• Journal of Environmental Science International
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• v.20 no.12
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• pp.1607-1615
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• 2011

The adsorption performance of cupper and zinc ions($Cu^{2+}$ and $Zn^{2+}$) in aqueous solution was investigated by an adsorption process on reagent grade Na-A zeolite(Z-WK) and Na-A zeolite (Z-C1) prepared from coal fly ash. Z-C1 was synthesized by a fusion method with coal fly ash from a thermal power plant. Batch adsorption experiment with Z-C1 was employed to study the kinetics and equilibrium parameters such as initial metal ions concentration and adsorption time of the solution on the adsorption process. Adsorption rate of metal ions occurred rapidly and adsorption equilibrium reached at less than 120 minutes. The kinetics data of $Cu^{2+}$ and $Zn^{2+}$ ions were well fitted by a pseudo-second-order kinetics model more than a pseudo-first-order kinetics model. The equilibrium data were well fitted by a Langmuir model and this result showed $Cu^{2+}$ and $Zn^{2+}$ adsorption on Z-C1 would be occupied by a monolayer adsorption. The maximum adsorption capacity($q_{max}$) by the Langmuir model was determined as $Cu^{2+}$ 99.8 mg/g and $Zn^{2+}$ 108.3 mg/g, respectively. It appeared that the synthetic zeolite, Z-C1, has potential application as absorbents in metal ion recovery and mining wastewater.

• Proceedings of the Korea Water Resources Association Conference
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• 2010.05a
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• pp.1211-1215
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• 2010

국내의 석탄자원은 1989년부터 비경제 탄광은 폐광시키고 경제성 있는 탄광을 육성하는 석탄산업 합리화시책을 실시하여, 전국 343개의 탄광이 폐광되어 현재는 5개의 탄광만이 가행되고 있다. 이들 가행광산중 강원도 삼척시 도계읍에 위치한 채탄작업을 위한 갱구 입구의 작업지역(DCM, Dogye coal mine)을 선정하여 강우 유출수 모니터링을 시행하였다. DCM지역의 수문분석 결과 연강우량의 83%는 일 강우 80 mm 이하에서 발생하였다. 또한 연강우량의 50% 이상이 40 mm 이하의 강우계급에서 발생하고 있는 것으로 나타났다. 연간 강우횟수는 약 90회 정도 발생하고 있으며, 평균적으로 4일에 1회의 강우가 발생하였다. 또한 100 mm 이상의 강우도 연평균 강수량의 13.78%를 차지하고 있어 집중호우가 총 강우량에 미치는 영향이 작지 않음을 나타냈다. 비점오염의 배출은 강우량에 의해 영향을 많이 받기 때문에 기상이변으로 게릴라성 집중호우가 많이 발생하는 요즘 큰 강우사상에 대하여 많은 대비를 해야 할 것으로 판단되었다.

• Journal of Ecology and Environment
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• v.31 no.1
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• pp.23-29
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• 2008

The effectiveness of rehabilitation programs for coal mining spoils in Samcheok, Jeongsun, and Mungyung were evaluated based on the physicochemical properties of soil in the rehabilitated areas. These spoils were reclaimed by introducing plants such as black locust (Robinia pseudoacacia), pitch pine (Pinus rigida), birch (Betula platyphylla var. japonica), alder (Alnus hirsuta), bush clover (Lespedeza cyrtobotrya), and grass (Lolium perenne) in planting beds covered with forest soil. In the surface soil, the pH, organic matter, total N, available P, and exchangeable Ca showed significant changes over the years after reclamation. The pH and exchangeable Ca content decreased exponentially over time, whereas organic matter increased linearly and total N and available P increased exponentially. Changes in the physicochemical properties of subsurface soils displayed a different pattern. There were significant changes over time in the organic matter, available P, and exchangeable Ca and Mg contents of the soil. Organic matter increased logarithmically with years since rehabilitation and available P increased exponentially. Meanwhile, exchangeable Ca decreased exponentially, and Mg decreased logarithmically. The changes in the subsurface soil were not as dramatic as those in the surface soil. This result suggests that the ameliorating effects of the establishment and growth of plants more pronounced on the surface soil layer. Stand ordination data showed different relationships with time since rehabilitation in the early and later stages of the rehabilitation process. In the early stages of rehabilitation, stands tended to be arranged in the order of reclamation age. However, in the later stages, there was not a clear relationship between reclamation age and vegetation characteristics. This result suggests that soil amelioration is required for the early stages, after which an autogenic effect becomes more prominent as the vegetation becomes better established.

• Economic and Environmental Geology
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• v.25 no.3
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• pp.317-336
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• 1992

The garden soils, main road dusts, residential road dusts, and playground soils/dusts of Seoul, Geumsan, Onsan, and Taebaek areas were analyzed in order to investigate the level of heavy metal pollution by urbanization and industrialization. The soil pH is in the range of 5.48~8.40 and was generally neutral. The color of soils and dusts is mainly Raw Umber to dark greyish Raw Umber. Some samples from Taebaek city, a coal mining area, showed a deep black color due to contamination by coal dusts. Major minerals of the dusts and soils are quartz, feldspars, and micas, reflecting the composition of the parent rocks. However, pyrite was found as a major mineral in the samples of industrial road dusts of Onsan, a smelting area, and resicential road dusts of Taebaek. Thus, the high level of heavy metals in mining and smelting areas can be explained with the sulfide minerals. The mode of occurences of heavy metals in Seoul, a comprehensive urbanized area, were related to the metallic pollutants and organic materials through observation by scanning eletron microscopy. In main road and residential road dusts of Onsan area, Cd, Zn, and Cu were extremely high. Some industrial road and residential road dusts of Seoul area showed high Cu, Zn, and Pb contents, wereas some garden soils and residential road dusts of Taebaek area were high in As content. In general, the heavy metal contents in dust samples were two to three times higher than those in soil samples. Main road dust samples were the most reflective from the discriminant analysis of multi-element data. Cadmium, Sb, and Se in Onsan area, As in Taebaek area, Pb and Te in Seoul area were most characteristic in discriminating the studied areas. Therefore, Cd in smelting areas, As in coal mining areas, and Pb in metropolitan areas can be suggested as the characteristic elements of each pollution pattern. The dispersion of heavy metal elements in urban areas tends to orignate in main roads and deposit in garden soils through the atmosphere and residential roads. The heavy metal contamination in Seoul is characteristic in areas with high population, factory, road, and traffic decsities. Heavy metal contents are high in the vicinity of smelters in Onsan area and are decayed to background levels from one kilometer away from the smelters.

• Tunnel and Underground Space
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• v.17 no.4
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• pp.255-265
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• 2007

As the mechanism and effect range of subsidence are altered according to the various conditions (the ground condition, the earth pressure, the geometric condition of underground cavity and the structure load), the analysis and prediction of subsidence in abandoned mining area are very difficult. Also, as the geological characteristics and the mining methods are differed in each mines, the application of the pre-existing reinforcements without improvement has a lot of difficulties and limits. In this study, the various underground investigation such as long-depth core drilling, seismic tomography and BIPS (borehole image processing system) were performed, the distribution of underground cavity and coal seam and rock relaxation condition were analyzed. And we predicted the type of subsidence and estimated the subsidence by theories of mining subsidence. With these results, we analyzed the mechanism of subsidence occurrence in the research object area. Finally, we improved existing methods which were applied to the abandoned mining area and also we established the rational reinforcement for the ground and structure foundation against each subsidence cause.

• Geomechanics and Engineering
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• v.29 no.2
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• pp.99-111
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• 2022

Instability of bolted rock mass has been a major hazard in the underground coal mining industry for decades. Developing effective support guidelines requires understanding of complex bolted rock mass failure mechanisms. In this study, the dynamic failure behavior, mechanical behavior, and energy evolution of a laboratory-scale bolted specimens is studied by conducting laboratory static-dynamic coupled loading tests. The results showed that: (1) Under static-dynamic coupled loading, the stress-strain curve of the bolted rock mass has a significant impact velocity (strain rate) correlation, and the stress-strain curve shows rebound characteristics after the peak; (2) There is a critical strain rate in a rock mass under static-dynamic coupled loading, and it decreases exponentially with increasing pre-static load level. Bolting can significantly improve the critical strain rate of a rock mass; (3) Compared with a no-bolt rock mass, the dissipation energy ratio of the bolted rock mass decreases exponentially with increasing pre-static load level, the ultimate dynamic impact energy and dissipation energy of the bolted rock mass increase significantly, and the increasing index of the ratio of dissipation energy increases linearly with the pre-static load; (4) Based on laboratory testing and on-site microseismic and stress monitoring, a design method is proposed for a roadway bolt support against dynamic load disturbance, which provides guidance for the design of deep underground roadway anchorage supports. The research results provide new ideas for explaining the failure behavior of anchorage supports and adopting reasonable design and construction practices.

• Geomechanics and Engineering
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• v.32 no.4
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• pp.375-385
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• 2023

There are many joint fissures distributed in the engineering rock mass. In the process of geological history, the underground rock mass undergoes strong geological processes, and undergoes complex geological processes such as fracture breeding, expansion, recementation, and re-expansion. In this paper, the damage-stick-slip process (DSSP), an analysis model used for rock mass failure slip, was established to examine the master control and time-dependent mechanical properties of the new and primary fractures of a multi-fractured rock mass under the action of stress loading. The experimental system for the recemented multi-fractured rock mass was developed to validate the above theory. First, a rock mass failure test was conducted. Then, the failure stress state was kept constant, and the fractured rock mass was grouted and cemented. A secondary loading was applied until the grouted mass reached the intended strength to investigate the bearing capacity of the recemented multi-fractured rock mass, and an acoustic emission (AE) system was used to monitor AE events and the update of damage energy. The results show that the initial fracture angle and direction had a significant effect on the re-failure process of the cement rock mass; Compared with the monitoring results of the acoustic emission (AE) measurements, the master control surface, key blocks and other control factors in the multi-fractured rock mass were obtained; The triangular shaped block in rock mass plays an important role in the stress and displacement change of multi-fracture rock mass and the long fissure and the fractures with close fracture tip are easier to activate, and the position where the longer fractures intersect with the smaller fractures is easier to generate new fractures. The results are of great significance to a multi-block structure, which affects the safety of underground coal mining.

• Geomechanics and Engineering
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• v.38 no.3
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• pp.215-229
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• 2024

Because of the various patterns of deep-water inrush and complicated mechanisms, accurately predicting mine water inflows is always a difficult problem for coal mine geologists. In study presented in this paper, the water inrush channels were divided into four basic water diversion structures: aquifer, rock fracture zone, fracture zone and goaf. The fluid flow characteristics in each water-conducting structure were investigated by laboratory tests, and multistructure and multisystem coupling flow analysis models of different water-conducting structures were established to describe the entire water inrush process. Based on the research of the water inrush flow paths, the analysis model of different water inrush space structures was established and applied to the prediction of mine water inrush inflow. The results prove that the conduction sequence of different water-conducting structures and the changing rule of permeability caused by stress changes before and after the peak have important influences on the characteristics of mine water-gushing. Influenced by the differences in geological structure and combined with rock mass RQD and fault conductivity characteristics and other mine exploration data, the prediction of mine water inflow can be realized accurately. Taking the water transmitting path in the multistructure as the research object of water inrush, breaking through the limitation of traditional stratigraphic structure division, the prediction of water inflow and the estimation of potentially flooded area was realized, and water bursting intensity was predicted. It is of great significance in making reasonable emergency plans.

• Journal of the Mineralogical Society of Korea
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• v.24 no.4
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• pp.327-336
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• 2011

• Communications of the Korean Mathematical Society
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• v.11 no.3
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• pp.601-611
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• 1996

In this paper, we introduce the notion of weakly associative BCI-algebras and investigate structure of it. Some of characterizations of elements of the quasi-associative part Q(X) of a BCI-algebra X are shown.