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Influence of Nd Content on Magnetic Properties of Nanocrystalline $\alpha$-(Fe, Co)-Based Nd-(Fe, Co)-B-Nb-Cu Alloys ($\alpha$-(Fe, Co)기 Nd-(Fe, Co)-B-Nb-Cu 초미세결정립합금의 자기특성에 미치는 Nd의 영향)

  • 조덕호;조용수;김택기;송민석;김윤배
    • Journal of the Korean Magnetics Society
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    • v.9 no.3
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    • pp.154-158
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    • 1999
  • Magnetic properties and microstructure of nanocrystalline $\alpha$-(Fe, Co)-based Nd-(Fe, Co)-B-Nb-Cu alloys have been investigated. $Nd_x(Fe_{0.9}Co_{0.1})_{90-x}B_6Nb_3Cu_1$(x=2, 3, 4, 5, 6) alloys prepared by rapid solidification process show amorphous phase except the one with x=2. By a proper annealing, the amorphous in the alloy is changed to a nanocrystalline phase. It is confirmed that the nanocrystalline alloys are composed of $\alpha$-(Fe, Co) and $Nd_2(Fe, Co)_{14}B_1$ phase. The optimally annealed $Nd_3(Fe_{0.9}Co_{0.1})_87B_6Nb_3Cu_1$ alloy shows the highest remanence of 1.55 T. The coercivity increases with the increase of Nd content The maximum coercivity of 4.6 kOe is obtained from an optimally annealed $Nd_6(Fe_{0.9}Co_{0.1})_84B_6Nb_3Cu_1$ alloy, resulting in the maximum energy product of 10.6 MGOe.

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Preparation of TiCoxFe1-x(x=0.50~1.00) System Metal Membrane for Hydrogen Separation (수소분리용 TiCoxFe1-x(x=0.50~1.00)계 금속막 제조)

  • Jang, Kyu-young;Kang, Tae Beom
    • Membrane Journal
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    • v.25 no.2
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    • pp.191-201
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    • 2015
  • We have studied on the preparation of $TiCo_xFe_{1-x}$(x=0.50~1.00) system alloy, the characteristics of $TiCo_xFe_{1-x}$(x=0.50~1.00) system alloy by X-ray diffractometer (XRD), pressure composition temperature (PCT) curve, scanning electron microscopy (SEM) and the $H_2-N_2$ gas mixture separation of $TiCo_xFe_{1-x}$(x=0.50~1.00)- stainless steel (SS) composite membranes. The formation of $TiCo_xFe_{1-x}$(x=0.50~1.00) system alloys with cubic crystal same as TiCo was confirmed by X-ray diffractometer. $TiCo_xFe_{1-x}$(x=0.50~1.00) system alloys showed the hysteresis at $120^{\circ}C$. As the Fe content of $TiCo_xFe_{1-x}$(x=0.50~1.00) system alloys increased, the hysteresis was increased both range x=0.90~1.00 and x=0.55~0.60, and the range x=0.55~0.90 gave decreased hysteresis. $TiCo_{0.55}Fe_{0.45}$ alloy was the one showed the lowest hysteresis among them. The lowest value of hydrogen permeation pressure of $TiCo_xFe_{1-x}$(x=0.50~1.00)-SS composite membrane was $TiCo_{0.55}Fe_{0.45}$-SS composite membrane with the value of 2.5 atm at $120^{\circ}C$; otherwise, $TiCo_{0.90}Fe_{0.10}$-SS composite had the highest pressure value among the membranes with the value of 10 atm. $TiCo_{0.55}Fe_{0.45}$-SS composite membrane was the best to separate the $H_2-N_2$ gas mixture excellently among the $TiCo_xFe_{1-x}$(x=0.50~1.00)-SS composite membranes since $TiCo_{0.55}Fe_{0.45}$ had the least hysteresis, and hydrogen permeation pressure was the lowest with value of 2.5 atm.

Effect of Alkali Promoter in CO Hydrogenation Using Co/NaY Catalyst (Co/NaY 촉매를 이용한 CO 수소화 반응에 있어서 알칼리 첨가제의효과)

  • Myong-Mo Sung;Min-Young Youn;Yunsoo Kim;Hang Nam Paik
    • Journal of the Korean Chemical Society
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    • v.32 no.5
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    • pp.501-506
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    • 1988
  • The effects of alkali promoters on the activity and selectivity of Co/NaY catalyst have been investigated. The catalysts were prepared by impregnating NaY with aqueous solutions of alkali compounds and a benzene solution of $Co_2(CO)_8$. Hydrocarbon synthesis was studied in a flow reactor under the reaction conditions : temperature = 200∼250$^{\circ}C$, space velocity = 120∼$160hr^{-1}$, pressure = 1 atm, $H_2$/CO = 1. As the basicity of alkali promoter increases, the olefin selectivity, probability of chain growth, and CO$_2$ formation increase and methane formation decreases. The activity of CO hydrogenation increases with the pH of alkali solutions.

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5.0 inch WVGA Top Emission AMOLED Display for PDA

  • Lee, Kwan-Hee;Ryu, Seoung-Yoon;Park, Sang-Il;Ryu, Do-Hyung;Kim, Hun;Song, Seung-Yong;Chung, Bo-Yong;Park, Yong-Sung;Kang, Tae-Wook;Kim, Sang-Chul;Cho, Yu-Sung;Park, Jin-Woo;Kwon, Jang-Hyuk;Chung, Ho-Kyoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.7-10
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    • 2003
  • Samsung SDI has developed a full color 5.0" WVGA AMOLED display with top emission and a super fine pitch of 0.1365mm(l86ppi), the world's highest resolution OLED display ever reported to date. Scan driver circuits and demux circuit were integrated into the display panel, using low temperature poly-Si TFT CMOS technology, and data driver circuit were mounted using COG chips. Peak luminescence was greater than 300cd/ $m^2$ with power consumption of 500mW with 30% of the pixels on illuminated.

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CoMFA and CoMSIA Analysis on the Fungicidal Activity against Damping-off (Pythium ultimum) with N-phenylbenzenesulfonamide Analogues (N-phenylbenzenesulfonamide 유도체들에 의한 모잘록병균 (Pythium ultimum)의 살균활성에 관한 CoMFA 및 CoMSIA분석)

  • Jang, Seok-Chan;Kang, Kyu-Young;Sung, Nack-Do
    • The Korean Journal of Pesticide Science
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    • v.11 no.1
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    • pp.8-17
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    • 2007
  • Three-dimensional quantitative structure-activity relationships (3D-QSARs) on the fungicidal activity against damping-off (Pythium ultimum) with N-phenylbenzenesulfonamide and N-phenyl-2-thienylsulfonamide analogues (1-34) were studied quantitatively using CoMFA (comparative molecular field analysis) and CoMSIA (comparative molecular similarity indeces analysis) methodologies. On the whole, the statistical qualities of CoMSIA models with field fit alignment (FF1-FF5) were slightly higher than that of atom based fit alignment (AF1-AF5) but, the deviations of statistical quality between two alignments in case of CoMFA models were slightly lower. The statistical results of CoMFA and CoMSIA model showed that the optimized CoMSIA model (FF1: $r_{cv.}^2\;(q^2)=0.674$ & $r_{ncv.}^2=0.964$) for damping-off is better predictability and fitness for fungicidal activities than CoMFA model (AF5: $r_{cv.}^2\;(q^2)=0.616$ & $r_{ncv.}^2=0.930$). The fungicidal activities according to the information of the CoMSIA (FF1) model were dependence upon the electrostatic and hydrophobic field of the N-phenylbenzene sulfonamide analogues. Therefore, from the results of graphical analyses on the contour maps with CoMSIA (FF3) model, it is expected that the characters of R4-substituent on the N-phenyl ring as hydrophobic and hydrogen bond acceptor will be contributed to the fungicidal activity against damping-off.

Microstructure and Magnetic properties of $Ti_{1-x}Co_xO_2$ Magnetic semiconductor thin films by Metal Organic Chemical Vapor Deposition (유기금속화학기상증착법으로 제조된 자성반도체 $Ti_{1-x}Co_xO_2$ 박막의 미세구조 및 자기적 특성)

  • Seong, Nak-Jin;Yoon, Soon-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.155-159
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    • 2003
  • Polycrystalline $Ti_{1-x}Co_xO_2$ thin films on $SiO_2$ (200 nm)/Si (100) substrates were prepared using liquid-delivery metalorganic chemical vapor deposition. Microstructures and ferromagnetic properties were investigated as a function of doped Co concentration. Ferromagnetic behaviors of polycrystalline films were observed at room temperature, and the magnetic and structural properties strongly depended on the Co distribution, which varied widely with doped Co concentration. The annealed $Ti_{1-x}Co_xO_2$ thin films with $x{\leq}0.05$ showed a homogeneous structure without any clusters, and pure ferromagnetic properties of thin films are only attributed to the $Ti_{1-x}Co_xO_2$ (TCO) phases. On the other hand, in case of thin films above x=0.05, Co clusters formed in a homogeneous $Ti_{1-x}Co_xO_2$ Phase, and the overall ferromagnetic (FM) properties depended on both $FM_{TCO}$ and $FM_{Co}$. Co clusters with about 10nm-150nm size decreased the value of Mr (the remanent magnetization) and increased the saturation magnetic field.

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Convergence in Per Capita CO2 Emission by Income Group (국가별 소득수준에 따른 1인당 CO2 배출량 수렴 분석)

  • Cho, Hyangsuk
    • Environmental and Resource Economics Review
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    • v.28 no.1
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    • pp.1-37
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    • 2019
  • This study investigates the convergence in per capita $CO_2$ emission by income group for an unbalanced panel of 152 countries from 1980 to 2013 using beta and sigma convergence model. Absolute beta and sigma convergence differed by $CO_2$ emission reduction policies in each countries. Conditional beta convergence shows that per capita income has a negative effect on growth in per capita $CO_2$ emission. In particular, better-quality institutions and technology accelerated the negative effect of per capita income on the speed of convergence of per capita $CO_2$ emission in high-income countries. For middle-income countries, the growth of income affected the convergence of $CO_2$ emission per capita, but institutional quality has an insignificant impact. On the other hand, improvements in the level of technology have a mitigating effect on the negative impact of income in middle-income and low-income countries, contributing to the increase in $CO_2$ emission.

Surface Diffusion Coefficients of Adatoms on Strained Overlayers (스트레인을 받고 있는 표면에서의 원자 확산계수)

  • Chung, K.H.;Yoon, J.K.;Kim, H.;Kahng, S.J.
    • Journal of the Korean Vacuum Society
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    • v.17 no.5
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    • pp.381-386
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    • 2008
  • Adatom kinetics on the surfaces of Co overlayers, prepared on the W(110) surface, was studied with scanning tunneling microscopy. By counting the number-density of the adatom-islands, we estimated the ratio of adatom diffusion coefficients. The ratio $D_{W(110)}:D_{1ML\;Co}:D_{2ML\;Co}$ was measured to be 1 : 125 : 33000 at room temperature, where $D_{W(110)},\;D_{1ML\;Co}$, and $D_{2ML\;Co}$ are the diffusion coefficients on bare W(110) surface, on one-monolayer Co overlayer, and on two-monolayers Co overlayers, respectively. An increased diffusion coefficient on two-ML Co overlayers, relative to that on one-ML Co overlayers, was explained with the heteroepitaxial strain effect.

Magnetoresistance Behavior of CuCo and AgCo Films using a Thermal Evaporation (열증착법으로 제조한 박막헝 CuCo와 AgCo의 자기저항 효과)

  • Song, Oh-Sung;Yoon, Ki-Jeong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.5
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    • pp.811-816
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    • 2006
  • The single layered magnetic thin films with anisotropic magnetoresistance behavior have advantage on micro integration due to their low cost in manufacturing. Although the conventional MCo (M=Cu, Ag) amorphous ribbons using a rapid solidification process have showed appropriate for magnetic property for bulk devices, they are not appropriate for micro-scale devices due to their brittleness. We prepared the thermal evaporated 100 nm-thick $Cu_{1-x}Co_x\;and\;Ag_{1-x}Co_x(x=0.1{\sim}0.7)$ films on silicon wafers and investigated the magnetic property of the as-depo films such as magnetization and magnetoresistance ratio. We confirmed that the maximum MR ratio of 1.4 and 2.6% at the external field of 0.5 Tesla in $CuCo_{30},\;AgCo_{40}$ films, respectively. Our result implies that AMR may be slightly less than those of the conventional CuCo and AgCo ribbons due to surface scattering, but their AMR ratio be enough for micro-scale application with easy integration compatibility for the process without surface oxidation.

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Half-metallicity and Magnetism of Co2ZrSi/ZnTe(001) Interface: A First-principles Study (Co2ZrSi/ZnTe(001)계면의 자성과 반쪽금속성에 대한 제일원리 연구)

  • Jin, Y.J.;Lee, J.I.
    • Journal of the Korean Magnetics Society
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    • v.17 no.4
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    • pp.147-151
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    • 2007
  • We have investigated the half-metallicity and magnetism for the Heusler ferromagnet $Co_2$ZrSi interfaced with semiconductor ZnTe along the (001) plane by using the full-potential linearized augmented plane wave (FLAPW) method. We considered low types of possible interfaces: ZrSi/Zn, ZrSi/Te, Co/Zn, and Co/Te, respectively. From the calculated density of states, it was found that the half-metallicity was lost at all the interfaces, however for the Co/Te system the value of minority spin density of states was close to zero at the Fermi level. These facts are due to the interface states, appeared in the minority spin gap in bulk $Co_2$ZrSi, caused by the changes of the coordination and symmetry and the hybridizations between the interface atoms. At the Co/Te interface, the magnetic moments of Co atoms are 0.68 and $0.78{\mu}_B$ for the "bridge" and "antibridge" sites, respectively, which are much reduced with respect to that ($1.15{\mu}_B$) of the bulk $Co_2$ZrSi. In the case of Co/Zn, Co atoms at the "bridge" and "antibridge" sites have magnetic moments of 1.16 and $0.93{\mu}_B$, respectively, which are almost same or slightly decreased compared to that of the bulk $Co_2$ZrSi. On the other hand, for the ZrSi/Zn and ZrSi/Te systems, the magnetic moments of Co atoms at the sub-interface layers are in the range of $1.13{\sim}1.30\;{\mu}_B$, which are almost same or slightly increased than that of the bulk $Co_2$ZrSi.