• Title/Summary/Keyword: coefficients of determination

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Simultaneous Determination of the Water Soluble Vitamins in Multi-Nutrient Tablets by Reversed-Phase High-Performance Liquid Chromatography

  • Kim, Hyung-Soo;Jang, Duck-Kyu;Woo, Dong-Kyun;Woo, Kang-Lyung
    • Preventive Nutrition and Food Science
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    • v.7 no.1
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    • pp.12-17
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    • 2002
  • Simultaneous determination of nine water-soluble vitamins contained in multi-nutrient tablets was carried out by reversed phase high-performance liquid chromatography (RP-HPLC) equipped with analytical $C_{18}$ column and UV (270 nm) detector. Those standard vitamins were successfully separated within 23 minutes by gradient elution with solvent A (0.5 M potassium phosphate monobasic) and solvent B (0.25 M potassium phosphate monobasic-methanol, 1:1). Calibration curves showed good linealities with correlation coefficients (> 0.92) in tested ranged respectively. The detection limits were considered to be 2.1 ng for ascorbic acids 60 ng for Vit B$_{6}$ 3 ng for p-aminobenzoic acid, 9 ng for niacinamide, 9 ng for thiamin, 5.0 ng for folic acid and 1.5 ng for riboflavin at 0.05 a.u.f.s. Solid phase extraction through Sep-Pak (C$_{18}$ ) cartridge was successfully applied for purification of water soluble vitamins in commercial multi-nutrient tablets.ts.

The Linear Density Predictive Models on the On-Ramp Junction in the Urban Freeway (도시고속도로의 진입연결로 접속부내 선형의 밀도예측모형 구축에 관한 연구)

  • Kim, Tae Gon;Shin, Kwang Sik;Kim, Seung Gil;Kim, Jeong Seo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.1D
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    • pp.59-66
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    • 2006
  • This study was to construct the linear density predictive models on the on-ramp junctions in urban freeway. From the analyses of the real-time traffic characteristic data, and the construction and verification of the linear density predictive models, the models showed a considerable explanatory power with the determination coefficients ($R^2$) of over 0.7 between the density and speed data. Also, they showed a considerably high correlativeness with the correlation coefficients (r) of over 0.8 between the calculated density data and the expected ones estimated by the models.

Simultaneous Determination of B Group Vitamins in Supplemented Food Products by High Performance Liquid Chromatography-Diode Array Detection

  • Suh, Joon-Hyuk;Yang, Dong-Hyug;Lee, Byung-Kyu;Eom, Han-Young;Kim, Un-Yong;Kim, Jung-Hyun;Lee, Hye-Yeon;Han, Sang-Beom
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2648-2656
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    • 2011
  • A simple HPLC-DAD method was developed and validated to determine B group vitamin content (thiamine, riboflavin, nicotinamide, pantothenic acid, pyridoxine and folic acid) in supplemented food samples, i.e., infant formula, cereal, low-calorie food, a multi-vitamin pill and a vitamin drink. In this study, the most significant advantages were simultaneous determination of the six B group vitamins in various food matrices and a small number of sample treatment steps that required only an organic solvent, acetonitrile. Moreover, this method prevents reduction of column durability, because the mobile phase does not contain ion-pairing reagents. Analytes were separated on a Develosil RPAQUEOUS $C_{30}$ (4.6 mm ${\times}$ 250 mm, 5 ${\mu}M$ particle size) column with a gradient elution of acetonitrile and 20 mM phosphate buffer (pH 3.0) at a flow rate between 0.8 and 1.0 mL/min. Detection was performed at 275 nm, except for that of pantothenic acid (205 nm). The calibration curves for all six vitamins showed good linearity with correlation coefficients ($r^2$) higher than 0.995. The developed method was validated with respect to linearity, intra- and inter-day accuracy and precision, limit of quantification (LOQ), recovery and stability. The method showed good precision and accuracy, with intra- and inter-assay coefficients of variation less than 15% at all concentrations. The recovery was carried out according to the standard addition procedure, with yields ranging from 89.8 to 104.4%. This method was successfully applied to the determination of vitamin B groups in supplemented food products.

Use of Beam Transmissometer as an Indirect Measure of Suspended Sediment Concentration in the Estuarine Environment: Application and Problems (강하구에서의 부유물질농도 결정을 위한 광전도측정기의 이용 및 문제점)

  • KIM Seok-Yun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.27 no.6
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    • pp.771-781
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    • 1994
  • Monthly measurements made at 15 stations along the axis of the upper Neuse River estuary show a highly variable degree of correlation between concentration of suspended particulate material (SPM) and attenuation coefficient (c) of light as measured by transmissometer. Coefficients of determination along transect lines ranged from $0.12{\sim}0.93$ and calibration slopes ranged from $0.50{\sim}5.63$. When examined on a station-by-station basis, coefficients of determination ranged from $0.21{\sim}0.96$ and calibration slopes ranged from $1.04{\sim}4.94$. Surface calibrations made at individual stations over the full 13-month period were the most consistent of all observations and were considerably better than calibrations made using all of the stations on a given day. Organic content, which can dominate the suspended sediment load during some months, does not appear to explain the variations in reliability of the calibrations. However, an abundance of large aggregates with time-varying size and shape distributions may be partly responsible for variations in optical properties of the sediments, and thus may confound the relationship between SPM and c in the Neuse River estuary Time-varying calibrations to account for non-negligible changes in optical properties may not suffice in complex estuarine environments where the in situ particle dynamics are poorly understood. However, the best use of Beam Transmissometer will continue to be for applications such as detecting water-column events or for use in situations where wide error bars in establishing SPM concentrations are acceptable.

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A Study on Growth Pattern in a New Synthetic Korean Native Commercial Chicken by Sex and Strains (신품종 토종닭의 계통과 성별에 따른 성장 특성에 관한 연구)

  • Kigon, Kim;Eun Sik, Choi;See Hwan, Sohn
    • Korean Journal of Poultry Science
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    • v.49 no.4
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    • pp.229-237
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    • 2022
  • This study investigated the growth characteristics of four strains of newly developed synthetic Korean native commercial chickens (KNCs). We investigated a suitable growth curve model in KNCs and estimated the number of days to reach a 2 kg market weight. Body weight was measured at 2-week intervals from birth to 12 weeks of age. The growth curves were estimated using von Berteralanffy, Gompertz, and logistic functions. The results showed that males were significantly heavier than females at all ages, but there were no significant differences in body weight between strains, except at birth and 2 and 6 weeks of age. The coefficients of determination and adjusted determination of growth function had high goodness-of-fit (97.4~99.7). Of the growth curve parameters, the mature weight and growth ratio were higher in males than in females, but the maturity rate was similar in males and females. The inflection point occurred at approximately 7 weeks of age for females and 8 to 9 weeks of age for males. The weights estimated from the growth curve functions almost agreed with the actual weights, except for male weights estimated using the von Bertalanffy function. The coefficients of determination of the regression equations for weight to age were 0.9583 to 0.9746. The 8- and 10-week-old body weights estimated using the regression equation, and the 12-week-old weight estimated using the logistic function were most similar to the actual weight. Using these models, the estimated age of KNCs to reach 2 kg was 62.0~64.6 days for males and 74.9~78.6 days for females.

Accuracy of Precision Ground Coordinates Determination Using Inverse RPC in KOMPSAT Satellite Data (다목적실용위성(KOMPSAT)의 Inverse RPC 해석을 통한 정밀지상좌표 결정 정확도)

  • Seo, DooChun;Jung, JaeHun;Hong, KiByung
    • Aerospace Engineering and Technology
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    • v.13 no.2
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    • pp.99-107
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    • 2014
  • There are two types of Physical Model and RFM (Rational Function Model) is to determinate ground coordinates using KOMPSAT-2 and KOMPSAT-3 satellite data. Generally, RPCs(Rational Polynomial Coefficients) based on RFM is provided for users. This RPCs is to compute the ground coordinates to the image coordinates. If users produce ortho-image with provided RPCs is useful, directly compute the ground coordinates corresponding to image coordinates and check location accuracy etc. are difficult. In this study, a basic algorithm of inverse RPCs that calculates the image coordinates to ground coordinates, compute based on provided RPCs and evaluation of determinated ground coordinates using developed inverse RPCs were proposed.

Non-Destructive Prediction of Head Rice Ratios using NIR Spectra of Hulled Rice (정조 상태에서 백미에 대한 완전미율의 비파괴 예측)

  • Kwon, Young-Rip;Cho, Seung-Hyun;Lee, Jae-Heung;Seo, Kyoung-Won;Choi, Dong-Chil
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.53 no.3
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    • pp.244-250
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    • 2008
  • The purpose of this study was to measure fundamental data required for the prediction of milling ratios, and to develop regression models to predict the head rice ratio of milled rice using NIR spectra of hulled rice. A total of 81 rice samples used in this study were collected from Jeongeup, Jeonbuk province in 2006. NIR spectra were measured using one mode of measurement, reflection. The reflectance spectra were measured in the wavelength region of 400-2500 nm with an NIR spectrophotometer "NIRSystems 6500" (Foss, Silverspring, USA). Calibration equations were developed by the modified partial least squares (MPLS), partial least squares (PLS), and principal components regression (PCR). Math treatments were 1-4-4-1, 1-10-10-1, 2-4-4-1, and 2-10-10-1. The software used was WinISI (Infrasoft International, State College, USA). Automatic head rice production and quality checking system used was "SY2000-AHRPQCS" (Ssangyong, Korea). The calibration was made with the first derivative and the spectrum designated was in 8 nm interval. The determination coefficients of head rice ratios were 0.8353, 0.8416 and 0.5277 for the MPLS, PLS and PCR, respectively. Those obtained with 20 nm interval were 0.8144, 0.8354 and 0.6908 for the MPLS, PLS and PCR, respectively. The calibration was made with second derivative that spectrum designated was 8 nm in interval. The determination coefficients of head rice ratios were 0.7994, 0.8017 and 0.4473 for the MPLS, PLS and PCR, respectively. Those with 20 nm interval were 0.8004, 0.8493 and 0.6609 for the MPLS, PLS and PCR, respectively. These results indicate that the accuracy of determination coefficient for MPLS and PLS is higher than that of PCR.

A Study on the Safe Blasting Design by Statistical Analysis of Ground Vibration for Vibration Controlled Blasting in Urban Area (II) (도심지 미진동 제어발파에서 진동분석을 통한 안전 발파설계에 관한 연구(II) - 진동측정 자료의 통계적 분석을 위주로 -)

  • 김영환;안명석;박종남;강대우;이창우
    • Explosives and Blasting
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    • v.18 no.2
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    • pp.7-13
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    • 2000
  • Abstract The characteristics of bed rock in the study area was classified by means of the crack coefficient estimated from the seismic velocities of in-situ and intact rocks. Various statistical methods were investigated in order to minimize the possible errors in estimating the predictive equation of blasting vibration and to enhance the determination coefficient $R^2$, for more reliable estimation. The determination coefficient showed the highest in the analysis for those groups using weighting function with the number of samples. The analysis for the weighting function employed with standard coefficient and variance also enhanced the determination coefficients significantly compared to the others, but the reliability was slightly lower than results obtained former method. Therefore the most reliable predictive equation of blasting vibration was found to be obtained from a regression analysis of the mean vibration level using the weighting of same distance groups within 15m with the same explosive charge weight per delay. The coefficients, K and n 317.4 and -1.66, respectively, when using the square root scaling, and 209.9 and -1.66, respectively, when using the cube root scaling. The analysis also showed that the square root scaling may be used in the distance less than 31m form the blast source, and the cube root scaling in the distance more than 31m for safe design.

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Emission Characteristics and Coefficients of Air Pollutants in Iron and Steel Manufacturing Facilities (제철제강시설의 대기오염물질 배출특성 및 배출계수 산정)

  • Kim, Byoung-Ug;Hong, Young-Kyun;Lee, Yeong-Seob;Yang, Seung-Pyo;Hyun, Geun-Woo;Yi, Geon-Ho
    • Journal of Environmental Health Sciences
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    • v.47 no.3
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    • pp.259-266
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    • 2021
  • Objectives: This study was conducted to identify the emissions characteristics of total particulate matter (TPM), fine dust (PM10, PM2.5), and gaseous pollutants (SOx, NOx) in iron and steel manufacturing facilities in order to investigate emissions factors suitable for domestic conditions. Methods: Total particulate matter (TPM), fine dust (PM10, PM2.5), and gas phase materials were investigated at the outlet of electric arc furnace facilities using a cyclone sampling machine and a gas analyzer. Results: The concentrations of TPM ranged from 1.64 to 3.14 mg/Sm3 and the average was 2.47 mg/Sm3. Particulate matter 10 (PM10) averaged 1.49 mg/Sm3 with a range of 0.92 to 1.99 mg/Sm3, and the resulting ratio of PM10 to TPM was around 60 percent. PM2.5/PM10 ranged from 33.7 to 47.9% and averaged 41.6%. Sulfur oxides (SOx) were not detected, and nitrogen oxides (NOx) averaged 6.8 ppm in the range of 5.50 to 8.67 ppm. TPM emission coefficients per product output were in the range of 0.60 to 1.26 g/kg, 0.13 to 0.79 g/kg for PM10 and 0.12 to 0.36 g/kg for PM2.5, and showed many differences from the emissions coefficients previously announced. An emissions coefficient for NOx is not currently included in the domestic notices, but the results were calculated to be 0.42 g/kg per product output. Conclusions: Investigation and research on emissions coefficients that can reflect the characteristics of various facilities in Korea should be conducted continuously, and the determination and application of unique emissions coefficients that are more suitable for domestic conditions are needed.

Determination of Weight Coefficients of Multiple Objective Reservoir Operation Problem Considering Inflow Variation (유입량의 변동성을 고려한 저수지 연계 운영 모형의 가중치 선정)

  • Kim, Min-Gyu;Kim, Jae-Hee;Kim, Sheung-Kown
    • Journal of Korea Water Resources Association
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    • v.41 no.1
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    • pp.1-15
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    • 2008
  • The purpose of this study is to propose a procedure that will be able to find the most efficient sets of weight coefficients for the Geum-River basin in Korea. The result obtained from multi-objective optimization model is inherently sensitive to the weight coefficient on each objective. In multi-objective reservoir operation problems, the coefficient setting may be more complicated because of the natural variation of inflow. Therefore, for multi-objective reservoir operation problems, it may be important for modelers to provide reservoir operators with appropriate sets of weight coefficients considering the inflow variation. This study presents a procedure to find an appropriate set of weight coefficients under the situation that has inflow variation. The proposed procedure uses GA-CoMOM to provide a set of weight coefficient sets. A DEA-window analysis and a cross efficiency analysis are then performed in order to evaluate and rank the sets of weight coefficients for various inflow scenarios. This proposed procedure might be able to find the most efficient sets of weight coefficients for the Geum-River basin in Korea.