• Title/Summary/Keyword: co-firing

Search Result 269, Processing Time 0.025 seconds

Effect of metal conditioner on bonding of porcelain to cobalt-chromium alloy

  • Minesaki, Yoshito;Murahara, Sadaaki;Kajihara, Yutaro;Takenouchi, Yoshihisa;Tanaka, Takuo;Suzuki, Shiro;Minami, Hiroyuki
    • The Journal of Advanced Prosthodontics
    • /
    • v.8 no.1
    • /
    • pp.1-8
    • /
    • 2016
  • PURPOSE. The purpose of this study was to evaluate the efficacy of two different metal conditioners for non-precious metal alloys for the bonding of porcelain to a cobalt-chromium (Co-Cr) alloy. MATERIALS AND METHODS. Disk-shaped specimens ($2.5{\times}10.0mm$) were cast with Co-Cr alloy and used as adherend materials. The bonding surfaces were polished with a 600-grid silicon carbide paper and airborne-particle abraded using $110{\mu}m$ alumina particles. Bonding specimens were fabricated by applying and firing either of the metal conditioners on the airborne-particle abraded surface, followed by firing porcelain into 5 mm in diameter and 3 mm in height. Specimens without metal conditioner were also fabricated. Shear bond strength for each group (n=8) were measured and compared (${\alpha}=.05$). Sectional view of bonding interface was observed by SEM. EDS analysis was performed to determine the chemical elements of metal conditioners and to determine the failure modes after shear test. RESULTS. There were significant differences among three groups, and two metal conditioner-applied groups showed significantly higher values compared to the non-metal conditioner group. The SEM observation of the sectional view at bonding interface revealed loose contact at porcelain-alloy surface for non-metal conditioner group, however, close contact at both alloy-metal conditioner and metal conditioner-porcelain interfaces for both metal conditioner-applied groups. All the specimens showed mixed failures. EDS analysis showed that one metal conditioner was Si-based material, and another was Ti-based material. Si-based metal conditioner showed higher bond strengths compared to the Ti-based metal conditioner, but exhibited more porous failure surface failure. CONCLUSION. Based on the results of this study, it can be stated that the application of metal conditioner is recommended for the bonding of porcelain to cobalt-chromium alloys.

Utilization of Upgraded Solid Fuel Made by the Torrefaction of Indonesian Biomass (인도네시아 바이오매스 반탄화를 통해 제조된 고품위 고형연료의 활용)

  • Yoo, Jiho
    • Clean Technology
    • /
    • v.26 no.4
    • /
    • pp.239-250
    • /
    • 2020
  • Biomass is an abundant renewable energy resource that can replace fossil fuels for the reduction of greenhouse gas (GHG). Indonesia has a large number of cheap biomass feedstocks, such as reforestation (waste wood) and palm residues (empty fruit bunch or EFB). In general, raw biomass contains more than 20% moisture and lacks calorific value, energy density, grindability, and combustion efficiency. Those properties are not acceptable fuel attributes as the conditions currently stand. Recently, torrefaction facilities, especially in European countries, have been built to upgrade raw biomass to solid fuel with high quality. In Korea, there is no significant market for torrefied solid fuel (co-firing) made of biomass residues, and only the wood pellet market presently thrives (~ 2 million ton yr-1). However, increasing demand for an upgraded solid fuel exists. In Indonesia, torrefied woody residues as co-firing fuel are economically feasible under the governmental promotion of renewable energy such as in feed-in-tariff (FIT). EFB, one of the chief palm residues, could replace coal in cement kiln when the emission trading system (ETS) and clean development mechanism (CDM) system are implemented. However, technical issues such as slagging (alkali metal) and corrosion (chlorine) should be addressed to utilize torrefied EFB at a pulverized coal boiler.

CO sensing Properties of $SnO_{2}$ fine particles ($SnO_{2}$ 초미세 입자의 CO 감지 특성)

  • Park, Jin-Seoung;Park, Bo-Seok;Noh, Whyo-Sub
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2002.05b
    • /
    • pp.55-61
    • /
    • 2002
  • Ultra-fine particles of $SnO_{2}$ was synthersized by the sol-gel powder processing using tin(II) chloride dihydrate$(SnCl_{2}{\cdot}2H_{2}O)$ and ethanol$(C_{2}H_{5}OH)$ as raw materials. Gel powders can be obtained by drying of sol at $120^{\circ}C$ after aging 72hrs and 168hrs. The amount of $SnO_{2}$ phase was increased with temperature because of the evaporation of volatile components, and the creation of $SnO_{2}$ phase was almost done by the heat treatment at $700^{\circ}C/30min$ The grain sizes after firing are about 20-30nm, and it showed the narrow distribution of grain size. The specimens to measure electrical properties were fabricated by the thick film screen printing technique on the alumina substrates. The conductance of $SnO_{2}$ was increased with temperature up to $380^{\circ}C$ by the typical conduction mechanism of semiconducting ceramics. There was a region of constant conductance between about $200^{\circ}C$ and $380^{\circ}C$ due to the increment of electron concentration with temperature and the annihilation of conduction carriers by the absorption and electron trapped-ionization of oxygen on the surface of $SnO_{2}$, It was finally showed the intrinsic behaviors above $450^{\circ}C$. The sensing properties of response time, recovery, and sensitivity of CO were improved with aging time.

  • PDF

Preparation of $SnO_2$ Semiconducting Gas Sensor by Wet Process (습식방법에 의한 $SnO_2$ 반도체 가스센사 제조)

  • 전병식;김홍대;최병현;최성근
    • Journal of the Korean Ceramic Society
    • /
    • v.23 no.3
    • /
    • pp.53-61
    • /
    • 1986
  • A gas sensor which has been made by wet process had fabricated by coating each of the mixture on alumina tube and firing at 85$0^{\circ}C$ for 3hrs. A gas concentration such $H_2$, CO, $C_3H_8$, $C_2H_2$ and $CH_4$ vs its detection voltage characteristics has been in-vestigated on $SnO_2-In_2O_3-MgO$ system doped with PdO, $La_2O_3$, $ThO_2$, NiO and $Nb_2O_5$ The optimum sensitivity composition for various gases were 90w/o $SnO_2$-9w/o $In_2O_3$-1w/o MgO for $H_2$, $C_2H_2$ CO and $C_3H_8$ and 95w/o $SnO_2$-4w/o $In_2O_3$-1w/o MgO for $CH_4$. The sample which has been made by wet process than dry process had predominated sensitivity for each gases and particle size of the sample coprecipitated with PH=9 was 0.1${\mu}{\textrm}{m}$ The $SnO_2$-In2_O_3-MgO$ system doped with 2w/o $Nb_2O_5$ and NiO was the most sensitive for $H_2$ and $C_2H_2$ gas. In $SnO_2$-In2_O_3-MgO$ system doped with $ThO_2$ the sensitivity of $H_2$ gas was decreased but CO gas was in-creased when dopant con was increased.

  • PDF

The Study of Economic Feasibility of Wood Pellet in Domestic Power Plants Sector (국내 발전부문에서의 목재펠릿 경제성 연구)

  • Jeong, Nam-Young;Kim, Lae-Hyun
    • Journal of Energy Engineering
    • /
    • v.19 no.4
    • /
    • pp.251-257
    • /
    • 2010
  • Korea have a plan to enforce the Renewable Portfolio Standard(RPS) in 2012 for climate change action and effective use of energy but because of lack of renewable energy resources and limits of technology development, it will be hard to fullfill a target for RPS obligation in domestic power generation sector and woodchip biomass cofiring with coal combustion is the one of the alternative methods of the goal. Woodchip biomass cofiring with coal combustion is easy to approach technical design and has competitiveness of $CO_2$ & renewble energy certificate benefit and also has much lower generation cost than any other renewable energy resources. Because of that reason, woodchip biomass cofiring with coal combustion should be needed to fullfill the goal for RPS obligation in domestic power generation sector with midlong-term direction.

Properties of $Fe_2O_3$-doped $SnO_2$ Oxides for CO Sensor (CO 센서용 $Fe_2O_3$를 첨가한 $SnO_2$ 산화물의 특성)

  • Bae, In-Soo;Lee, Hyun-Kyu;Hong, Kwang-Joon;Lee, Woo-Sun;Park, Jin-Seoung
    • Journal of Sensor Science and Technology
    • /
    • v.10 no.4
    • /
    • pp.222-231
    • /
    • 2001
  • The material properties of $SnO_2$ were investigated as a function of the amount of $Fe_2O_3$, the partial pressure of oxygen, the concentration of CO gas, and temperature. $Fe_2O_3$-doped $SnO_2$ thick films were prepared by the screen printing technique on alumina substrate. The specimens sintered at $700^{\circ}C$ for 6 hours showed little difference of the grain size and narrow distribution with the content of $Fe_2O_3$. The electrical conductance of undoped $SnO_2$ is high at low firing temperature and at low partial pressure of oxygen. The electrical conductance of $Fe_2O_3-$-doped $SnO_2$ is increased with measurement temperature, but decreased with the content of $Fe_2O_3$. The dependence of oxygen partial pressure is decreased with dopant addition. The highest sensitivity and the good properties of response speed and repeatability for CO gas were observed on the specimen with 0.1 mol% $Fe_2O_3$ at $350^{\circ}C$.

  • PDF

A 2012 Size Multilayer LTCC BPE for 2.4 GHz Band (2.4 GHz 대역 2012사이즈 적층 LTCC 대역통과 필터의 설계 및 제작)

  • 이영신;송희석;박종철
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.10 no.1
    • /
    • pp.19-24
    • /
    • 2003
  • A very small size 2.4 GHz ISM band BPF(Band Pass Filter) is realized using LTCC Multi-layer technology. Proposed design method enables to achieve BPF size $2.0\times1.2\times0.8mm^3$. A $lambda/4$ resonator with shunt-to-ground loaded capacitor is used to shorten resonator length, achieving higher quality factor. Also this resonator enables BPF to improve out-of-band rejection. Coupling coefficients between coupled strip-line resonators and external quality factor (Qe) of a resonator are derived and applied to the filter design. The measured results show good agreement with simulated data.

  • PDF

Numerical Study of Biomass Char Applying FERPM (FERPM을 적용한 바이오매스 촤의 전산해석적 연구)

  • OH, HYUN-SUK;KIM, KANG-MIN;KIM, GYEONG-MIN;JEON, CHUNG-HWAN
    • Journal of Hydrogen and New Energy
    • /
    • v.31 no.1
    • /
    • pp.122-131
    • /
    • 2020
  • To reduce emissions from coal-fired power plants, researchers focusing on coal and biomass co-firing technology. Biomass, with its carbon-neutral nature and lower quantities of nitrogen and sulfur compared with coals, has a positive impact on coal-fired power generation. Many studies on the combustion of biomass have been conducted, but the study on the combustion characteristics of biomass char is limited. FERPM predicts char combustion characteristics with high accuracy by introducing experimental data-based parameters of biomass char and has not yet been applied in numerical simulation. In this study, FERPM is numerically applied to char combustion of wood pellets representing wood-based biomass and the combustion characteristics are compared with the kinetic/diffusion limited model, intrinsic model, and diffusion limited model.

Study on the Characteristics of Bio-mass according to Various Process of Torrefaction (반탄화 공정 변화에 따른 바이오매스 연료의 특성 연구)

  • Ohm, Tae-In;Chae, Jong-Seong;Kim, Jung-Ku;Choi, Soo-A;Oh, Sea-Cheon
    • 한국연소학회:학술대회논문집
    • /
    • 2014.11a
    • /
    • pp.375-378
    • /
    • 2014
  • In this study, we carried out torrefaction experiment using PKS(Palm Kernel Shell), and Bagasse as a raw material of oversee of herbaceous biomass and using waste wood and logging residue as a raw material of domestic of woody biomass. And then, by analyzing the physical & chemical properties, we investigated the characteristics as a fuel. By using the result of thermo gravimetric analysis, the biomass residue was torrefied for 30 minutes at a temperature range of $250-350^{\circ}C$ in anaerobic condition. As a result, torrefied materials of moisture content are lower than raw, but of fixed carbon, calorific value and ash are higher than raw.

  • PDF

Study on the Compositions of Photosensitive Ag Paste for Patterning Embedded Fine-Line Inductor in LTCC (LTCC 내장형 미세 라인 인덕터 구현을 위한 감광성 Ag Paste 조성에 관한 연구)

  • Lee, Sang-Myoung;Park, Seong-Dae;Yoo, Myong-Jae;Lee, Woo-Sung;Kang, Nam-Kee;Nahm, Sahn
    • Journal of the Korean Ceramic Society
    • /
    • v.44 no.3 s.298
    • /
    • pp.157-161
    • /
    • 2007
  • Line width under $100\;{\mu}m$ with good resolution is difficult to achieve using conventional thick-film process utilizing screen printing method. However combined with lithography technology finer line and space for miniaturization and highly integrated package is achievable. In this study, photosensitive Ag paste of optimum formulation used for thick film lithography technology was fabricated by various Ag powder, glass powder and additives. As the result, line width of $30\;{\mu}m$ with good definition and reduced mismatch during co-firing with LTCC substrate was acquired. Formulated Ag paste was used to pattern embedded fine line inductor with over 90% yield.