• 한국세라믹학회지
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• 제47권5호
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• pp.457-460
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• 2010

$SmCoO_3$ system was investigated for their application to themoelectric materials. All specimens showed p-type semiconducting behavior and their electrical conductivity ($\sigma$), Seebeck coefficient (S) and power factor were measured at high temperature. And the effect of dopant ions on their thermoelectrical properties were also investigated. $Fe^{3+}$ ion doped into $Co^{3+}$ site enhanced the Seebeck coefficient and decreased the electrical conductivity simultaneously. The maximum Seebeck coefficient value for 60% doping case reached to 780 ${\mu}V$/K at $240^{\circ}C$. However $Fe^{3+}$ doped system cause an negative effect on power factor value. In case of the pure phase, the maximum Seebeck coefficient value reached to 290 ${\mu}V$/K at $240^{\circ}C$ and the maximum electrical conductivity was obtained 748 1/(ohm$\times$cm) at $960^{\circ}C$. As a result, the maximum power factor was obtained $1.49\times10^{-4}$ W/$mK^2$ at $550^{\circ}C$.

• Nuclear Engineering and Technology
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• 제32권4호
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• pp.342-349
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• 2000

A soil whose texture is silt loam was collected for the study from an area around a nuclear facility in Korea. The equilibrium sorption coefficient between Co$^{2+}$in water and the soil was 1.51/kg, on the other hand, that between Co$^{2+}$ in EDTA and the soil was 0.21/kg. The values calculated by the developed nonequilibrium sorption code corresponded to the experimental values better than those calculated by the existing equilibrium sorption code. When an EDTA solution was used as a solvent to decontaminate Co$^{2+}$ in the soil column, the relative Co$^{2+}$ concentrations of the effluent were higher at 2~10 pore volumes than those of the case using water. The soil in the column was decontaminated by 95.5% of the total amount of Co$^{2+}$ after being flushed with EDTA solution of 20 pore volumes.e volumes.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2009년도 하계학술발표대회 논문집
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• pp.821-826
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• 2009

Due to environmental concerns $CO_2$ has been reintroduced as a potential candidate to replace HFCs in refrigeration systems. Oils are always required in a vapor-compression cycle, and thus actual working fluid in the system is $CO_2$-oil mixtures even though the oil concentrations are low at the heat exchangers and the expansion device. The cooling heat transfer coefficients for $CO_2$-oil mixtures under supercritical condition are required to designing of the gas cooler in the $CO_2$ refrigeration system properly. In the present study, the gas cooling heat transfer coefficients for $CO_2$-PEC9 was estimated by using the Gnileinski correlation, and the Kim and Ghajar model through the previous prediction models for the thermo-physical properties of $CO_2$-oil mixture. The Gnileinski correlation was used when the oil wt.% in the mixture is less than 1.0, and for the higher oil concentration the Kim and Ghajar model was applied. The estimated results agree with the experimental results conducted by the Dang et al.

• 한국건설관리학회논문집
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• 제14권2호
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• pp.78-86
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• 2013

지구온난화의 원인인 $CO_2$를 줄이기 위한 연구들이 전(全) 산업분야에서 활발하게 진행되고 있는 가운데, 건설분야에서도 $CO_2$의 발생을 최소화하려는 연구들이 다양하게 추진되고 있다. $CO_2$ 발생량 최소화를 위한 연구는 $CO_2$ 배출량을 기반으로 하고 있는데 $CO_2$배출량을 산정하는 방법은 크게 연료사용량 대비 탄소배출계수를 이용한 방법, LCA기반 방법론 그리고 산업연관표를 이용한 방법으로 나뉜다. 특히 연료사용량을 기반으로 탄소배출계수를 이용하는 방법은 IPCC 에서 3가지 방법(Tier1~Tier3)을 권장하고 있다. 이 중 현재 가장 많이 활용되고 있는 방법이 Tier1으로서 연료사용량과 탄소배출계수만을 이용하는 방법이다. 그러나 이 방법은 차종별 이동거리가 반영되지 않을 뿐 아니라 주행환경 등의 반영이 안되기 때문에 정확한 $CO_2$배출량을 산정할 수 없다. 특히 건설프로젝트 는 프로젝트의 특성에 따라 이산화탄소 배출량은 달라질 수 있다. 하지만 현재의 방법으로는 이러한 차이를 제대로 반영할 수 없다. 따라서 개별 프로젝트의 특성을 반영하여 이산화탄소 배출량을 산정하는 방법론이 필요하며 이러한 방법론의 가장 핵심은 에너지를 사용하는 건설장비의 이산화탄소 배출량을 직접 측정하는 것이다. 본 연구에서는 건설과정에서 발생하는 이산화탄소의 배출량 산정방법론을 개발하기 위한 연구로서 건설장비의 이산화탄소 배출량을 실시간으로 측정할 수 있는 방법의 제안을 목적으로 한다.

• Transactions on Electrical and Electronic Materials
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• 제15권5호
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• pp.284-289
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• 2014

The effects of additives (Nb, Bi and Cr) on the microstructure, varistor properties, and aging behavior of V/Mn/Co/ La/Dy co-doped zinc oxide ceramics were systematically investigated. An analysis of the microstructure showed that all of the ceramics that were modified with various additives were composed of zinc oxide grain as the main phase, and secondary phases such as $Zn_3(VO_4)_2$, $ZnV_2O_4$, and $DyVO_4$. The $Bi_2O_3$-modified samples exhibited the lowest density, the $Nb_2O_5$-modified sample exhibited the largest average grain size, and the $Cr_2O_3$-modified samples exhibited the highest breakdown field. All additives improved the non-ohmic coefficient (${\alpha}$) by either a small or a large margin, and in particular an $Nb_2O_5$ additive noticeably increased the non-ohmic coefficient to be as large as 36. The $Bi_2O_3$-modified samples exhibited the highest stability with variation rates for the breakdown field and for the non-ohmic coefficient (${\alpha}$) of -1.2% and -26.3%, respectively, after application of a DC accelerated aging stress of 0.85 EB/$85^{\circ}C$/24 h.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.2200-2205
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• 2007

In order to investigate the variation on a heat transfer coefficient during evaporation of $CO_2$, basic experiment on the evaporation heat transfer characteristics in a horizontal micro-channel tube was performed. Hydraulic diameters of micro-channels were 0.68 and 1.46 mm. The experiment apparatus consisted of a test section, a DC power supply, a heater, a chiller, a mass flow meter, a pump and a measurement system. Experiments were conducted for various mass fluxes of 300 to 800 kg/$m^2s$, heat fluxes of 10 to 40 kW/$m^2$ and saturation temperatures of -5 to 5$^{\circ}C$. With the increase heat flux, the evaporation heat transfer coefficient increased. And the significantly change of the heat transfer coefficient was observed at any heat flux and mass flux. As the saturation temperature increased and the hydraulic diameter decreased, the heat transfer coefficient increased.

• Nuclear Engineering and Technology
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• 제56권3호
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• pp.1022-1028
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• 2024

A neutronics study of a supercritical CO₂-cooled fast reactor core for nuclear propulsion has been performed in this work. The thermal power of the reactor core is 30 MWth and a ceramic UO₂ fuel can be used to achieve a 20-year lifetime without refueling. In order to make a compact core with inherent safety features, the drum-type reactivity control system and folding-type shutdown system are adopted. In addition, we suggest a cold shutdown system using gadolinium as a spectral shift absorber (SSA) against flooding. Although there is a penalty of U-235 enrichment for the core embedded with the cold shutdown system, it effectively mitigates the increment of reactivity at the flooding of seawater. In this study, the neutronics analyses have been performed by using the continuous energy Monte Carlo Serpent 2 code with the evaluated nuclear data file ENDF/B-VII.1 Library. The supercritical CO₂-cooled fast reactor core is characterized in view of important safety parameters such as the reactivity worth of reactivity control systems, fuel temperature coefficient (FTC), coolant temperature coefficient (CTC), and coolant temperature-density coefficient (CTDC). We can say that the suggested core has inherent safety features and enough flexibility for load-following operation.

• 한국산학기술학회논문지
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• 제9권3호
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• pp.574-579
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• 2008

수평관내 $CO_2$의 증발 열전달 계수를 실험적으로 조사하였다. 냉매 순환루프의 주요 구성품은 수액기, 변속냉매 펌프, 질량 유량계, 예열기, 증발기(시험부)로 구성된다. 시험부는 내경 4.57 mm의 수평 평활 스텐레스관이다. 실험은 질량유속 $400{\sim}900kg/m^2s$, 포화온도 $5{\sim}20^{\circ}C$, 열유속 $10{\sim}40kW/m^2$인 조건에서 수행하였다. 실험결과로부터 $CO_2$의 열전달은 대류비등보다는 핵비등에 더 많은 영향을 받는 것을 알 수 있었고, $CO_2$의 질량유속은 핵비등에 많은 영향을 미치지 않는 것으로 나타났다. 실험결과와 종래의 상관식을 비교해 본 결과, 기존의 상관식은 실험데이터를 과소예측하였지만, 정 등의 상관식은 좋은 일치를 보였다. 따라서, 수평관내 $CO_2$의 증발 열전달 계수를 예측할 수 있는 정확한 상관식의 개발이 필요하리라 판단된다.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2005년도 전기학술대회논문집
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• pp.216-221
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• 2005

The heat transfer coefficient and pressure drop during gas cooling process of carbon dioxide in a helically coiled tube were investigated experimentally. The experiments were conducted without oil in the refrigerant loop. The main components of the refrigerant loop are a receiver, a variable speed pump, a mass flowmeter, a pre-heater, a gas cooler(test section) and an isothermal tank. The test section is a double pipe type heat exchanger with refrigerant flowing in the inner tube and water flowing in the annulus. It was made of a copper tube with the inner diameter of 4.85 [mm], the outer diameter of 6.35 [mm] and length of 10000 [mm]. The refrigerant mass fluxes were 200${\sim}$600 [kg/$m^2$s] and the average pressure varied from 7.5 [MPa] to 10.0 [MPa]. The main results were summarized as follows: The heat transfer coefficient of supercritical $CO_2$ increases, as the cooling pressure of gas cooler decreases. And the heat transfer coefficient increases with the increase of the refrigerant mass flux. The pressure drop decreases in increase of the gas cooler pressure and increases with increase the refrigerant mass flux.

• Journal of Advanced Marine Engineering and Technology
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• 제31권6호
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• pp.707-714
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• 2007

The heat transfer coefficient and Pressure drop during gas cooling process of $CO_2$ (R-744) in inclined helical coil copper tubes were investigated experimentally. The main components of the refrigerant loop are a receiver. a variable-speed pump. a mass flow meter, a pre-heater and a inclined helical coil type gas cooler (test section). The test section consists of a smooth copper tube of 2.45mm inner diameter. The refrigerant mass fluxes were varied from 200 to $600[kg/m^2s]$ and the inlet Pressures of gas cooler were 7.5 to 10.0 [MPa]. The heat transfer coefficients of $CO_2$ in the inclined helical coil tubes increases with the increase of mass flux and gas cooling pressure of $CO_2$. The pressure drop of $CO_2$ in the gas cooler shows a relatively good agreement with those Predicted by Ito's correlation developed for single-phase in a helical coil tube. The local heat transfer coefficient of $CO_2$ agrees well with the correlation by Pitla et al. However, at the region near pseudo-critical temperature. the experiments indicate higher values than the Pitla et al. correlation. Therefore. various experiments in the inclined helical coil tubes have to be conducted and it is necessary to develop the reliable and accurate prediction determining the heat transfer and pressure drop of $CO_2$ in the inclined helical coil tubes.