined compressive tests were performed with cylindrical specimens prepared at varying dry densities (𝜌_d = 1.58 g/cm³ to 1.74 g/cm³) using cold isostatic pressing technique. It is found that as 𝜌_d increase, the unconfined compressive strength (q_u), failure strain, and elastic modulus (E) of Gyeongju compacted bentonite (GCB) increases. Normalized elastic modulus (E_sec/E_max) degradation curves of GCB specimens are fitted using Ramberg-Osgood model and the elastic threshold strain (𝜀_e,th) is determined through the fitted curves. The strain-dependency of E and Poisson's ratio (v) of GCB were observed. E and v were measured constant below 𝜀_e,th of 0.14 %. Then, E decreases while v increases after exceeding the strain threshold. The E_sec/E_max degradation curves of GCB in this study suggests wider linear range and higher linearity than those of sedimentary clay in previous study. On top of that, the influence of 𝜌_d is observed on E_sec/E_max degradation curves of GCB, showing a slight increase in 𝜀_e,th with increase in 𝜌_d. Furthermore, an empirical model of q_u with 𝜌_d and a correlation model between q_u and E are proposed for Gyeongju bentonite buffer materials.

• Applied Chemistry for Engineering
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• v.20 no.3
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• pp.317-321
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• 2009

In order to analyze the high temperature phase formation and the sinterability of super ionic conductor $K^+-{\beta}/{\beta}"-Al_2O_3$ which is commonly used as a solid oxide electrolyte, the pure $K^+-{\beta}/{\beta}"-Al_2O_3$ powder in the ternary system $K_2O-LiO_2-Al_2O_3$ was synthesized by solid state reaction and formed to tube and disk using slip casting method and cold isostatic pressing (CIP), respectively. The slip casting was conducted in an alumina mold with the slurry containing 40 wt% of solid contents and the CIP was carried out under 20 MPa. The samples were sintered at $1600^{\circ}C$, $1700^{\circ}C$ and $1750^{\circ}C$, respectively, and their phase formation and the sintering density were investigated according to the forming method. The samples produced by CIP showed far higher ${\beta}"-Al_2O_3$ fraction as compared with those by slip casting. On the other hand, the samples by slip casting showed slightly higher sintering density. The relative density reached to about 83% at $1750^{\circ}C$ and for 1 h, independent of the forming method. In the case of 90 min socking time, the density was decreased owing to the exaggerated grain growth and the pores by $K_2O$ evaporation.